Article
Biochemical Research Methods
Wolfgang Thormann
Summary: The study evaluated the impact of complexation constant and the mobility of formed diastereomeric complex on stereoisomer separation in the presence of a neutral chiral selector. The findings indicate that differences in these parameters affect the efficiency of chiral separation.
JOURNAL OF CHROMATOGRAPHY A
(2022)
Article
Engineering, Chemical
Amna Khatoon, Nadir H. Khand, Arfana Mallah, Amber R. Solangi, Saima Q. Memon, Almas F. Memon, Ceren Karaman, Fatemeh Karimi, Onur Karaman
Summary: This study demonstrates the potential and utility of capillary electrophoresis for rapid size-based characterization of Ag NPs. By using specific buffer and voltage conditions, the size of Ag NPs can be analyzed based on electrophoretic mobility, providing comparable results with conventional techniques at a lower cost.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Chemistry, Inorganic & Nuclear
Ozlem Ipsiz Oney, H. Yasemin Yenilmez, Dilek Bahar, Nazli Farajzadeh Ozturk, Zehra Altuntas Bayir
Summary: This study presents the first report on the anticancer properties of carbazole-containing phthalonitrile/phthalocyanine-modified silver nanoparticles. Mono-substituted phthalonitrile and its metal phthalocyanines were synthesized and linked to the surface of silver nanoparticles. The cytotoxic activities of the nanoconjugates were tested against different cell lines with/without irradiation, showing potential as anticancer agents.
DALTON TRANSACTIONS
(2023)
Review
Chemistry, Multidisciplinary
Catarina S. M. Martins, Helena B. A. Sousa, Joao A. V. Prior
Summary: There has been a significant increase in the application of AgNPs in various fields, leading to greater human exposure and potential risks to health and the environment. The use of AgNPs without purification or separation from synthesis medium can pose severe risks of environmental contamination. Various separation techniques and their sustainability and efficiency in separating AgNPs are reviewed in this study.
Article
Chemistry, Analytical
Fotouh R. Mansour, R. Dario Arrua, Christopher T. Desire, Emily F. Hilder
Summary: The influence of various non-ionic surfactants on poly(ethylene glycol) diacrylate-based monolith formulations was studied. Different surfactants resulted in permeable materials, with Tween 40 showing the highest efficiency and methylene selectivity. This porogenic mixture was successfully used for preparation of monolithic columns from various monomers, demonstrating its versatility as a universal porogen system.
ANALYTICAL CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Shu Fen Gu, Xiao Hong Xiong, Le Le Gong, Hui Ping Zhang, Ying Xu, Xue Feng Feng, Feng Luo
Summary: This study demonstrates successful classification encapsulation of different guest molecules in actinide-based metal-organic frameworks for the first time, with precise encapsulation locations. The resulting guest@MOF composites exhibit varied performance depending on the type of encapsulated guest molecules, showing potential for different applications.
INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Analytical
Danielle Bennett, Xueqian Chen, Gregory J. Walker, Sacha Stelzer-Braid, William D. Rawlinson, D. Brynn Hibbert, Richard D. Tilley, J. Justin Gooding
Summary: Plasmonic nanoparticles in dimer format are used for single molecule sensing, where the interaction with hairpin DNA leads to a shift in localized surface plasmon resonance. Spectroscopy may detect this shift, but point-of-care devices require a faster analysis method. By using dark-field imaging and digital analysis, the plasmonic resonance shift of thousands of dimer structures can be measured in minutes. The challenge is separating dimers from non-specifically bound clusters to achieve accurate results. The LAB-based classifier algorithm demonstrated the highest accuracy for this digital separation.
ANALYTICAL CHEMISTRY
(2023)
Article
Biophysics
Duc Dung Nguyen, Shingjiang Jessie Lue, Jui-Yang Lai
Summary: The size of silver nanoparticles plays a crucial role in their therapeutic efficacy in treating Staphylococcus aureus keratitis, with medium-sized particles demonstrating the best treatment outcomes.
COLLOIDS AND SURFACES B-BIOINTERFACES
(2021)
Article
Biochemical Research Methods
Olivia Gordon, Joshua Gibbons, Jared Lamp, Andrew W. Lantz
Summary: There is a great need for fast, affordable, and accurate methods for microbial analysis in various fields. This study presents a novel capillary isotachophoresis (CITP) method for quantifying intact cells in mixed samples based on their electrophoretic mobility ranges. The method uses ion spacers to create efficient cell peaks in the electropherogram, which can be used to determine the concentrations of different cell species. The results demonstrate the potential application of CITP in cell growth studies, microbial contamination testing, and sterility testing.
Article
Biochemistry & Molecular Biology
Piersandro Pallavicini, Luca Preti, Maria L. Protopapa, Daniela Carbone, Laura Capodieci, Yuri A. Diaz Fernandez, Chiara Milanese, Angelo Taglietti, Lavinia Doveri
Summary: A synthetic approach was developed to prepare silica gel monoliths embedded with well separated silver or gold spherical nanoparticles with different diameters. The oxidation and removal of silver nanoparticles from silica was achieved using Fe3+, O-2/cysteine, and HNO3, while aqua regia was necessary for gold nanoparticles. NP-imprinted silica powders were obtained by grinding the monoliths, which showed efficient reuptake of silver ultrafine nanoparticles and remarkable size selectivity based on the match between nanoparticle radius and cavity curvature. The materials and methods described in this paper may provide an efficient solution for capturing and safely disposing of silver ultrafine nanoparticles from environmental waters.
Article
Chemistry, Applied
Kun Peng, Yanan Huang, Na Peng, Chunyu Chang
Summary: This study developed a superhydrophilic/underwater superoleophobic nanocellulose-based membrane by depositing silver nanoparticles on tunicate cellulose nanocrystals. These membranes exhibit nanoporous structure, high separation efficiency for oil/water emulsion, and excellent antibacterial efficacy.
CARBOHYDRATE POLYMERS
(2022)
Article
Chemistry, Multidisciplinary
Ya-Meng Wu, Pei-Chen Zhao, Bin Jia, Zhe Li, Shuai Yuan, Cheng-Hui Li
Summary: Silver nanoparticles have broad spectrum antimicrobial activities, but their tendency to aggregate reduces their antibacterial effectiveness. A metal-organic framework modified with Ag(i) shows highly effective antibacterial activity against E.coli and S. aureus.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Chemistry, Physical
Tsai-Wei Lin, Baicheng Mei, Kenneth S. Schweizer, Charles E. Sing
Summary: The role of cross-linked network polymers in governing the molecular motion of penetrants is investigated using molecular simulation. The results show that cross-links primarily affect molecular diffusion through the modification of the matrix glass transition, and penetrant transport is affected by dynamic heterogeneity at low temperatures. This research provides important insights for the design of materials for applications such as coatings and membranes.
JOURNAL OF CHEMICAL PHYSICS
(2023)
Article
Engineering, Environmental
Mohit Kumar, G. Pugazhenthi, D. Vasanth
Summary: In this study, Kocuria rhizophila BR-1 bacterium was used to produce extracellular silver nanoparticles (AgNPs) and a ceramic membrane was used for their separation. The results showed that the AgNPs could be successfully separated from the aqueous solution using a coated membrane and a dead-end filtration method.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Multidisciplinary
Zhengyang Fan, Jiayi Wang, Linlin He, Bo Shen, Jie Chen, Huaming Mao, Yu Ren, Jungang Yin, Hao Cui, Hongwei Yang
Summary: This study presents a simple and robust approach to synthesize ultrahigh aspect ratio silver nanowires (AgNWs) by utilizing tetrabutylammonium tribromide as an auxiliary additive. The fabricated AgNWs exhibit the highest aspect ratio up to 4000 and an average length of 72 μm. The transparent conductive film created using these AgNWs shows low sheet resistance, high transmittance, and low haze, indicating great potential for applications in flexible transparent electrodes.
Article
Thermodynamics
S. Vallova, E. Plevova, K. Smutna, B. Sokolova, L. Vaculikova, V. Valovicova, M. Hundakova, P. Praus
Summary: This study evaluates the potential of commercial montmorillonites in removing analgesic drugs from aqueous solutions. The organically modified montmorillonite demonstrated strong adsorption ability, especially exhibiting the best adsorption performance for diclofenac among the three analgesics studied.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2022)
Review
Chemistry, Multidisciplinary
Petr Praus
Summary: This study provides an overview of s-C3N4, an allotrope of graphitic carbon nitride, addressing its significance, particularly in terms of its potential as a photocatalyst.
Article
Materials Science, Multidisciplinary
Vlastimil Matejka, Mara Leonardi, Petr Praus, Giovanni Straffelini, Stefano Gialanella
Summary: This study evaluated the role of graphitic carbon nitride (gCN) in friction composites for brake pad manufacturing and found that its main function is as a soft abrasive.
Article
Chemistry, Physical
Karolina Simkovicova, Muhammad Qadir, Nadezda Zilkova, Joanna E. Olszowka, Pavel Sialini, Libor Kvitek, Stefan Vajda
Summary: This study investigated the influence of copper content and particle morphology on the performance of Cu/FeOx catalysts in the gas-phase conversion of CO2 with hydrogen. The findings indicate potential new ways of tuning the morphology and composition of iron-oxide-based particles, ultimately yielding catalyst compositions and morphologies with variable catalytic performances.
Article
Materials Science, Multidisciplinary
Vlastimil Matejka, Radim Skuta, Krystof Foniok, Vlastimil Novak, Daniel Cvejn, Alexandr Martaus, Monika Michalska, Jiri Pavlovsky, Petr Praus
Summary: This study describes the doping of graphitic carbon nitride (g-C3N4) with phosphorus through heat treatment, and investigates the influence of phosphorus content on the photocatalytic degradation activity.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2022)
Article
Multidisciplinary Sciences
Petr Praus, Lenka Rehackova, Jakub Cizek, Aneta Smykalova, Martin Kostejn, Jiri Pavlovsky, Miroslava Filip Edelmannova, Kamila Koci
Summary: This study synthesized C3N4 from nitrogen-rich precursors, forming vacancy complexes that are beneficial for hydrogen generation, and the photocatalyst exhibited higher performance than bulk C3N4 synthesized in air.
SCIENTIFIC REPORTS
(2022)
Article
Chemistry, Inorganic & Nuclear
Kende Attila Beres, Zoltan Homonnay, Libor Kvitek, Zsolt Durvanger, Martina Kubikova, Veronika Harmat, Fanni Szilagyi, Zsuzsanna Czegeny, Peter Nemeth, Laura Bereczki, Vladimir M. Petrusevski, Matyas Papai, Attila Farkas, Laszlo Kotai
Summary: Research on catalysts for CO2 hydrogenation is of great importance. This study presents a method to prepare a permanganate salt of urea-coordinated iron(III) and demonstrates its catalytic activity in CO2 hydrogenation.
INORGANIC CHEMISTRY
(2022)
Article
Materials Science, Multidisciplinary
Petr Praus, Aneta Smykalova, Daniel Cvejn, Sandra Losertova, Martin Kostejn, Vlastimil Novak
Summary: By surface modification of graphitic carbon nitride (g-C3N4), the pore size distribution and surface structure could be altered, resulting in improved photocatalytic activity. Among the doping agents, the photocatalyst prepared through the reaction of PCl3 and pyridine showed the highest activity.
DIAMOND AND RELATED MATERIALS
(2022)
Article
Green & Sustainable Science & Technology
Jiri Horak, Lenka Kubonova, Milan Dej, Jiri Rysavy, Stanislav Bajer, Zdennk Kysucan, Pavel Ulrich, Pavel Marecek, Filip Tesar, Martin Garba, Frantisek Hopan, Petr Praus
Summary: Maintaining a pH value between 6 and 9 in wastewater is crucial for protecting water organisms. The use of dolomite is an effective and affordable way to neutralize the acidic condensate from gas condensing boilers. However, the effectiveness of dolomite may be reduced in the long run due to the aluminum content in the heat exchanger, so aerating the condensate in the neutralization box is recommended for more efficient neutralization.
Review
Chemistry, Multidisciplinary
Petr Praus
Summary: This review summarizes research articles on the photocatalytic fixation of nitrogen using graphitic carbon nitride (g-C3N4) from 2015 onwards. The NH3/NH4+ production rates from these articles were statistically processed, with the highest rate achieved by the composite g-C3N4 and 1T-MoS2 being 11120 mu mol g(-1) L-1 h(-1). The highest reported rate provided by bulk g-C3N4 was 5561 mu mol g(-1) L-1 h(-1), which surpassed 90% of the rates from various g-C3N4 composites. The quantum efficiency of the composites ranged from 0.033 to 5.65% with a median of 1.25%. Although not competitive with the industrial Haber-Bosch process, graphitic carbon nitride shows promise for future investigations into photocatalytic nitrogen fixation under visible light.
Review
Computer Science, Interdisciplinary Applications
Petr Praus
Summary: This study searched for an empirical relationship between the number of review and research articles published per year. The simple idea based on proportionality between the numbers of both kinds of articles was expressed using a quadratic relationship that accounts for negative or positive deviations from assumed linearity. The quadratic relationship was able to accurately describe the early and mature phases of research fields and detect unexpectedly high numbers of review articles. The findings were verified using articles from 20 different research fields across various time spans obtained from the Web of Science.
Article
Multidisciplinary Sciences
M. Michalska, V. Matejka, J. Pavlovsky, P. Praus, M. Ritz, J. Serencisova, L. Gembalova, M. Kormunda, K. Foniok, M. Reli, G. Simha Martynkova
Summary: This study demonstrates the comparison of two different semiconductor materials, TiO2 and melem/g-C3N4 composites, modified with Ag nanoparticles as photocatalysts for degradation of acid orange 7 (AO7) dye. A new synthesis route for Ag NPs was proposed, and the best photocatalytic performances were achieved for TiO2 and melem/g-C3N4 materials modified with a very low Ag content. The results suggest the potential of these materials for the degradation of organic contaminants in wastewater treatment.
SCIENTIFIC REPORTS
(2023)
Article
Chemistry, Physical
Shashikant A. Kadam, Stefania Sandoval, Zdenek Bastl, Karolina Simkovicova, Libor Kvitek, Juraj Jasik, Joanna Elzbieta Olszowka, Stanislav Valtera, Mykhailo Vaidulych, Jaroslava Moravkova, Petr Sazama, David Kubicka, Arnaud Travert, Jeroen A. van Bokhoven, Alessandro Fortunelli, Armin Kleibert, Martin Kalbac, Stefan Vajda
Summary: In this study, the cyclohexane oxidative dehydrogenation (ODH) catalyzed by cobalt ferrite nanoparticles supported on reduced graphene oxide (RGO) was investigated. The active sites responsible for full and partial dehydrogenation were identified using advanced spectroscopic techniques and kinetic analysis. The study revealed the cooperativity between different sites and the role of the support in controlling the abundance of undesired active sites.
Article
Engineering, Environmental
Sarka Pausova, Michal Baudys, Jiri Kosina, Petr Praus, Albin Pintar, Gregor Zerjav, Matevz Roskaric, Matjaz Finsgar, Josef Krysa
Summary: Sufficient photochemical stability is crucial for the successful environmental applications of g-C3N4 photocatalyst. This study investigates the photostability of g-C3N4 materials under UV and visible light irradiation, and analyzes the production of organic compounds. The results show that g-C3N4 materials produce organic compounds under UV or visible light, while TiO2 does not. This may be due to the surface oxidation reaction of g-C3N4 materials, which leads to the disruption of C-N bonds and the release of organic compounds.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Engineering, Environmental
Petr Praus, Aneta Smykalova, Krystof Foniok, Vlastimil Novak, Jan Hrbac
Summary: Bare and oxygen doped graphitic carbon nitride were synthesized by thermal polymerization and mechanical mixtures, with the addition of cyanuric acid leading to changes in morphology and increased surface functional groups, ultimately enhancing photocatalytic activity.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)