期刊
SOLAR ENERGY MATERIALS AND SOLAR CELLS
卷 130, 期 -, 页码 426-434出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.solmat.2014.07.033
关键词
Hybrid solar cell; Samarium phosphate; Electron/hole transport; Rare-earth compounds; Titanium dioxide
资金
- Natural Science Foundation of China [61366003]
- science and technology project of the education department of Jiangxi Province, China [GJJ13474, GJJ14533]
- Aviation Science Fund of China [2013ZF56025]
An effective energy level regulation of acceptor by doping samarium phosphate nanophosphors (SmPO4 NPs) was reported for inorganic/organic hybrid solar cell applications. SmPO4 NPs doped TiO2/P3HT bulk heterojunction (BHJ) solar cell shows an enhanced power conversion efficiency of approaching 3% as compared with that of its counterpart without SmPO4 NPs (1.98%). The underlying photophysical mechanism was probed by applying femtosecond transient absorption spectroscopy and the results show that the efficiency enhancement was ascribed to the improved hot electron, less energetic electron, hole transports at the interface of BHJ apart from down-conversion photoluminescence of SmPO4 NPs. It has been evidenced that the hot electron transfer life time was shortened by more than 40% (i.e., from tau(hot-e)=30.2 to 17.9 ps) than pure TiO2 acceptor while the hole transfer lifetime was boosted by almost 20% (i.e., from 6.92 to 5.58 ns). Such charge carrier improvements stem from the efficient energy level regulations by SmPO4 NPs. In detail, the conduction band (CB) edge of TiO2 has been elevated by 0.57 eV while the valence band (VB) edge has been elevated by 0.32 eV, thus not only narrowing down the energy offset between CB energy levels of acceptor TiO2 and donor P3HT, but also meanwhile enlarging the band gap of TiO2 itself that permits to inhibit electron-hole recombination within TiO2. This work demonstrates that samarium ions can efficiently facilitate exciton generation, dissociation and charge transport and have an important role in enhancing photovoltaic performance. (C) 2014 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据