Article
Materials Science, Ceramics
Aline R. Passos, Sandra H. Pulcinelli, Celso Santilli
Summary: In this study, in situ techniques were used to investigate the hierarchical porous structure of alumina monoliths formed by the combined processes of sol-gel transition and spinodal phase separation. The addition of low molecular weight poly(ethylene oxide) (PEO) influenced the phase separation and porous structure formation during gelation of alumina. Specifically, PEO addition led to a transition in the spinodal decomposition stage, ultimately impacting the formation of porous structures in the alumina monoliths.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2022)
Article
Multidisciplinary Sciences
Rebecca K. Lindsey, Nir Goldman, Laurence E. Fried, Sorin Bastea
Summary: This study employs machine-learned reactive interatomic potentials to perform large-scale simulations of nanocarbon formation from prototypical shocked C/O-containing precursor, providing direct insight into the carbon condensation process and suggesting the potential use of simulations as design tools for new nanomaterials.
NATURE COMMUNICATIONS
(2022)
Article
Materials Science, Multidisciplinary
Li He, Dongfang Wang, Tiantian Ma, Jinliang Song, Yongkang Wu, Yucheng Li, Yongfeng Deng, Guoping Zhang
Summary: An experimental study on the processing and mechanical properties of graphene-reinforced superhydrophobic siloxane was conducted. The results show that adding 0.9 wt% graphene can increase the strength of the superhydrophobic composites to 34 MPa. Ultrasonication improves microscale dispersion but decreases the composite's strength, while curing at elevated temperatures leads to a more uniform distribution of graphene but induces thermal cavitation and bubble formation.
MATERIALS & DESIGN
(2023)
Article
Multidisciplinary Sciences
Michio Tateno, Hajime Tanaka
Summary: The study reveals that in gas-liquid-type phase separation, network coarsening is controlled by mechanical relaxation, following a universally valid coarsening law. This research is significant for fundamental physical understanding of network-forming phase separation.
NATURE COMMUNICATIONS
(2021)
Article
Polymer Science
Peter Rodic, Barbara Kapun, Ingrid Milosev
Summary: This study presents a new PEHA-SS corrosion protective coating for lightweight cast aluminium alloy AlSi7Mg0.3, achieving durable corrosion protection. The coating was synthesized using organic monomers and inorganic silanes, and its synthesis process was monitored using real-time infrared spectroscopy. Various techniques were used to characterize the coating and evaluate its corrosion resistance. Electrochemical impedance spectroscopy was employed to assess the corrosion resistance of the coated alloy in sodium chloride solutions.
Article
Engineering, Chemical
Agustin Forchetti Casarino, Santiago Andres Bortolato, Diana Alejandra Estenoz, Marisa Elisabet Sponton
Summary: The novel polybenzoxazine/polysilsesquioxane nanocomposites exhibit uniform and reproducible structural morphology, high thermal stability, and T-g value, synthesized by polysilsesquioxane and silane-based benzoxazine monomer. The study found that adjusting the experimental conditions of the sol-gel process for polysilsesquioxane can impact material characteristics, particularly the concentration of silanol units and selective condensation.
POLYMER ENGINEERING AND SCIENCE
(2021)
Article
Materials Science, Multidisciplinary
Gen Hayase
Summary: The increasing need for outdoor remote sensing using drones and robots and reducing the urban heat island effect has created a demand for highly reflective materials suitable for outdoor use. The development of flexible macroporous silicon monoliths that exhibit high diffuse reflectance has been successful. These materials were prepared using a two-step catalyzed surfactant-free sol-gel process and demonstrated total reflectance of over 97.5% in the 400-1100nm wavelength range. The high reflectance, along with other favorable properties, makes the macroporous silicone monoliths promising for outdoor thermal management applications.
ACS APPLIED POLYMER MATERIALS
(2023)
Article
Materials Science, Ceramics
Chang Zou, Xingzhong Guo, Fan Wang, Rui Tian, Yang Hou, Fu Liu, Hui Yang
Summary: Three-dimensional macroporous heterostructural Ni-Fe hydroxides with different mole ratio were prepared and investigated for their overall water splitting electrocatalytic activity. The materials exhibited outstanding electrocatalytic performance and stability, which could be attributed to their unique macroporous structure and strong synergistic effect between Ni-Fe hydroxides.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2022)
Article
Materials Science, Ceramics
Daisuke Kino, Kenji Okada, Yasuaki Tokudome, Masahide Takahashi, Luca Malfatti, Plinio Innocenzi
Summary: Controlling the steric effects around silanol groups in the intermediate oligomers allows modulation of the crosslink density of siloxane skeletons, thereby tuning the structure and chemical properties of the resultant siloxane materials.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2021)
Article
Multidisciplinary Sciences
Zezhong Xiang, Jin Li, Peng You, Linbo Han, Mingxia Qiu, Gengliang Chen, Yu He, Songqiang Liang, Boyuan Xiang, Yaorong Su, Hongyu An, Shunpu Li
Summary: Regular patterns can be spontaneously generated in uphill-diffusion solution systems without a chemical reaction process, as observed through in-situ and ex-situ observations. These patterns can be condensed onto substrates to form structured micro/nanomaterials and have potential applications. This finding is important for understanding pattern formation in nature.
NATURE COMMUNICATIONS
(2022)
Review
Chemistry, Physical
Ana C. Marques, Mario Vale
Summary: The synthesis of macroporous and hierarchically macro/mesoporous materials has made significant advancements through the sol-gel technique, with optimized methodologies using alkoxides or metal-salts, and incorporating grafting or immobilization of specific species for technological applications such as photocatalysis. This review discusses the evolution of material composition and synthesis strategies, aiming to inspire new improvements and breakthroughs in the realm of porous materials.
Article
Materials Science, Coatings & Films
Reza Gharibi, Sara Safavian, Mohammad Bagher Teimouri
Summary: This study focused on designing bioactive and biocidal coatings to improve the performance of implanted medical devices affected by microbial contamination. The fabricated non-leaching biocidal polyurethanesiloxane coating demonstrated excellent adhesion strength, hardness, flexibility, impact resistance, and showed superior contact-active biocidal activity against both Gram-negative and Gram-positive bacteria. Furthermore, the coating exhibited favorable cell adhesion, proliferation, and cytocompatibility.
SURFACE & COATINGS TECHNOLOGY
(2022)
Article
Chemistry, Physical
Lizeth Martinez, Godofredo Garcia-Salgado, Francisco Morales-Morales, Bernardo Campillo, Angelica G. Hernandez, Tangirala V. K. Karthik, Maria R. Jimenez-Vivanco, Jose Campos-Alvarez
Summary: This study developed hybrid nanostructures based on ZnO films deposited on macroporous silicon substrates using sol-gel spin coating and ultrasonic spray pyrolysis techniques. The results showed the beneficial influence of macroporous silicon on the structural properties of ZnO films, with nano-morphologies potentially useful for highly sensitive gas sensors.
Article
Chemistry, Physical
Peter Adam, Marius Horvath, Katalin Sinko
Summary: The main aim of this research was to develop a new low-cost synthesis route for producing ultralight Al2O3 cryogel - fiber composite materials for high temperature insulation. The Al2O3 fibers act as the matrix in these composites instead of the typical reinforcement phase. The synthesis of precursor systems involves sol-gel chemistry, with the same starting materials used for both types of porous Al2O3 systems. The composite systems were characterized using various tests and analysis techniques.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Review
Materials Science, Ceramics
Yun Hyeok Kim, Injun Lee, Hyunhwan Lee, Seung-Mo Kang, Yung Lee, Seungwan Kim, Byeong-Soo Bae
Summary: This paper introduces a new type of material called sol-gel-derived siloxane hybrid material (Hybrimer), which exhibits the flexibility and mechanical toughness of plastics, as well as the thermal and mechanical resistance of glass. By controlling organic functional groups and the sol-gel reaction and polymerization steps, the properties of the material can be easily optimized. It can be applied in various display and optoelectronic applications such as patterning, passivation, glass-fabric reinforced film, and color conversion films.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2023)
Article
Materials Science, Ceramics
George Hasegawa, Kazuyoshi Kanamori, Kazuki Nakanishi
Summary: Porous nonoxide ceramics have shown remarkable progress in synthesis and applications due to their unique characteristics. The use of preceramic polymer route and one-pot sol-gel process allows for the control of material shape and microstructures.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Taehee Kim, Sanjib Baran Roy, Sunil Moon, SangHyuk Yoo, Haryeong Choi, Vinayak G. Parale, Younghun Kim, Jihun Lee, Seong Chan Jun, Keonwook Kang, Seung-Hyun Chun, Kazuyoshi Kanamori, Hyung-Ho Park
Summary: In this study, a high-performance electrochemical hydrogen evolution reaction (HER) catalyst was developed by combining F-doped tin(IV) oxide (F-SnO2) aerogel with Pt catalyst. The as-synthesized hybrid F-SnO2@Pt exhibited efficient HER activity, a large specific surface area, high porosity, and excellent robustness.
Article
Agronomy
Ryosuke Nakamura, Gaku Amada, Hirofumi Kajino, Kei Morisato, Kazuyoshi Kanamori, Motohiro Hasegawa
Summary: This study investigated the impact of leaf silicious trichomes on leaf mass loss by soil meso- and macrofauna. The results showed that despite having rich nutrient quality, Moraceae tree species with higher trichome densities experienced slower leaf decomposition in the presence of large decomposers. The presence of silicious trichomes on leaves may have a suppressive effect on decomposition by larger decomposers.
Article
Polymer Science
Hoan Ngoc Doan, Shotaro Tagami, Phu Phong Vo, Masaki Negoro, Wataru Sakai, Naoto Tsutsumi, Kazuyoshi Kanamori, Kenji Kinashi
Summary: In this study, cross-linked porous polyimide fibers were prepared using centrifugal spinning, and the influence of different parameters was evaluated. The obtained fibers exhibited low thermal conductivity, high thermal stability, and flexibility.
EUROPEAN POLYMER JOURNAL
(2022)
Article
Materials Science, Ceramics
Ioannis Michaloudis, Kazuyoshi Kanamori, Ifigenia Pappa, Nikolaos Kehagias
Summary: Micro/nano structuring in distinct chemical compositions has shown its value in modern applications and products, especially in the visual arts. Silica aerogel, as an example of such a nanostructure, has been used in high jewelry design, resembling a piece of sky. Collaborations between artists and scientists have resulted in developments in science, technology, design, fashion, and art industries, merging new technologies, functional materials, manufacturing processes with visual arts.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2023)
Article
Nanoscience & Nanotechnology
Yosuke Hara, Rikuo Shigetake, Kazuki Nakanishi, Kazuyoshi Kanamori, Ken Sakaushi
Summary: The internal spacing of electrodes is crucial for controlling electron transfer phenomena. However, the disordered porous structures of electrodes often hinder the observation of microscopic effects and impede the development of modern electrochemical theories. In this study, the authors developed a new synthetic strategy to create controlled hierarchically porous all-oxide monolithic electrodes with oxide-oxide heterojunctions. By using these model electrodes, the authors demonstrated unconventional oxide-oxide heterojunction effects and improved reversible lithium-ion coupled electron transfer properties.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Editorial Material
Materials Science, Ceramics
Kazuki Nakanishi, Hiromitsu Kozuka
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2022)
Article
Biochemical Research Methods
Tomoka Yoshii, Akihiro Sakama, Kazuyoshi Kanamori, Kazuki Nakanishi, Hiroaki Imai, Daniel Citterio, Yuki Hiruta
Summary: This article presents a study on an alkali-resistant reversed-phase packing material prepared from eggshells modified with an amphiphilic copolymer for purification of basic drugs. The material showed good selectivity and retention performance, making it effective for purifying alkaline drugs and acid-sensitive compounds.
JOURNAL OF CHROMATOGRAPHY A
(2023)
Article
Materials Science, Ceramics
Ioannis Michaloudis, Konstantina Papachristopoulou, Farah El-Zein, Szymon Pruciak, Pagona-Noni Maravelaki, Kazuyoshi Kanamori
Summary: Silica aerogel, with its transparent and low refractive index properties, has become a novel material for visual arts called aer()sculptures. The first author's artwork "M(Other)" proposes using silica aerogel to restore cultural heritage, replacing traditional plaster of Paris techniques. The use of translucent material to restore missing parts adds a new aesthetic quality, such as ethereal images of missing arms on a Parthenon Caryatid, which cannot be achieved using plaster of Paris restoration technique.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2023)
Article
Materials Science, Multidisciplinary
Khanh-Van Thi Khuat, Hoan Ngoc Doan, Phu Phong Vo, Masaki Negoro, Kenji Kinashi, Kazuyoshi Kanamori, Wataru Sakai, Naoto Tsutsumi
Summary: In this study, nanofibrous aerogels (NFAs) were constructed using electrospun 3-aminopropyltriethoxysilane-grafted polyimide (PI@APTES) nanofibers, resulting in improved properties and functionalities. The obtained polyimide nanofibrous aerogels (PiNFAs) had a hierarchically three-dimensional (3D) microporous structure, high porosity, tunable densities, solvent resistance, superhydrophobicity, low thermal conductivity, and mechanical stability. These PiNFAs are promising candidates for potential applications in thermal insulation, lightweight construction, filtration, and sensors.
ACS APPLIED POLYMER MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Jiangfeng Lu, Yukihiro Yoshida, Kazuyoshi Kanamori, Hiroshi Kitagawa
Summary: This study successfully fabricated highly flexible free-standing CP membranes with a high surface-to-volume ratio, which is beneficial for enhanced performance in fuel cells and hydrogen sensors. The mechanical flexibility was evaluated by bending and tensile tests, and it was found that the membrane maintained in-plane proton conductivity even under applied bending stress.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Yuji Sato, Kazuyoshi Kanamori, Kazuki Nakanishi
Summary: Hierarchically porous niobium(V) oxide monoliths with controlled macroporous and mesoporous structures were prepared through sol-gel process and subsequent heat treatment. The crystal structures and mesoporous characteristics were modified through heat treatment, while the macroporous structures were controlled by starting composition. The formation of different niobium-containing complex oxides was also examined by incorporating alkali metals postgelation treatments.
CHEMISTRY OF MATERIALS
(2023)
Review
Materials Science, Ceramics
Koichi Kajihara, Kazuyoshi Kanamori, Atsushi Shimojima
Summary: The sol-gel process is defined as the formation of a network from a solution, gradually transforming the liquid precursor into a sol, then a gel, and finally a dry network. This article provides a brief review of recent topics on sol-gel processing, including the synthesis and applications of nonporous glasses and ceramics, aerogels, and mesoporous and/or nanostructured materials, focusing on reaction mechanisms, process optimization, and functionalities.
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN
(2022)
Article
Chemistry, Physical
Yiping Yin, Zhe Wang, Hua Zou
Summary: This study presents a novel method for preparing dimpled polymer-silica nanocomposite particles using interfacial swelling-based seeded polymerization. The optimized conditions allow for a relatively high percentage of dimpled particles to be achieved.
Article
Chemistry, Physical
Brenden D. Hoehn, Elizabeth A. Kellstedt, Marc A. Hillmyer
Summary: Porous materials with nanometer-scale pores have important applications as nanoporous membranes. In this study, ABA triblock copolymers were used as precursors to produce nanoporous polymeric membranes (NPMs) in thin film form by degrading the end blocks. Polycyclooctene (PCOE) NPMs with tunable pore sizes were successfully prepared using solvent casting technique. Oxygen plasma etching was employed to improve the surface porosity and hydrophilicity of the membranes. This study provides a straightforward method to produce tough NPMs with high porosity and hydrophilic surface properties.
Article
Chemistry, Physical
Vladislav S. Petrovskii, Stepan I. Zholudev, Igor I. Potemkin
Summary: This article investigates the behavior of linear and ring polypeptide chains in aqueous solution and explores the properties of the complexes formed by these chains with oppositely charged surfactants. The results demonstrate that the complexes of linear supercharged unfolded polypeptides and the corresponding surfactants exhibit impressive adhesive properties.
Article
Chemistry, Physical
Merve Cevik, Serkan Dikici
Summary: Cardiovascular diseases are a leading cause of death globally, and vascular grafts are a promising treatment option. This study focuses on tissue-engineered vascular grafts (TEVGs) using decellularized parsley stems as a potential biomaterial. The decellularized parsley stems showed suitable properties for TEVGs, providing a suitable environment for human endothelial cells to form a pseudo endothelium. This study showcases the potential of using parsley stems for TEVGs.
Article
Chemistry, Physical
Gustavo A. Vasquez-Montoya, Tadej Emersic, Noe Atzin, Antonio Tavera-Vazquez, Ali Mozaffari, Rui Zhang, Orlando Guzman, Alexey Snezhko, Paul F. Nealey, Juan J. de Pablo
Summary: The optical properties of liquid crystals are typically controlled by electric fields. In this study, we investigate the effects of microfluidic flows and acoustic fields on the molecular orientation and optical response of nematic liquid crystals. We identify several previously unknown structures and explain them through calculations and simulations. These findings hold promise for the development of new systems combining sound, flow, and confinement.
Article
Chemistry, Physical
Xinjun Wu, Xin Guan, Shushu Chen, Jiangpeng Jia, Chongyi Chen, Jiawei Zhang, Chuanzhuang Zhao
Summary: This research presents a novel shape memory hydrogel with a remodelable permanent shape and programmable cold-induced shape recovery behavior. The hydrogel is prepared using specific treatment methods to achieve shape fixation by heating and shape recovery by cooling. Additionally, deformable devices can be obtained by assembling hydrogel blocks with different concentrations.
Article
Chemistry, Physical
Rebecca Hengsbach, Gerhard Fink, Ulrich Simon
Summary: This study examines the properties of DNA functionalized pNipmam microgels and pure pNipmam microgels at different concentrations of sodium chloride and in PBS solutions using temperature dependent H-1-NMR measurements. The results show that DNA modification affects the volume phase transition temperature and the addition of salt and PBS further enhances this effect.
Article
Chemistry, Physical
Ningyi Li, Junhong Li, Lijingting Qing, Shicheng Ma, Yao Li, Baohui Li
Summary: This paper investigates the self-assembly behavior of colloids with competing interactions under spherical confinement and finds that different ordered structures can be formed under different sized spherical confinements. Moreover, more perforated structures are formed in smaller spheres.