4.7 Article

Facile, size-controlled deposition of highly dispersed gold nanoparticles on nitrogen carbon nanotubes for hydrogen sensing

期刊

SENSORS AND ACTUATORS B-CHEMICAL
卷 160, 期 1, 页码 1034-1042

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2011.09.022

关键词

Nitrogen carbon nanotubes (NCNTs); Gold; Nanoparticles; Hydrogen sensors

资金

  1. Australian Research Council (ARC), Commonwealth of Australi
  2. ARC [DP0988099, DP110105125, LP100200859, LE0989615, LE110100097]
  3. Australian Research Council [LE110100097] Funding Source: Australian Research Council

向作者/读者索取更多资源

Highly dispersed gold nanoparticles (AuNPs) supported on nitrogen-doped multiwalled carbon nanotubes (NCNTs) were synthesized using an electrochemical method. Size of AuNPs and their dispersion profile were tuned in a facile manner by controlling the applied potential and deposition time. The structure of the films was characterized using SEM, HRTEM, XRD and Raman spectroscopy. Electron microscopy revealed that the nanoparticles were deposited homogeneously on the outer surface of the NCNTs in high density. The average dimensions of the AuNPs could be tuned by varying the applied voltage and the duration of the electrochemical process. The XRD patterns confirmed the presence of metallic fcc gold along with disordered graphitic phases. The Raman spectroscopy showed that NCNTs possess 3-5 at.% nitrogen with a heterogeneous distribution profile, which is consistent with nitrogen incorporation in both graphitic and pyridinic moieties within the carbon sp(2) network of disordered NCNTs. SERS enhancement was also observed for AuNPs/NCNTs prepared at 10V/20 min condition. Conductometric gas sensors were developed from the thin films of AuNPs/NCNTs nanocomposites and evaluated towards H-2 gas. The sensors were exposed to different concentrations of H-2 in synthetic air at room temperature. The highest sensitivity of 75% was measured towards 1% H-2 when average size of AuNPs on NCNTs is about 4-6 nm. (C) 2011 Elsevier B.V. All rights reserved.

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