4.6 Article

A Novel Porphyrin-Containing Polyimide Nanofibrous Membrane for Colorimetric and Fluorometric Detection of Pyridine Vapor

期刊

SENSORS
卷 13, 期 11, 页码 15758-15769

出版社

MDPI
DOI: 10.3390/s131115758

关键词

zinc porphyrin; nanofibrous membrane; colorimetric sensor; fluorometric sensor; pyridine vapor

资金

  1. National Science Foundation of China [51303155]
  2. Natural Science Foundation of Zhejiang Province of China [LQ13E030001]
  3. Foundation of Hangzhou Science and Technology Information Institute of China [20120433B26]
  4. Foundation of Traditional Chinese medicine of Zhejiang Province [2013ZQ022]
  5. Foundation of Zhejiang Medical and Technology [2013KYA152]

向作者/读者索取更多资源

A novel zinc porphyrin-containing polyimide (ZPCPI) nanofibrous membrane for rapid and reversible detection of trace amounts of pyridine vapor is described. The membrane displays a distinct color change, as well as dramatic variations in absorption and fluorescent emission spectra, upon exposure to pyridine vapor. This condition allows the detection of the analyte at concentrations as low as 0.041 ppm. The vapochromic and spectrophotometric responses of the membrane are attributed to the formation of the ZPCPI-pyridine complex upon axial coordination. From surface plasmon resonance analysis, the affinity constant of ZPCPI-pyridine complex was calculated to be (3.98 +/- 0.25) x 10(4) L.mol(-1). The ZPCPI nanofibrous membrane also showed excellent selectivity for pyridine vapor over other common amines, confirming its applicability in the manufacture of pyridine-sensitive gas sensors.

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