期刊
SOFT MATTER
卷 8, 期 10, 页码 2950-2955出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2sm07231a
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资金
- World Class University (WCU) [R32-2008-000-20003-0]
- NRF from Ministry of Education, Science, S. Korea [2011-0003903]
- NRF [2011-0001211]
- Korean Government (MEST)
A tetrazole-based ligand forms a supramolecular gel in the presence of transition metal ions, particularly Zn2+, Cu2+ and Co2+. The gels have been characterized by SEM, TEM, fluorescence spectroscopy, rheometry and fluorescence microscopy. The polymer exhibits a strong fluorescence enhancement upon gel formation. According to DFT calculations, one of Zn2+ is bound to 4 tetrazole moieties and 2 solvent molecules by octahedral structure. The Zn2+-induced gelation does not strongly depend on anions. The Zn2+-tetrazole ligand gel shows a spherical structure with 20-50 nm diameter. The rheological properties of the Zn2+-tetrazole ligand gel were strongly dependent on the concentration of Zn2+.
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