Article
Multidisciplinary Sciences
William M. Ringle, Tomas Gallareta Negron, Rossana May Ciau, Kenneth E. Seligson, Juan C. Fernandez-Diaz, David Ortegon Zapata
Summary: The use of lidar technology has greatly impacted settlement and landscape archaeology, particularly in the Maya lowlands. This study focuses on the Puuc region of Yucatan, Mexico, revealing insights into settlement distribution and population estimates. The region is one of the most densely settled areas within the Maya lowlands, lacking defensive features and relying on various water storage technologies.
Article
Chemistry, Physical
T. N. Cruz-May, A. Herrera, J. Rodriguez-Hernandez, Mario Basulto-Martinez, Juan P. Flores-Tapia, P. Quintana
Summary: Urinary lithiasis is a global disease, and the study found that oxalates and phosphates are the predominant constituents in kidney stones among the Maya population in Yucatan. Prophylactic measures should focus on these main compounds.
JOURNAL OF MOLECULAR STRUCTURE
(2021)
Article
Geochemistry & Geophysics
A. C. Da Silva, A. Triantafyllou, N. Delmelle
Summary: The use of portable Energy Dispersive X-Ray Fluorescence (pXRF) spectrometers has greatly increased in environmental, geological, and archaeological field research in the past decade. However, generating reliable geochemical data with a pXRF is challenging and requires the development of dedicated and matrix-matched empirical calibrations. Many research papers still use unquantified pXRF data or unsuitable built-in calibrations, and interpret chemical concentrations without checking the limit of quantification. In this paper, a general workflow for building an empirical calibration model is presented, and the geochemical results obtained from thirty-two calibration models built using different software are compared.
Article
Materials Science, Multidisciplinary
Luisa Straulino-Mainou, Teresa Pi-Puig, Becket Lailson-Tinoco, Karla Castro-Chong, Maria Fernanda Urbina-Lemus, Pablo Escalante-Gonzalbo, Sergey Sedov, Aban Flores-Moran
Summary: This study used XRF, SEM and XRD to analyze blue samples found in convents across Puebla, Tlaxcala and Morelos, confirming that these wall paintings were made with Maya blue, a pre-Hispanic pigment.
Article
Spectroscopy
Jacopo Orsilli, Marco Martini, Anna Galli
Summary: With the Angle Resolved XRF (AR-XRF) technique, the intensity of the characteristic elemental fluorescence signal of a sample can be affected by the geometry of analysis at different angles of detection and irradiation. This technique has been proven to be useful in analyzing metallic bilayer samples. In this paper, AR-XRF was applied to study a glazed ceramic from Puebla, Mexico, in the field of Cultural Heritage. The analysis of the decorations revealed the limitations of the technique, especially for thick and diffused layers, highlighting the importance of prior knowledge in retrieving structural information in complex systems with numerous variables.
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
(2023)
Article
Archaeology
Jeff Theys, John Webb
Summary: The study demonstrated that hornfels undergo significant chemical changes during weathering, resulting in substantial loss of elements such as Mg, Na, and Ca. The dominant component in the weathered hornfels is kaolinite. Analyses of trace elements can effectively differentiate hornfels artifacts from different sites in southeastern Tasmania, even with the effects of weathering.
GEOARCHAEOLOGY-AN INTERNATIONAL JOURNAL
(2022)
Article
Geochemistry & Geophysics
Shuguang Zhou, Jinlin Wang, Yong Bai, Wei Wang, Shanshan Wang
Summary: This study focused on applying portable X-ray fluorescence spectrometry (pXRF) to determine the elemental content of sediment samples and investigate its use in mineral exploration. Various factors influencing the results of pXRF analysis were analyzed. The results showed that pXRF could detect more than 30 elements in stream sediments, and the combination of pXRF analysis and laboratory analysis is effective for establishing a multi-element content inference equation, providing valuable support for mineral resource exploration.
Article
Environmental Sciences
Xinxin Zhang, Aaron J. Specht, Ellen Wells, Marc G. Weisskopf, Jennifer Weuve, Linda H. Nie
Summary: The study compared bone lead concentrations measured by portable XRF and KXRF devices in different age groups and occupational exposure history. Results showed a significant correlation between measurements from the two devices, with portable XRF measurements affected by scan time and soft tissue thickness but still comparable in quantifying bone lead concentrations.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)
Article
Chemistry, Inorganic & Nuclear
David E. B. Fleming, Samantha L. Crook, Colby T. Evans, Michel N. Nader, Manuel Atia, Jason M. T. Hicks, Ellen Sweeney, Christopher R. McFarlane, Jong Sung Kim, Erin Keltie, Anil Adisesh
Summary: The study evaluated arsenic concentrations in toenail clippings of Atlantic Canadian participants using a portable XRF approach, with high correlation coefficients up to 0.89 compared to ICP-MS measurements under certain conditions. The XRF method demonstrated promising sensitivity and specificity in assessing arsenic concentration in toenail clippings.
APPLIED RADIATION AND ISOTOPES
(2021)
Article
Spectroscopy
S. Porcinai, A. Cagnini, M. Galeotti, M. Ferretti
Summary: The investigation of alloy composition is crucial for studying archaeological and historical metal artifacts. Portable X-ray fluorescence is commonly used for non-invasive alloy analysis, but its quantitative results are not reliable when the metal surface is covered by corrosion or patination layers. In such cases, micro samples representative of the bulk alloy need to be taken. This study evaluates and compares the accuracy and precision of X-ray fluorescence quantitative data obtained from surface and shavings samples, and suggests that a suitable calibration model using certified reference materials should be applied. Repeatability tests show consistent results within 5%, with slightly higher uncertainties for shavings compared to surface measurements. Two case studies of archaeological and Renaissance bronze artifacts are also discussed.
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
(2023)
Article
Food Science & Technology
Nondita Malo, Debashish Mazumder, Jagoda Crawford, Patricia Gadd, Karthik Gopi, Neil Saintilan, Jesmond Sammut
Summary: Seafood elemental profiling (SEP) is a useful method for analyzing elements in seafood to determine their origin and quality. Traditional methods have limitations, but portable handheld X-ray fluorescence (pXRF) analysis shows promise as an alternative. This study demonstrates the potential of pXRF for industry-level analysis, but further improvements are needed for instrument calibration to account for factors that can affect the results.
Article
Geochemistry & Geophysics
Ross D. Knight, Bruce A. Kjarsgaard, Hazen A. J. Russell
Summary: The paper introduces an analytical protocol for examining Quaternary glaciogenic sediments using a portable spectrometer, which outlines best practices for sample preparation, analysis, and data cleaning. Through analysis of over 4000 geological samples and around 9000 Certified and Standard Reference Materials, it was found that pXRF technology can provide geochemical data at a fraction of the cost of traditional laboratory methods while delivering comparable results.
APPLIED GEOCHEMISTRY
(2021)
Article
Environmental Sciences
Samantha Krause, Timothy P. Beach, Sheryl Luzzadder-Beach, Duncan Cook, Steven R. Bozarth, Fred Valdez Jr, Thomas H. Guderjan
Summary: Research demonstrates that ancient Maya farmers managed riparian wetlands in northwestern Belize to a much greater spatial extent than previous estimates. They transformed the wetland from a natural to an agricultural system as early as around 2100 years ago, and their activities such as constructing berms, clearing, and canal construction coincided with population growth and urban construction-related ecological changes.
Article
Environmental Sciences
Nele Delbecque, Eric Van Ranst, Stefaan Dondeyne, Abdul M. Mouazen, Pieter Vermeir, Ann Verdoodt
Summary: This study investigates the differences in anthropogenic, lithogenic and pedological contributions in urban soils using volume-specific magnetic susceptibility and geochemical soil properties. The results show that volume-specific magnetic susceptibility can predict heavy metal enrichment and provide insights into the nature of anthropogenic influence, particle size distribution, lithology, and pedology in urban soils.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Spectroscopy
Brendan J. Orenstein, David T. Flannery, Lachlan W. Casey, William T. Elam, Christopher M. Heirwegh, Michael W. M. Jones
Summary: A new automated method based on statistical threshold is proposed to remove diffraction peaks from multiple-detector spectra, which retains more fluorescence data and increases the information content available for diffraction-free elemental quantification and mapping. The proposed method does not require an increase in dwell times or additional data to be collected to compensate for the removed fluorescence data.
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
(2023)