Article
Biochemistry & Molecular Biology
Daniela Millan, Felipe Gonzalez-Turen, Josei Perez-Recabarren, Christopher Gonzalez-Ponce, Marcos Caroli Rezende, Andre M. Da Costa Lopes
Summary: In this study, different organic solvents and their aqueous mixtures were used for lignin extraction from Pinus radiata sawdust. The results showed that adding a small amount of water could increase the extraction yield, but the yield decreased as the water content increased. The purity of the extracted lignins was analyzed, and it was found that the solute-solvent interactions had a significant influence on the extraction effectiveness.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2022)
Article
Energy & Fuels
Dong Zhang, Ying Huang, Kazuyuki Oshita, Masaki Takaoka, Meng Ying, Zifei Sun, Changdong Sheng
Summary: The study successfully recovered oil from oily sludge using liquefied dimethyl ether (DME) extraction, with the DME/sludge ratio, extraction time, and stirring speed affecting the oil recovery ratio. Compared to traditional methods, DME extraction yielded a higher recovery rate and the recovered oil contained more beneficial components.
Article
Chemistry, Physical
Mohammed Abobakr Al-Maari, Hanee F. Hizaddin, Adeeb Hayyan, Mohamed Kamel Hadj-Kali
Summary: Deep eutectic solvents (DESs) have been recognized as eco-friendly alternatives to conventional solvents. However, reliable methods for selecting task-specific DESs are limited. Using COSMO-RS, 126 DESs were screened based on their solubility capacity to estimate their potential use as plant seed oil extractants. The results showed that DESs with higher linoleic acid solubility had lower solubility for protein, and the similarity of DESs to both linoleic acid and protein was compared through sigma-profiles. DESs with high linoleic acid solubility could be used as individual solvents, while DESs with high protein solubility could be used as co-solvents with organic solvents.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Multidisciplinary
Jinjian Hou, Mingyao Cao, Keyi Duan, Lingyu Sun, Shuanglong Lin, Ming Zhang, Wei Li
Summary: In this study, Span 80 was used to enhance the solvent extraction process and its mechanism was explored. The results indicated that different solvents had different effects on oil recovery, with toluene showing the highest recovery and n-heptane showing the lowest. Complex solvents improved oil recovery and decreased viscosity. The C/H ratio was correlated with oil recovery, with an increase in asphaltene and resin content leading to a higher C/H ratio. Span 80 increased the C/H ratio, reduced viscosity, and minimized solvent loss.
ARABIAN JOURNAL OF CHEMISTRY
(2022)
Article
Energy & Fuels
Tatiana Farane Mein, Andre Luiz Veiga Gimenes, Eduardo Mario Dias, Maria Lidia Rebello Pinho Dias Scoton, Miguel Edgar Morales Udaeta
Summary: This study aims to analyze disturbances in the environment caused by anthropic activities in the oil and gas extraction sector, focusing on environmental vulnerability. The research found variations in the criteria and methodologies of EIAs between stages, making it impossible to define a single vulnerability index for the pre-salt venture.
Article
Thermodynamics
Wenyang Fan, Chunliang Ge, Delong Ding, Liping Deng, Jun Gao, Dongmei Xu
Summary: The separation of sulfides from fuel oil using sulfolane as the organic solvent was studied in this paper, highlighting its importance for environmental protection. The liquid-liquid equilibrium data for the mixtures of n-heptane with thiophene/2-methylthiophene and sulfolane were measured at different temperatures and pressures. The extraction performance of sulfolane was evaluated and compared with other solvents, demonstrating its superior performance for thiophene. Quantum chemical calculation was employed to understand the separation mechanism of sulfolane. Finally, the NRTL and UNIQUAC models were used to fit the experimental data and the mixed surface analysis method was applied to verify the binary interaction parameters.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2023)
Article
Energy & Fuels
Abigail A. Manto, Ian Felix T. Ramirez, Louella M. Arnado, Cherelyn T. Damiotan, Eljie T. Sumalpong, Alexander L. Ido, Renato O. Arazo
Summary: This study successfully extracted oil from bitaog seeds using ultrasonic-assisted solvent extraction, with a high yield of unsaturated fatty acids indicating its potential for biodiesel production. The method proved to be more efficient than traditional extraction methods, highlighting the effectiveness of ultrasonication.
BIOMASS CONVERSION AND BIOREFINERY
(2022)
Article
Engineering, Chemical
Junyan Wang, Xingang Li, Guoqiang Ma, Hong Sui, Lin He, Runzhe Liu
Summary: A gas bubbling method was proposed to remove and recover residual solvents from extracted gangue in unconventional oil ore solvent extraction processes. The method showed high efficiency in solvent removal and recovery, with insights provided for similar situations in oil or solvent removal and recovery from solids.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Engineering, Chemical
Qi Cao, Yu Qian, Junjie Li, Siyu Yang
Summary: Petrochemical, coal chemical, and metal smelting industries produce oily wastewater with surfactant-stabilized oil microdroplets, which are difficult to treat. This study analyzes the mechanism and factors affecting the extraction efficiency of surfactant-stabilized oil microdroplets using solvent extraction. The results show that the extraction is accomplished by the mass transfer of extractant from the exterior to the interior of the oil microdroplets and the rise of extractant-containing oil droplets in the aqueous phase. Multistage extraction experiments demonstrate that this solvent extraction technology can treat oily wastewater to discharge standards. Non-polar extractants are considered more suitable due to their regenerability, lower regeneration costs, and better extraction performance.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Jun Woo Park, Min Yong Kim, Soo Ik Im, Kang Seok Go, Nam Sun Nho, Ki Bong Lee
Summary: This study conducted a quantitative analysis to predict the yields of deasphalted oil (DAO) in the solvent deasphalting (SDA) process. The effects of temperature and solvent-to-oil ratio (SOR) on the DAO yield were explained using simple and accurate correlations. The results showed that temperature and SOR have a significant impact on the DAO yield.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2022)
Article
Energy & Fuels
A. O. Oni, I. C. Toro Monsalve, A. Kumar
Summary: Simulation models were developed to assess the performance of solvent-assisted, solvent-electromagnetic heating, and steam-assisted oil sands extraction central processing facilities. The results showed that solvent-assisted and solvent-electromagnetic heating processes performed better than steam-assisted gravity drainage in terms of greenhouse gas emissions.
Article
Engineering, Environmental
Guojia Yu, Dongyu Jin, Fan Zhang, Shichao Tian, Zhiyong Zhou, Zhongqi Ren
Summary: This study used novel porous liquids to achieve the desulfurization process of fuel oil, and improved the desulfurization performance through electrostatic interaction and microporous structure. The experimental results showed that the porous liquids have dual functions of extraction and adsorption. This new type of solvent has great potential for application and research value.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Chemical
Chenhua Shu, Feng Zhu, Xianhong Zhu, Faying Lai
Summary: The study introduced a novel method for fuel oil desulphurization by using deep eutectic solvent (DES) and sodium borohydride (NaBH4), which achieved efficient sulphur removal by synergistic action of DES and NaBH4, reaching a desulphurization efficiency of over 96% for dibenzothiophene, showing promising potential for various applications.
CANADIAN JOURNAL OF CHEMICAL ENGINEERING
(2021)
Article
Environmental Sciences
Tao Dong, Zhifei Hao, Yinmin Zhang, Yongfeng Zhang
Summary: Solvent extraction of lignite was used to analyze the chemical structure and the possible source of PAHs. It was found that the extracts contained a high percentage of poly-condensed aromatic compounds, mainly in the form of 2 and 3 rings. The macromolecular structure of lignite was evaluated using multiple analytical techniques. The potential generation of PAHs was comprehensively ascertained through the analysis of the extracts and combustion products.
Article
Engineering, Chemical
Mengmeng Liu, Liqiang Shen, Jianqiang Wang, Yajie Ding, Yong Zhou, Fu Liu
Summary: This study proposes a membrane-based non-dispersive solvent extraction method for continuous separation and recovery of oil from oil-in-water emulsion with high viscosity and concentration. The method utilizes a hydrophobic poly(vinylidene fluoride) (PVDF) nanofibrous membrane to facilitate the transfer of oil from the emulsion side to the solvent side. The recovered oil can easily be obtained by evaporating the solvent, and its water content remains similar to the original sample.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Environmental Sciences
Inna E. Popova, Matthew J. Morra, Sanjai J. Parikh
JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART B-PESTICIDES FOOD CONTAMINANTS AND AGRICULTURAL WASTES
(2019)
Article
Pharmacology & Pharmacy
Emmy Luu, Kevin B. Ita, Matthew J. Morra, Inna E. Popova
CURRENT DRUG DELIVERY
(2018)
Article
Environmental Sciences
Inna E. Popova, Matthew J. Morra
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2020)
Article
Biochemical Research Methods
Inna E. Popova, Matthew J. Morra
Summary: Solanum sisymbriifolium, also known as litchi tomato or sticky nightshade, is a promising feedstock for nematicide production. The plant contains various bioactive compounds, mainly glycoalkaloids, but the specific chemistry is not well understood. High-performance liquid chromatography-mass spectrometry analysis revealed 19 glycoalkaloids in the plant, with five major compounds representing 95% of the total composition, and solamargine being the most abundant.
Article
Chemistry, Applied
Andrea H. Wade, Matthew J. Morra, Brennan Smith, Inna Popova
Summary: This study demonstrates that oilseeds from the Brassicaceae family can serve as a viable source of lecithin with high concentrations of phosphatidylcholine and phosphatidylinositol, as well as potentially novel emulsifying characteristics. The total yields and compositions of lecithin extracted from seeds of Brassica juncea, Sinapis alba, and Brassica napus were quantified and analyzed. The data obtained indicates that mustard seeds can provide non-allergen phospholipids for various applications.
JOURNAL OF FOOD COMPOSITION AND ANALYSIS
(2021)
Article
Plant Sciences
Inna Popova, Belinda Sell, Syamkumar Sivasankara Pillai, Joseph Kuhl, Louise-Marie Dandurand
Summary: Solanum glycoalkaloids in underexploited Solanum species were comprehensively analyzed, and their composition was found to be correlated with biological activity in the defense against pests and pathogens.
Article
Agronomy
Daniel Temmen, John Randall, Inna Popova
Summary: Mustard seed meal extract has a positive impact on soil quality, reducing pesticide pressure and enhancing crop yields, making it a promising organic soil amendment in organic agriculture.
COMMUNICATIONS IN SOIL SCIENCE AND PLANT ANALYSIS
(2023)
Article
Plant Sciences
Prativa Chhetri, L. M. Dandurand, I. Popova
Summary: In this study, it was demonstrated that Sinapis alba seed meal extract or 4-hydroxybenzyl alcohol can enhance the hatch rate of Globodera pallida eggs when exposed to potato root diffusate. Combining Solanum sisymbriifolium with HBA or Sinapis alba SME significantly reduced the egg count, hatch rate, and viability of G. pallida. B. juncea SME alone or with HBA also reduced egg hatch rate, viability, and reproduction of G. pallida.
Article
Engineering, Environmental
Lindsey Smoot, Jason Mellin, Cynthia K. Brinkman, Inna Popova, Erik R. Coats
Summary: This study demonstrates that partial nitritation can be achieved and maintained by adjusting the conditions of nitritation and nitrification, using mixed microbial consortia cultured on real wastewater, leading to effective wastewater treatment with good effluent quality.
Article
Plant Sciences
Bhupendra Bhatta, Louise-Marie Dandurand, Matthew J. Morra, Inna Popova
Summary: In order to control potato pests, alternative strategies such as the use of Brassica juncea seed meal extract and trap crops were investigated. The results showed that the combined application of seed meal extract and trap crops was more effective in reducing hatch and reproduction of potato pests than using each strategy alone.
Article
Agronomy
Daniel Temmen, John Randall, Inna Popova
Summary: The utilization of white mustard seed meal extract as an organic amendment in soil has been shown to enhance the nutritional quality of potatoes by increasing total phenolic content and nitrogen absorption, with minimal impact on the accumulation of anti-nutrients.
Article
Agricultural Engineering
Inna Popova, Dev Shrestha, Matthew Morra
Summary: Oils from Sinapis alba and Brassica juncea can be used for biofuel and biodiesel production. The leftover mustard seed meal can be valorized into biopesticide. Developing a scaled-up process for producing mustard seed meal biopesticides is crucial.
INDUSTRIAL CROPS AND PRODUCTS
(2023)
Article
Chemistry, Multidisciplinary
Anup Tuladhar, Horng-Bin Pan, Inna Popova
Summary: Amidoxime and carboxylate-containing polymer adsorbents derived from acrylic yarn have high adsorption capacity for Pb2+ ions in water. The adsorption process follows pseudo-second-order kinetics and fits the extended Langmuir isotherm model. Thermodynamic studies show endothermic, spontaneous adsorption with increased entropy. Dynamic column adsorption experiments demonstrate the efficiency of the fiber adsorbent in treating lead-contaminated water. However, the selectivity of Pb2+ varies with different competitive metal ions.
Article
Environmental Sciences
Danika Hill, Matthew J. Morra, Thibault Stalder, Sven Jechalke, Eva Top, Anne T. Pollard, Inna Popova
Summary: The study analyzed nine uncomposted manure samples from Idaho dairies and found potential contaminants and valuable nutrients. This is the first study to document the presence of the non-steroidal anti-inflammatory drug flunixin in solid stacked manure from regular dairy operations, as well as the detection of various antibiotics, hormones, and other substances.
JOURNAL OF ENVIRONMENTAL SCIENCES
(2021)
Article
Environmental Sciences
Danika N. Hill, Inna E. Popova, John E. Hammel, Matthew J. Morra
JOURNAL OF ENVIRONMENTAL QUALITY
(2019)