4.7 Article

Optical gas sensing through nanostructured ZnO films with different morphologies

期刊

SENSORS AND ACTUATORS B-CHEMICAL
卷 145, 期 1, 页码 167-173

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2009.11.064

关键词

Zinc oxide; Nanostructures; Sensors; Pulsed laser deposition; Thin films

向作者/读者索取更多资源

We report on nitrogen dioxide (NO2) sensing measurements by means of zinc oxide films presenting different morphologies. The variation in the photoluminescence emission of the films is employed as transduction mechanism to detect the presence of NO2 gas molecules at room temperature. The significant role of film morphology on the sensing properties is presented and possible limits in the use of ZnO nanostructures for NO2 detection at high gas concentration (>20 ppm) and low gas flow (50 ml/min), where a worsening of the sensor response is observed, are discussed. These features are ascribed to a likely incomplete reversibility of the NO2 adsorption process and examined in connection with the mechanisms of interaction between NO2 molecules and ZnO. (C) 2009 Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Materials Science, Multidisciplinary

Wear and Fretting Behavior of Cold Sprayed IN625 Superalloy

Pasquale Daniele Cavaliere, Antonella Rizzo, Daniele Valerini, Laura Capodieci

Summary: The wear and fretting behavior of IN625 cold spray coatings were analyzed, demonstrating that coatings produced under specific conditions can offer improved wear resistance and energy dissipation capabilities. Nanoindentation evaluation revealed an increase in hardness from the surface towards the substrate, leading to enhanced resistance to wear. Scratch tests at increasing loads also showed the coating's ability to resist damage under triaxial stresses.

METALS (2021)

Article Chemistry, Analytical

Nanoplasmonic Biosensing Approach for Endotoxin Detection in Pharmaceutical Field

Adriano Colombelli, Elisabetta Primiceri, Silvia Rizzato, Anna Grazia Monteduro, Giuseppe Maruccio, Roberto Rella, Maria Grazia Manera

Summary: This study successfully realized the sensitive detection of LPS using nanoplasmonic transducers and specific antibodies, offering a solution to endotoxin contamination issues. By demonstrating a linear relationship and achieving a detection limit down to 5 ng/mL, this technology has the potential for application in quality determination of pharmaceutical products.

CHEMOSENSORS (2021)

Review Chemistry, Physical

Critical Raw Materials Saving by Protective Coatings under Extreme Conditions: A Review of Last Trends in Alloys and Coatings for Aerospace Engine Applications

Maria Luisa Grilli, Daniele Valerini, Anca Elena Slobozeanu, Bogdan O. Postolnyi, Sebastian Balos, Antonella Rizzo, Radu Robert Piticescu

Summary: This paper discusses the latest trends in coatings for high temperature alloys in aerospace engines, as well as scenarios for current and future savings of CRMs in alloys and coatings for aerospace engines. The aim is to raise awareness of the CRM issue in alloys and coatings for aerospace, and suggest mitigation measures without providing a comprehensive overview or a turnkey solution.

MATERIALS (2021)

Article Materials Science, Multidisciplinary

Sputter-Deposited Ag Nanoparticles on Electrospun PCL Scaffolds: Morphology, Wettability and Antibacterial Activity

Daniele Valerini, Loredana Tammaro, Roberta Vitali, Gloria Guillot, Antonio Rinaldi

Summary: This study successfully provided strong antibacterial action to electrospun polycaprolactone (PCL) scaffolds by depositing silver (Ag) onto the PCL fibers through sputtering deposition, maintaining the integrity of the fibers' morphology and hydrophobic character. The easy fabrication of these PCL-Ag mats has a wide range of potential applications in biomedical devices, bioremediation, filtration, personal protective equipment, food packaging materials, and more.

COATINGS (2021)

Editorial Material Materials Science, Multidisciplinary

Antibacterial Surfaces, Thin Films, and Nanostructured Coatings

Daniele Valerini

COATINGS (2021)

Correction Metallurgy & Metallurgical Engineering

Fretting Wear and Scratch Resistance of Cold-Sprayed Pure Cu and Ti (vol Jul, 10.1007/s13632-021-00758-2, 2021)

Rodolpho F. Vaz, Alessio Silvello, Pasquale D. Cavaliere, Sergi Dosta, Irene G. Cano, Laura Capodieci, Antonella Rizzo, Daniele Valerini

METALLOGRAPHY MICROSTRUCTURE AND ANALYSIS (2021)

Article Metallurgy & Metallurgical Engineering

Fretting Wear and Scratch Resistance of Cold-Sprayed Pure Cu and Ti

Rodolpho F. Vaz, Alessio Silvello, Pasquale D. Cavaliere, Sergi Dosta, Irene G. Cano

Summary: The paper investigates the fretting and wear behavior of pure copper and pure titanium coatings achieved through cold spray, finding that materials with low porosity and high strength exhibit high resistance to wear damaging. The hardness of the coatings varies based on distance from the substrate and thickness, influencing the response to wear damaging. Coatings with greater thickness demonstrate better wear resistance due to deformation hardening, but also exhibit brittle fracture at higher loads.

METALLOGRAPHY MICROSTRUCTURE AND ANALYSIS (2021)

Article Physics, Applied

Magnetophotonics for sensing and magnetometry toward industrial applications

Conrad Rizal, Maria Grazia Manera, Daria O. Ignatyeva, Jorge R. Mejia-Salazar, Roberto Rella, Vladimir I. Belotelov, Francesco Pineider, Nicolo Maccaferri

Summary: Magnetic nanostructures with different optical modes have potential for magnetometry and refractive index probing, but compact devices for industrial application are needed. Emerging trends focus on innovative sensors that can manipulate optical properties using an externally applied magnetic field. Recent advances also explore the use of all-dielectric platforms to overcome losses inherent to metallic components.

JOURNAL OF APPLIED PHYSICS (2021)

Article Materials Science, Multidisciplinary

A Comparative Study of the Mechanical and Tribological Properties of Thin Al2O3 Coatings Fabricated by Atomic Layer Deposition and Radio Frequency Sputtering

Maria Luisa Grilli, Daniele Valerini, Antonella Rizzo, Mehmet Yilmaz, Chen Song, Guohang Hu, Alexey Mikhaylov, Rosa Chierchia, Antonio Rinaldi

Summary: The study deposited thin Al2O3 films (150 nm thick) on Si substrates using ALD and sputtering, followed by annealing at 900 degrees C for 90 min in N-2 atmosphere. The annealed coatings exhibited higher hardness, with the ALD coating showing the highest hardness (18.8 GPa), indicating clear trends of stiffening and hardening associated with different processes and postprocessing methods.

PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE (2022)

Article Chemistry, Multidisciplinary

Shape Modulation of Plasmonic Nanostructures by Unconventional Lithographic Technique

Adriano Colombelli, Daniela Lospinoso, Roberto Rella, Maria Grazia Manera

Summary: Conventional nano-sphere lithography techniques have been extended to the fabrication of highly periodic arrays of sub-wavelength nanoholes in a thin metal film. The investigated nano-structured materials exhibit interesting plasmonic properties which can be precisely modulated in a desired optical spectral region.

NANOMATERIALS (2022)

Article Chemistry, Multidisciplinary

Self-Assembled Metal Nanohole Arrays with Tunable Plasmonic Properties for SERS Single-Molecule Detection

Daniela Lospinoso, Adriano Colombelli, Mauro Lomascolo, Roberto Rella, Maria Grazia Manera

Summary: Arrays of metal nano-holes have great potential for applications in nano-photonics and optoelectronics. By adjusting the size and composition of the holes, the electromagnetic field distribution can be modulated, leading to hotspot excitations and enhancing Raman spectroscopy.

NANOMATERIALS (2022)

Article Engineering, Biomedical

Modal analysis of novel coronavirus (SARS COV-2) using finite element methodology

Caaisha Warsame, Daniele Valerini, Inigo Llavori, Asa H. Barber, Saurav Goel

Summary: The research proposes an engineering method using resonant frequencies to denature SARS-CoV-2. Through modal analysis, it was found that the natural frequency of the virus ranges from 88 to 125 MHz, which opens up new avenues for developing medical solutions to combat future pandemics.

JOURNAL OF THE MECHANICAL BEHAVIOR OF BIOMEDICAL MATERIALS (2022)

Article Chemistry, Multidisciplinary

Design and Manufacturing of Antibacterial Electrospun Polysulfone Membranes Functionalized by Ag Nanocoating via Magnetron Sputtering

Noemi Fiaschini, Chiara Giuliani, Roberta Vitali, Loredana Tammaro, Daniele Valerini, Antonio Rinaldi

Summary: The antibacterial properties of engineered materials are crucial for various industries like healthcare, food, and water treatment. Nanocoating and electrospinning are low-cost technologies that can be used to manufacture innovative non-woven membranes with antibacterial and antifouling properties. This study demonstrates the use of combinatorial testing and nanocoating to optimize the mechanical properties of electrospun membranes and enhance their antimicrobial resistance.

NANOMATERIALS (2022)

Article Chemistry, Analytical

Tunable Nanoplasmonic Transducers: Performance Analysis and Potential Application

Adriano Colombelli, Daniela Lospinoso, Roberto Rella, Maria Grazia Manera

Summary: This paper presents an efficient and reproducible fabrication protocol for metal nanostructures with tunable plasmonic features using nanosphere lithography. The relationships between the geometric characteristics of different types of nanostructures and related optical phenomena are investigated, and optimized for their application as optical transducers in nanoplasmonic chemosensor platforms operating in the UV-VIS spectral range.

CHEMOSENSORS (2023)

Article Chemistry, Analytical

MEMS sensor based on MOF-derived WO3-C/In2O3 heterostructures for hydrogen detection

Mengmeng Guo, Na Luo, Yueling Bai, Zhenggang Xue, Qingmin Hu, Jiaqiang Xu

Summary: A porous heterostructure WO3-C/In2O3 was designed and prepared for a miniature H2 sensor, which showed higher response value, lower operating temperature, fast response-recovery speed, and low limit of detection.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Signal amplification strategy by chitosan-catechol hydrogel modified paper electrode for electrochemical detection of trace arsenite

Feng Hu, Hui Hu, Yuting Li, Xiaohui Wang, Xiaowen Shi

Summary: Arsenic contamination in water bodies is a significant health risk. This study developed a chitosan-catechol modified electrode for rapid and accurate detection of trace amounts of arsenic. The modified electrode demonstrated good detection capability and resistance to ionic interference, making it suitable for in situ detection.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

A buffering fluorogenic probe for real-time lysosomal pH monitoring

Yantao Zhang, Qian Liu, Tao Tian, Chunhua Xu, Pengli Yang, Lianju Ma, Yi Hou, Hui Zhou, Yongjun Gan

Summary: In this study, a lysosome-targeting buffering fluorogenic probe (Lyso-BFP) was designed and synthesized, demonstrating excellent photostability, pH specificity, and responsiveness to lysosomal acidification in living cells. The performance of Lyso-BFP in pH sensing was attributed to the inhibition of the photo-induced electron transfer process. Lyso-BFP allowed for wash-free imaging and long-term real-time monitoring of lysosome pH changes based on its off-on fluorescence behavior and buffer strategy.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Rational design of α-glucosidase activated near-infrared fluorescent probe and its applications in diagnosis and treatment of diabetes

Wei Cai, Wenbo Sun, Jiayue Wang, Xiaokui Huo, Xudong Cao, Xiangge Tian, Xiaochi Ma, Lei Feng

Summary: In this study, a near-infrared fluorescent probe HCBG was developed for imaging of alpha-GLC. HCBG exhibited excellent selectivity and sensitivity towards alpha-GLC in complex bio-samples, and showed good cell permeability for in situ real-time imaging. Through the high-throughput screening system established by HCBG, a natural alpha-GLC inhibitor was successfully isolated and identified. This study provides a novel fluorescence visualization tool for discovering and exploring the biological functions of diabetes-related gut microbiota, and a high-throughput screening approach for alpha-GLC inhibitor.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Electrochemical immunosensor for the quantification of galectin-3 in saliva

Trey W. Pittman, Xi Zhang, Chamindie Punyadeera, Charles S. Henry

Summary: Heart failure is a growing epidemic and a significant clinical and public health problem. Researchers have developed a portable and affordable diagnostic device for heart failure that can be used at the point-of-care, providing a valid alternative to current diagnostics approaches.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Optical hydrogen peroxide sensor for measurements in flow

Anders O. Tjell, Barbara Jud, Roland Schaller-Ammann, Torsten Mayr

Summary: An optical hydrogen peroxide sensor based on catalytic degradation and the detection of produced oxygen is presented. The sensor offers higher resolution and better sensitivity at lower H2O2 concentrations. By removing O2 from the sample solution, a more sensitive O2 sensor can be used for measurement. The sensor has been successfully applied in a flow-through cell to measure H2O2 concentration in different flow rates.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Engineered vertically-aligned carbon nanotube microarray for self-concentrated SERS detection

Seong Jae Kim, Ji-hun Jeong, Gaabhin Ryu, Yoon Sick Eom, Sanha Kim

Summary: Surface-enhanced Raman spectroscopy (SERS) is a high-sensitivity, label-free detection method with various analytical applications. Researchers have developed a hydrophobic SERS substrate based on engineered carbon nanotube arrays (CNT-SERS) and studied the role of structural design at both micro and nanoscales. The substrate demonstrated controlled self-enrichment capability and enhanced sensitivity, with a significant increase in the SERS signal. The study also proposed a theoretical model and a concentration strategy inspired by plants for analyte deposition on microarrays.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Flexible enzyme-like platform based on a 1-D CeVO4/2-D rGO-MCC heterostructure as sensor for the detection of intracellular superoxide anions

Dan Zhao, Renjun Jiang, Xiaoqiang Liu, Subbiah Alwarappan

Summary: In this study, a novel ternary composite material was constructed by assembling cerium vanadate nanorods on reduced graphene oxide-microcrystalline cellulose nanosheets, and it was used for real-time monitoring of the concentration of superoxide anions in vivo. The ternary composite showed excellent conductivity, large surface area, and abundant active sites, leading to a wider linear range, high sensitivity, low detection limit, and fast response time for superoxide anion detection.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Covalent organic framework enhanced aggregation-induced emission of berberine and the application for detection

Tengfei Wang, Liwen Wang, Guang Wu, Dating Tian

Summary: In this study, a covalent organic framework material TaTp-COF with porous and uniform spheres was successfully prepared via hydrothermal reaction, and it was found to significantly enhance the aggregation-induced emission (AIE) of berberine. The unique emission properties of berberine on TaTp-COF were studied and utilized for the sensitive detection of berberine.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Visualized time-temperature monitoring by triplet-sensitized ratiometric fluorescent nanosensors

Lin Li, Yilei Ding, Lei Xu, Shuoran Chen, Guoliang Dai, Pengju Han, Lixin Lu, Changqing Ye, Yanlin Song

Summary: In this study, a novel TTI based on a ratiometric fluorescent nanosensor is designed, which has the advantages of high accuracy and low cost. Experimental and theoretical investigations confirm its pH responsiveness and demonstrate its good sensitivity and reliability. By monitoring the total volatile basic nitrogen, this TTI can accurately predict food spoilage and can be adaptively modified for different types of food. The TTI based on this nanosensor enables visual monitoring of food quality.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

A fluorescent prodrug to fight drug-resistant lung cancer cells via autophagy-driven ferroptosis

Fangju Chen, Xueting Wang, Wei Chen, Chenwen Shao, Yong Qian

Summary: Lung cancer is the second most common malignant tumor worldwide. Drug resistance in lung cancer leads to treatment failure and recurrence in majority of patients. This study developed a fluorescent prodrug that can be activated in cancer cells to release drugs, and its signal can be tracked by imaging. It shows a unique autophagy-driven ferroptosis effect, indicating its potential for targeting drug-resistant cancer cells.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

ZnO quantum dots sensitized ZnSnO3 for highly formaldehyde sensing at a low temperature

Weichao Li, Qiming Yuan, Zhangcheng Xia, Xiaoxue Ma, Lifang He, Ling Jin, Xiangfeng Chu, Kui Zhang

Summary: This study developed a high-performance gas sensor for formaldehyde detection by modifying ZnSnO3 with ZnO QDs and SnO2 QDs. The modified sensor showed improved sensing response and lower working temperature. The presence of ZnO QDs formed rich heterojunctions, increased surface area, and provided oxygen deficiency for formaldehyde sensing reaction, thus enhancing the sensor performance. This research provides an alternative method to enhance the sensing properties of MOS by QDs modification.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Development of highly sensitive plasmonic biosensors encoded with gold nanoparticles on M13 bacteriophage networks

Joung-Il Moon, Eun Jung Choi, Younju Joung, Jin-Woo Oh, Sang-Woo Joo, Jaebum Choo

Summary: A novel nanoplasmonic substrate was developed for biomedical applications, which showed strong hot spots for detecting biomarkers at low concentrations. The substrate, called AuNPs@M13, was made by immobilizing 60 nm gold nanoparticles onto the surface of an M13 bacteriophage scaffold. It demonstrated higher sensitivity and lower limit of detection compared to commercially available assays.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Single-atom Cu-attached MOFs as peroxide-like enzymes to construct dual-mode immunosensors for detection of breast cancer typing in serum

Ning Li, Ya Zhang, Ying Xu, Xiaofang Liu, Jian Chen, Mei Yang, Changjun Hou, Danqun Huo

Summary: The molecular subtype of breast cancer guides treatment and drug selection. Invasive tests can promote cancer cell metastasis, so the development of high-performance, low-cost diagnostic tools for cancer prognosis is crucial. Liquid biopsy techniques enable noninvasive, real-time, dynamic, multicomponent, quantitative, and long-term observations at the cellular, genetic, and molecular levels. A Cu-Zr metal-organic framework (MOF) nanoenzyme with monatomic Cu attachment has been synthesized and proven to have high catalytic performance. The sensor constructed using this nanoenzyme shows potential for accurate classification of breast cancer serum samples.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Analytical

Individually-addressable composite microneedle electrode array by mold-and-place method for glucose detection

Jeongmin Kim, Hyemin Kim, Seunghyun Park, Hyeonaug Hong, Yong Jae Kim, Jiyong Lee, Jaeho Kim, Seung-Woo Cho, Wonhyoung Ryu

Summary: This study presents a method to fabricate independently functioning microneedle (MN) electrodes with narrow intervals for high precision electrochemical sensing. The optimized mixture of photocurable polymer and single-wall carbon nanotubes was used to mold single composite MNs, which were then attached to pre-patterned electrodes. Plasma etching and electropolymerization were performed to enhance the electrochemical activity, and Prussian blue and glucose oxidase were electrodeposited on the MNs for glucose detection. The MN electrodes showed good sensitivity and linearity, and the feasibility of glucose detection was demonstrated in an in vivo mouse study.

SENSORS AND ACTUATORS B-CHEMICAL (2024)