Seasonal characterization of components and size distributions for submicron aerosols in Beijing

Submicron aerosols (PM1) in Beijing were studied using an Aerodyne aerosol mass spectrometer (AMS) from January to October 2008. This paper presents seasonal variations of different chemical components (sulfate, nitrate, ammonium, chloride and organics) and size distributions of PM1. Results show that mass concentration of PM1 was highest in summer, and lowest in autumn. Organics represented the dominant species in all seasons, accounting for 36%-58% of PM1, and their concentrations were highest in winter. Concentrations of inorganic components, sulfate, nitrate, and ammonium were highest in summer. Based on principal component analysis, organics were deconvolved and quantified as hydrocarbon-like and oxygenated organic aerosol (HOA and OOA, respectively). HOA was highest in winter, accounting for about 70% of organics. However, OOA was highest in summer, and had lower values in autumn and winter. A similar diurnal pattern of various components was observed, which is higher at nighttime and lower during daytime. HOA increased more dramatically than other species between 17:00 and 21:00 and peaked at noon, which could be related to cooking emissions. OOA, sulfate, nitrate, ammonium and chloride varied with the same trend. Their concentrations increased with solar radiation from 9:00 to 13:00, and declined with weakening solar radiation. Size distributions of all species showed apparent peaks in the range 500-600 nm. Size distributions of organics were much broader than other species, particularly in autumn and winter. Distributions of sulfate, nitrate and ammonium had similar patterns, broadening in winter. Contributions of different species were size-dependent; the finer the particle, the greater the contribution of organics. Organics represented more than 60% of particles smaller than 200 nm, contributing 50% to PM1 in winter. In spring and summer, HOA was the dominant organic fraction for particles smaller than 200 nm, while OOA contributed more to particles larger than 300 nm. In winter, HOA contributed more than OOA to all PM1 particles.