4.6 Article

LiTaO3 microcubes: the layered structure and the increased Curie temperature

期刊

RSC ADVANCES
卷 5, 期 40, 页码 31615-31621

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra03209a

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资金

  1. National Basic Research Program of China [2012CB932303]
  2. National Natural Science Foundation of China [11104268, 11104269, 11474284, 11404341]
  3. Instrument Developing Project of the Chinese Academy of Sciences [yg2102070]
  4. CAS/SAFEA International Partnership Program for Creative Research Teams

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Lithium tantalate (LiTaO3) is a very important material with various outstanding properties. In this paper, a LiTaO3 microcube has been successfully synthesized using a hydrothermal method at 220 degrees C. The microcube is about 1 mm in diameter. The structure is characterized by FESEM, TEM and Raman investigation, and the results suggest that the microcube is constructed by nanolayers. To clarify the growth mechanism of the layered microcube, a time-dependent FESEM investigation is performed. Further investigation of PL, dielectric and ferroelectric properties indicate that there are lots of oxygen related defects among the layers, which is helpful for increasing the Curie temperature. The LiTaO3 microcubes show application potential to be used as a pyroelectric detector material with high performance.

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