期刊
RSC ADVANCES
卷 5, 期 18, 页码 13727-13732出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra16386a
关键词
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资金
- Japan Petroleum Institute
- Sasakawa Scientific Research Grant
- Grants-in-Aid for Scientific Research [15J01556] Funding Source: KAKEN
We have accomplished an efficient and mild multiple deuteration method for alkanes catalyzed by the combined use of heterogeneous platinum on carbon (Pt/C) and rhodium on carbon (Rh/C) catalysts in i-PrOD-d(8) and D2O as a mixed solvent. The present multi-deuteration could be initiated by the transition metal-catalyzed dedeuteration of i-PrOD-d(8) to produce D-2 and the subsequent C-H bond activation of alkanes catalyzed by the Pt/C and/or Rh/C-D-2 complex. This method could be applied to the deuteration of wide variety of linear, branched and cyclic alkanes as useful deuterated materials under mild conditions.
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