4.7 Article

Synthesis of low bandgap polymer based on 3,6-dithien-2-yl-2, 5-dialkylpyrrolo[3,4-c]pyrrole-1,4-dione for photovoltaic applications

期刊

SOLAR ENERGY MATERIALS AND SOLAR CELLS
卷 95, 期 4, 页码 1168-1173

出版社

ELSEVIER
DOI: 10.1016/j.solmat.2010.12.049

关键词

Conjugated polymer; DTDPP; Low bandgap; Polymer solar cells

资金

  1. National Nature Science Foundation of China (NSFC) [20674049, 20834005]
  2. Shanghai municipal government [B202, 102215]

向作者/读者索取更多资源

A new 3,6-dithien-2-yl-2,5-dialkylpyrrolo[3,4-c]pyrrole-1,4-dione (DTDPP) based polymer, poly {thieno[3,2-b]thiophene-alt-3,6-dithien-2-yl-2,5-di(2-octyldodecyl)-pyrrolo[3,4-c]pyrrole-1,4-dione} (PTT-DTDPP) was synthesized by the Stilln coupling reaction. The polymer shows a broad absorption in visible and near infrared region and displays suitable HOMO/LUMO energy levels for marching with those of PCBM acceptor. The photovoltaic properties of the polymer were studied by bulk heterojunction solar cell devices using PTT-DTDPP as donor and PC71BM as acceptor. The power conversion efficiency of device achieved 1.60% under the illumination of AM1.5 G, 100 mW/cm(2). (C) 2011 Elsevier B.V. All rights reserved.

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