X-ray nanodiffraction reveals strain and microstructure evolution in nanocrystalline thin films

A novel synchrotron X-ray nanodiffraction approach for the quantitative characterization of strain and microstructure depth gradients in nanocrystalline thin films is introduced. Experiments were performed using monochromatic X-ray beams 100 and 250 nm in diameter on a 15 mu m thick CrN thin film. The results reveal a correlation between applied deposition conditions and a complex residual strain depth profile with a step-like shape and superimposed low-amplitude oscillations. Microstructure analysis shows multiple grain nucleation sites, smooth texture transitions and oscillating grain size distributions. (c) 2012 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.