4.6 Article

An Exfoliated Graphite-Based Bisphenol A Electrochemical Sensor

期刊

SENSORS
卷 12, 期 9, 页码 11601-11611

出版社

MDPI AG
DOI: 10.3390/s120911601

关键词

exfoliated graphite electrode; bisphenol A; phenol; electrode fouling; pollutant

资金

  1. University of Johannesburg (UJ)
  2. Nanotechnology Innovation Centre (NIC)
  3. National Research Foundation
  4. Council for Scientific and Industrial Research (CSIR)
  5. Indian Institute of Science

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The use of an exfoliated graphite (EG) electrode in the square wave voltammetric detection of bisphenol A (a model phenolic pollutant) in water, whereby the phenolic electrode fouling challenge is mitigated, is described. The oxidation peak of BPA was observed at about 0.45 V in phosphate buffer solution at pH 10. The current response exhibited a linear relationship with the concentration over a range from 1.56 mu M-50 mu M. The detection limit was calculated to be 0.76 mu M. The EG electrode surface was renewed after each measurement with excellent reproducibility. A real sample application was also investigated.

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