Article
Materials Science, Multidisciplinary
Lingyu Zhao, Bo Guan, Yunchang Xin, Xiaoxu Huang, Chenglu Liu, Peidong Wu, Qing Liu
Summary: This study systematically investigated the mechanical behavior of Mg AZ31 rods under tension along the extrusion direction and the relationship with bimodal texture components. The results showed that the yield strength does not decrease linearly with an increase in the percentage of soft orientations. Bimodal texture components stimulate the activation of twin variants with a low Schmid factor, indicating that the interaction among twin variants plays a major role in twinning behavior.
Article
Nanoscience & Nanotechnology
Jing Xu, Yanshuo Peng, Bo Guan, Yunchang Xin, Adrien Chapuis, Guangjie Huang, Qing Liu
Summary: Dual-phase Mg-Li alloys with different rolling paths were studied to investigate the effect of rolling path on microstructure, texture and mechanical anisotropy. The lamellar alpha+beta structures remained after ED-rolling and subsequent annealing, while disappeared after TD-rolling. The texture of beta phase was hardly affected by the rolling path. Annealing only reduced the maximum intensity of texture without changing the type of texture. VPSC simulations revealed that the activated deformation modes and alpha/beta phase boundaries played important roles in texture evolution. There was an obvious mechanical anisotropy after ED-rolling, which disappeared after TD-rolling.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2022)
Article
Materials Science, Multidisciplinary
B. Q. Shi, Y. Z. Wang, X. L. Shang, L. Y. Zhao, C. Q. Li, D. C. Chen, B. H. Nie, R. S. Chen, W. Ke
Summary: This study investigates the microstructure evolution and texture development of a RE-containing Mg alloy during hot rolling, aiming to understand the formation of shear bands and their correlation with macro-texture characteristics. The results reveal the roles of different types of twins/variants and dislocation mechanisms in shear band formation, and provide insights into the influence of these factors on the texture development.
MATERIALS CHARACTERIZATION
(2022)
Article
Materials Science, Multidisciplinary
Mozhgan Shokri, Abbas Zarei-Hanzaki, Hamid Reza Abedi, Jae Hyung Cho
Summary: The study investigated the correlation between microstructure/texture evolutions and high temperature flow behavior in Mg alloy containing long period stacking order (LPSO) phases. The annealing treatment effectively strengthened the alloy and decreased ductility, with blocky LPSO assisting dynamic recrystallization and lamellar LPSO increasing alloy strength. The findings suggest that microstructure and texture evolution play a significant role in the high-temperature behavior of the Mg alloy.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2021)
Article
Materials Science, Multidisciplinary
Biaobiao Yang, Jun Wang, Yunping Li, Matthew Barnett, Javier LLorca
Summary: A dual-textured Mg-6.5 Zn alloy with limited yield asymmetry is studied. The deformation mechanisms responsible for the behavior are analyzed and it is found that compressive deformation is accommodated by basal slip and extension twinning, while tensile deformation promotes basal and nonbasal slip. The contribution of rotated grains leads to similar values of the yield strength in tension and compression.
Article
Metallurgy & Metallurgical Engineering
Jong Un Lee, Gyo Myeong Lee, Sung Hyuk Park
Summary: Precompression and subsequent annealing treatment can improve the bending formability of the Mg-9Al-1Zn-0.3Mn-0.9Ca-0.6Y alloy. The PCAed material exhibits higher bending formability due to the promoted twinning and slip behaviors.
JOURNAL OF MAGNESIUM AND ALLOYS
(2022)
Article
Materials Science, Multidisciplinary
T. Nakata, C. Xu, S. Kamado
Summary: After cold-rolling an Mg-6Zn-0.3Ca alloy sheet with a strong basal texture, anomalous double twinning occurred with the (0001) pole aligned to the transverse direction. These twins served as nucleation sites for statically recrystallized grains during annealing, resulting in weak texture features in the annealed sheet with transverse-direction split (0001) poles.
MATERIALS CHARACTERIZATION
(2021)
Article
Materials Science, Multidisciplinary
Amir Hassan Zahiri, Luiz Carneiro, Jamie Ombogo, Pranay Chakraborty, Lei Cao
Summary: The study investigates the structure and formation mechanism of {11 (2) over bar2} twin-twin boundaries in Mg, revealing alignment with {11 (2) over bar2} or {11 (2) over bar6} planes. These boundaries significantly contribute to the understanding of twinning theories in Mg.
COMPUTATIONAL MATERIALS SCIENCE
(2022)
Article
Chemistry, Physical
Jan Dittrich, Gergely Farkas, Daria Drozdenko, Michal Knapek, Kristian Mathis, Peter Minarik
Summary: A combination of advanced in-situ experimental techniques, including neutron diffraction, acoustic emission, and electron backscattered diffraction, was used to investigate the deformation behavior of magnesium alloys. The potential and limitations of these techniques were demonstrated in a study on the influence of crystallographic texture on deformation mechanisms in a hot-rolled sheet of the AZ31 alloy. The results showed the twinning activity and its evolution, as well as the deformed microstructure, providing valuable insights into the deformation mechanisms of the alloy.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Materials Science, Multidisciplinary
Ravi Sankar Haridas, Priyanka Agrawal, Surekha Yadav, Priyanshi Agrawal, Anurag Gumaste, Rajiv S. Mishra
Summary: The excellent work hardening in TRIP-enabled metastable high entropy alloys is attributed to the phase transformation from austenite to martensite, as well as non-basal slip activity and deformation twinning. A five-parameter empirical model has been developed to replicate the work hardening rate in TRIP HEAs, with easy parameter identification compared to physically based models. The model parameters are correlated with stacking fault energy to predict the tensile stress-strain response of TRIP HEAs.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2022)
Article
Chemistry, Physical
T. Nakata, C. Xu, L. Geng, S. Kamado
Summary: This paper reports the application of cold-sample rolling (CSR) processing in a Mg-6Al-1Zn alloy sheet, which resulted in a high fraction of double twins and a substantial texture-weakening effect. Compared to high-temperature rolling (HTR) processing, CSR processing induced a relatively higher texture-weakening effect. The results indicate that twinning-mediated static recrystallization is essential for texture weakening in Al-concentrated Mg-alloy sheets.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Nanoscience & Nanotechnology
T. Nakata, C. Xu, L. Geng, S. Kamado
Summary: We report the formation of an unusual texture on the sheet-surface of a rolled Mg-3Al-0.4Mn alloy, where a typical basal texture is formed at the center of the sheet and an unusual texture with vertical tiling is observed at the sheet-surface. The surface promotes prismatic slips and dynamic recrystallization, leading to a high fraction of fine basal-textured grains and a small fraction of off-basal-textured grains. In contrast, the center preserves a relatively high fraction of deformed grains, promoting the growth of basal-textured grains and the formation of the typical basal texture.
SCRIPTA MATERIALIA
(2023)
Article
Metallurgy & Metallurgical Engineering
T. Nakata, C. Xu, L. Geng, S. Kamado
Summary: This study investigates the origin of the unique parallel alignment of (0001) poles to the transverse direction in rolled alloy sheets. It is found that intermediate reheating during rolling facilitates static recrystallization and leads to the formation of the parallel alignment of (0001) poles to the transverse direction. In contrast, continuous rolling without intermediate reheating suppresses the formation of the unique alignment. The presence of severely deformed regions near double twins hinders the nucleation and growth of statically recrystallized grains, resulting in in-plane anisotropy in ductility.
JOURNAL OF MAGNESIUM AND ALLOYS
(2023)
Review
Metallurgy & Metallurgical Engineering
Ehsan Gerashi, Reza Alizadeh, Terence G. Langdon
Summary: Magnesium and its alloys are lightweight and potential bioresorbable materials, but their corrosion resistance is poor. This review summarizes the effects of crystallographic texture and twinning on the corrosion behavior of magnesium and its alloys, revealing contradictory results.
JOURNAL OF MAGNESIUM AND ALLOYS
(2022)
Article
Nanoscience & Nanotechnology
Jun Wang, Mahmoud Reza Ghandehari Ferdowsi, Peter A. Lynch, Sitarama R. Kada, Matthew R. Barnett
Summary: This study investigates the effects of age hardening on different types of twinning in magnesium alloys, specifically in alloy Mg-6.5Zn with bimodal textures. It was found that tensile twinning is stimulated by precipitates while compression twinning is suppressed by them. This difference is attributed to lower twin surface energy and a larger twinning dislocation Burgers vector in compression twins.
SCRIPTA MATERIALIA
(2022)
Article
Metallurgy & Metallurgical Engineering
Rameshkumar Varma, Sitarama Kada, Matthew Barnett
Summary: In this study, the effect of deformation on microstructure and thermoelectric properties of Mg2Sn alloys with excess magnesium concentrations was investigated. The alloys showed high plasticity at elevated temperatures, forming a substructure, and the thermoelectric performance was improved due to reduced thermal conductivity from phonon scattering at grain boundaries.
JOURNAL OF MAGNESIUM AND ALLOYS
(2021)
Article
Materials Science, Multidisciplinary
Filip Siska, Ludek Stratil, Jan Cizek, Tingting Guo, Matthew Barnett
Summary: This paper investigates the interactions between {10 (1) over bar2} ten sile twin and precipitates aligned along basal planes in magnesium alloys. The results show that precipitates influence the shear stress necessary to accommodate twins, and the thickness of precipitates plays a crucial role in twin thickening and propagation.
Article
Materials Science, Biomaterials
Ehsan Farabi, Julie A. Sharp, Alireza Vahid, Daniel M. Fabijanic, Matthew R. Barnett, Santiago Corujeira Gallo
Summary: A study on Zn-Al-Li alloys for potential bioresorbable implant applications revealed that the formation of secondary phases during hot-extrusion significantly influenced the dynamic recrystallization and grain refinement of the matrix, while the corrosion rate was affected by the formation of zinc oxide and phosphate layers.
MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS
(2021)
Article
Metallurgy & Metallurgical Engineering
Ehsan Bahrami Motlagh, Peter A. Lynch, Thomas Dorin, Pavel Cizek, Alireza Ghaderi, Matthew R. Barnett, Sitarama R. Kada
Summary: In the Mg-7Sn-3Zn-0.04Na alloy, the critical shear stress for achieving 5% twinning is increased by the presence of 7% of Sn and by the presence of particles formed after 10 hours of aging. The evolution of twin volume fraction with plastic strain is similar in both non-aged and aged conditions, indicating precipitation hardening is particularly sensitive to relaxation effects.
JOURNAL OF MAGNESIUM AND ALLOYS
(2021)
Article
Chemistry, Multidisciplinary
Alexey Falin, Matthew Holwill, Haifeng Lv, Wei Gan, Jun Cheng, Rui Zhang, Dong Qian, Matthew R. Barnett, Elton J. G. Santos, Konstantin S. Novoselov, Tao Tao, Xiaojun Wu, Lu Hua Li
Summary: The study investigates the mechanical properties of 2D tungsten disulfide, tungsten diselenide, and tungsten ditelluride, revealing that high-quality 1L WS2 has the highest Young's modulus and strength, with WS2 showing the most significant decrease in elasticity and strength with increased thickness among the three materials. The findings provide insights into the behavior of these materials under different conditions and aging effects, which can be beneficial for the design and application of 2D tungsten dichalcogenides in various fields.
Article
Metallurgy & Metallurgical Engineering
Jun Cheng, Tingting Guo, Matthew R. Barnett
Summary: This paper examines the temperature sensitivity of tensile twinning in a magnesium single crystal during nanoindentation. It is found that the generation of twinning is temperature-dependent, with a decrease in pop-in load as temperature increases. The activation energy obtained from thermal activation analysis is consistent with the observations.
JOURNAL OF MAGNESIUM AND ALLOYS
(2022)
Article
Nanoscience & Nanotechnology
J. Joseph, M. Annasamy, S. R. Kada, P. D. Hodgson, M. R. Barnett, D. M. Fabijanic
Summary: This study analyzed the effect of the relative contents of Al and Ti on the equilibrium phase formation in a novel high entropy superalloy system. Lower Al/Ti ratio improved the mechanical properties of the alloy.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2022)
Article
Materials Science, Multidisciplinary
Hossein Beladi, Ehsan Farabi, Peter D. Hodgson, Matthew R. Barnett, Gregory S. Rohrer, Daniel Fabijanic
Summary: Solid-state additive friction stir deposition was used for three-dimensional printing of 316L stainless steel. The resulting microstructure was exceptionally fine, with a significantly different misorientation angle distribution from the original material, and a texture showing strong shear components.
PHILOSOPHICAL MAGAZINE
(2022)
Article
Nanoscience & Nanotechnology
Jun Wang, Mahmoud Reza Ghandehari Ferdowsi, Peter A. Lynch, Sitarama R. Kada, Matthew R. Barnett
Summary: This study investigates the effects of age hardening on different types of twinning in magnesium alloys, specifically in alloy Mg-6.5Zn with bimodal textures. It was found that tensile twinning is stimulated by precipitates while compression twinning is suppressed by them. This difference is attributed to lower twin surface energy and a larger twinning dislocation Burgers vector in compression twins.
SCRIPTA MATERIALIA
(2022)
Article
Mechanics
Alban de Vaucorbeil, Vinh Phu Nguyen, Christopher R. Hutchinson, Matthew R. Barnett
Summary: This paper presents a study on the Total Lagrangian Material Point Method (TLMPM) for simulating scratch tests, showing its stability and accuracy through comparisons with experimental results and existing research.
INTERNATIONAL JOURNAL OF SOLIDS AND STRUCTURES
(2022)
Article
Nanoscience & Nanotechnology
Jun Wang, Mahmoud Reza Ghandehari Ferdowsi, Sitarama Raju Kada, Steven Babaniaris, Bevis Hutchinson, Peter A. Lynch, Matthew R. Barnett
Summary: The C-texture appears in Mg-6.5Zn alloy with heavy alloying and higher extrusion ratios. It is not solely linked to the presence of second phase particles, and the starting texture is not essential for its formation. The promoted pyramidal < c + a > slip mechanism is likely responsible for its formation.
SCRIPTA MATERIALIA
(2022)
Article
Engineering, Mechanical
Daniel Grasser, Michael Pereira, Matthew Barnett, Santiago Corujeira Gallo
Summary: This study investigates the wear behavior of macro-scale composites consisting of hard inserts in a soft matrix and suggests that the spacing between the inserts, relative to the size of abrasive particles, is crucial in reducing wear and forming protective particle layers.
Article
Materials Science, Multidisciplinary
Yi Yang, Veronique Massardier, Mahmoud Reza Ghandehari Ferdowsi, Lu Jiang, Jun Wang, Thomas Dorin, Sitarama R. Kada, Matthew R. Barnett, Michel Perez
Summary: This study provides new insights into the precipitation kinetics in Mg-Zn alloys. Through the characterization of the evolution of Zn solute, precipitate size, and volume fraction using various techniques, the experimental results are supported by a precipitation model based on classical nucleation and growth theories. The study reveals the prevalence of rod-shaped precipitates in the early aging stage and plate-shaped precipitates in the overaging stage.
Article
Materials Science, Multidisciplinary
Charline Le Nue, Santiago Corujeira Gallo, Alireza Vahid, Jiangting Wang, Mehdi Taherishargh, Hooyar Attar, Daniel Fabijanic, Matthew Barnett
Summary: High-chromium cast irons are commonly used for wear-resistant applications, and there is ongoing debate on the secondary carbide types during heat treatment. This study examines the microstructural evolution of a hypoeutectic high-chromium cast iron and finds that M23C6 secondary carbides precipitate during heating, while higher temperatures result in the formation of both M23C6 and M7C3 secondary carbides. The carbon content of the matrix plays a significant role in determining the martensite start temperature and bulk hardness.
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE
(2023)
Article
Engineering, Manufacturing
Ehsan Farabi, Steven Babaniaris, Matthew R. Barnett, Daniel M. Fabijanic
Summary: The additive friction stir deposition (AFSD) of Ti6Al4V alloy was performed successfully with improved ductility and strength of the deposited state, achieved by the reduction of deposition temperature and refinement of the as-deposited phase structure.
ADDITIVE MANUFACTURING LETTERS
(2022)
Article
Nanoscience & Nanotechnology
Jie Zhang, Xiaoyang Chen, MingJian Ding, Jiaqiang Chen, Ping Yu
Summary: This study enhances the compositional inhomogeneity of relaxor ferroelectric thin films to improve their dielectric temperature stability. The prepared films exhibit a relatively high dielectric constant and a very low variation ratio of dielectric constant over a wide temperature range.
SCRIPTA MATERIALIA
(2024)
Article
Nanoscience & Nanotechnology
Xiaoyu Chen, Ranran Zhang, Hao Zou, Ling Li, Qiancheng Zhu, Wenming Zhang
Summary: Polyaniline-manganese dioxide composites exhibit high conductivity, long discharge platform, and stable circulation, and the specific capacity is increased by providing additional H+ ions to participate in the reaction.
SCRIPTA MATERIALIA
(2024)
Article
Nanoscience & Nanotechnology
Xutao Huang, Yinping Chen, Jianjun Wang, Gang Lu, Wenxin Wang, Zan Yao, Sixin Zhao, Yujie Liu, Qian Li
Summary: This study aims to establish a novel approach to better understand and predict the behavior of materials with multi-scale lamellar microstructures. High-resolution reconstruction and collaborative characterization methods are used to accurately represent the microstructure. The mechanical properties of pearlite are investigated using crystal plasticity simulation and in-situ scanning electron microscopy tensile testing. The results validate the reliability of the novel strategy.
SCRIPTA MATERIALIA
(2024)
Article
Nanoscience & Nanotechnology
Cheng Chen, Fanchao Meng, Jun Song
Summary: This study systematically investigated the unfaulting mechanism of single-layer interstitial dislocation loops in irradiated L12-Ni3Al. The unfaulting routes of the loops were uncovered and the symmetry breaking during the unfaulting processes was further elucidated. A continuum model was formulated to analyze the energetics of the loops and predict the unfaulting threshold.
SCRIPTA MATERIALIA
(2024)
Article
Nanoscience & Nanotechnology
Darshan Bamney, Laurent Capolungo
Summary: This work investigates the formation of adjoining twin pairs (ATPs) at grain boundaries (GBs) in hexagonal close-packed (hcp) metals, focusing on the co-nucleation (CN) of pairs of deformation twins. A continuum defect mechanics model is proposed to study the energetic feasibility of CN of ATPs resulting from GB dislocation dissociation. The model reveals that CN is preferred over the nucleation of a single twin variant for low misorientation angle GBs. Further analysis considering GB character and twin system alignment suggests that CN events could be responsible for ATP formation even at low m' values.
SCRIPTA MATERIALIA
(2024)
Article
Nanoscience & Nanotechnology
Bing Han, Zhengqian Fu, Guoxiang Zhao, Xuefeng Chen, Genshui Wang, Fangfang Xu
Summary: This study investigates the behavior of electric-field induced antiferroelectric to ferroelectric (AFE-FE) phase transition and reveals the evolution of atomic displacement ordering as the cause for the transition behavior changing from sharp to diffuse. The novel semi-ordered configuration results from the competing interaction between long-range displacement modulation and compositional inhomogeneity, which leads to a diffuse AFE-FE transition while maintaining the switching field.
SCRIPTA MATERIALIA
(2024)
Article
Nanoscience & Nanotechnology
Akib Jabed, Golden Kumar
Summary: This study demonstrates that cryogenic rejuvenation promotes homogeneous-like flow and increases ductility in metallic glass samples. Conversely, annealing has the opposite effect, resulting in a smoother fracture surface.
SCRIPTA MATERIALIA
(2024)
Article
Nanoscience & Nanotechnology
Xin Ji, Yan Chong, Satoshi Emura, Koichi Tsuchiya
Summary: A heterogeneous microstructure in Ti-15Mo-3Al alloy with heterogeneous distributions of Mo element and omega(iso) precipitates has achieved a four-fold increase in tensile ductility without a loss of tensile strength, by blocking the propagation of dislocation channels and preventing the formation of micro-cracks.
SCRIPTA MATERIALIA
(2024)
Article
Nanoscience & Nanotechnology
Amit Samanta, Prasanna Balaprakash, Sylvie Aubry, Brian K. Lin
Summary: This study proposes a combined large-scale first principles approach with machine learning and materials informatics to quickly explore the chemistry-composition space of advanced high strength steels (AHSS). The distribution of aluminum and manganese atoms in iron is systematically explored using first principles calculations to investigate low stacking fault energy configurations. The use of an automated machine learning tool, DeepHyper, speeds up the computational process. The study provides insights into the distribution of aluminum and manganese atoms in systems containing stacking faults and their effects on the equilibrium distribution.
SCRIPTA MATERIALIA
(2024)
Article
Nanoscience & Nanotechnology
Guowei Zhou, Yuanzhe Hu, Zizheng Cao, Myoung Gyu Lee, Dayong Li
Summary: In this work, a physics-constrained neural network is used to predict grain-level responses in FCC material by incorporating crystal plasticity theory. The key feature, shear strain rate of slip system, is identified based on crystal plasticity and incorporated into the loss function as physical constitutive equations. The introduction of physics constraints accelerates the convergence of the neural network model and improves prediction accuracy, especially for small-scale datasets. Transfer learning is performed to capture complex in-plane deformation of crystals with any initial orientations, including cyclic loading and arbitrary non-monotonic loading.
SCRIPTA MATERIALIA
(2024)
Article
Nanoscience & Nanotechnology
Pengfei Yang, Qichang Li, Zhongying Wang, Yuxiao Gao, Wei Jin, Weiping Xiao, Lei Wang, Fusheng Liu, Zexing Wu
Summary: In this study, the HER performance of Ru-based catalysts is significantly improved through the dual-doping strategy. The obtained catalyst exhibits excellent performance in alkaline freshwater and alkaline seawater, and can be stably operated in a self-assembled overall water splitting electrolyzer.
SCRIPTA MATERIALIA
(2024)
Article
Nanoscience & Nanotechnology
Ilias Bikmukhametov, Garritt J. Tucker, Gregory B. Thompson
Summary: Depositing a Ni-1at. % P film can facilitate the formation of multiple quintuple twin junctions, resulting in a five-fold twin structure and a pentagonal pyramid surface topology. The ability to control material structures offers opportunities for creating novel surface topologies, which can be used as arrays of field emitters or textured surfaces.
SCRIPTA MATERIALIA
(2024)
Article
Nanoscience & Nanotechnology
Zening Yang, Weiwei Sun, Zhengyu Sun, Mutian Zhang, Jin Yu, Yubin Wen
Summary: Multicomponent oxides (MCOs) have wide applications and accurately predicting their thermal expansion remains challenging. This study introduces an innovative attention-based deep learning model, which achieves improved performance by using two self-attention modules and demonstrates adaptability and interpretability.
SCRIPTA MATERIALIA
(2024)
Article
Nanoscience & Nanotechnology
Ze Liu, Cai Chen, Yuanxun Zhou, Lanting Zhang, Hong Wang
Summary: This study attempts to address the gap in cooling rates between thin film deposition and bulk metallic glass (BMG) casting by correlating the glass-forming range (GFR) determined from combinatorial materials chips (CMCs) with the glass-forming ability (GFA) of BMG. The results show that the full-width at half maximum (FWHM) of the first sharp diffraction peak (FSDP) is a good indicator of BMG GFA, and strong positive correlations between FWHM and the critical casting diameter (Dmax) are observed in various BMG systems. Furthermore, the Pearson correlation coefficients suggest possible similarities in the GFA natures of certain BMG pairs.
SCRIPTA MATERIALIA
(2024)
Article
Nanoscience & Nanotechnology
Mike Schneider, Jean-Philippe Couzinie, Amin Shalabi, Farhad Ibrahimkhel, Alberto Ferrari, Fritz Koermann, Guillaume Laplanche
Summary: This work aims to predict the microstructure of recrystallized medium and high-entropy alloys, particularly the density and thickness of annealing twins. Through experiments and simulations, a database is provided for twin boundary engineering in alloy development. The results also support existing theories and empirical relationships.
SCRIPTA MATERIALIA
(2024)