期刊
RSC ADVANCES
卷 5, 期 91, 页码 74712-74719出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra16197e
关键词
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资金
- Strategic Environmental Research and Development Program [SERDP WP-2214]
- Office of Naval Research ILIR Program
Three thermosetting cyanate ester resins with phosphate cores have been synthesized from chlorophosphates by a straightforward, three-step approach. A p-substituted bis(cyanate) ester generated by this route (PhosCy) was cured to give a thermoset material with a T-g of 223 degrees C and a char yield of 47% in air, while the m-substituted version (MPhosCy) yielded a thermoset with a T-g of only 131 degrees C and a char yield of 65% in air. The low T-g of the MPhosCy thermoset is attributed to a unique intramolecular cyclization of the cyanate ester groups, while the high char yield is attributed to a high temperature cross-linking reaction involving the phosphate core. To further explore this class of materials, a trifunctional phosphate cyanate ester (PhosCy3) was prepared from POCl3. This material was cured to generate a thermoset with an impressive T-g of > 360 degrees C and a char yield of 67% in air. All three hybrid resins can potentially be used in fire-resistant composite materials or as protective surface coatings for conventional polymers.
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