4.7 Article

Thermal and photoinduced valence tautomerism of a chain compound

期刊

SCIENCE CHINA-CHEMISTRY
卷 55, 期 6, 页码 1037-1041

出版社

SCIENCE PRESS
DOI: 10.1007/s11426-011-4484-7

关键词

valence tautomerism; coordination polymer; cobalt(II); photo excitation

资金

  1. National Natural Science Foundation of China [90922012, 20971106, 21021061]
  2. Natural Science Foundation of Fujian Province [2009J06006]

向作者/读者索取更多资源

Herein reported is an example of one-dimensional coordination polymer [Co-II(3,5-DBsq)(2)(dpg)]center dot(3,5-H(2)DBcat)(2) (1) (3,5-DBsq = 3,5-di-tert-butylsemiquinonate, 3,5-H(2)DBcat = 3,5-di-tert-butyl-benzene-1,2-diol, dpg = meso-alpha,beta-di(4-pyridyl)glycol) capable of undergoing thermal and photoinduced valence tautomeric transitions.

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