期刊
RSC ADVANCES
卷 5, 期 125, 页码 103465-103473出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra15336k
关键词
-
资金
- Pondicherry University [2011-12/305]
In spite of the potential biomedical application, ceria nanoparticles suffer from poor optical and magnetic properties. Here we report the structural, optical and magnetic properties of iron (8 at%) and europium (1 at%) co-doped ceria nanoparticles with respect to annealing temperature. A cubic fluorite structure of ceria was observed on co-doping but an additional alpha-Fe2O3 phase emerged on annealing at 700 degrees C and above. An increase in the mean crystallite size from 6.5 to 37 nm and a corresponding reduction in strain was observed with annealing temperature. Surface area and scanning electron microscopic studies indicated a porous structure which became dense upon annealing. Raman spectroscopic studies reveal the presence of oxygen vacancy defects arising from the combination of intrinsic and extrinsic defects due to the presence of Ce3+ and dopant, respectively. X-ray photoelectron spectroscopic results confirm the oxidation of Ce3+ to Ce4+ state while the trivalent state of iron was retained on annealing at higher temperatures. On annealing above 500 degrees C, reduction in defect concentration improved the emission intensity primarily through magnetic dipole transition. A typical ferromagnetic behaviour was noticed in all the samples and shift a from soft to hard magnetic behaviour upon annealing.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据