期刊
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
卷 87, 期 1, 页码 44-48出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036024413010226
关键词
reaction mechanism; reduction; kinetics; cyanocobalamin
资金
- Russian Foundation for Basic Research [11-03-00132a]
The kinetics and mechanism of cyanocobalamin reduction by sodium hydroxymethanesulfinate and dithionite in alkaline media are studied. It is established that the character of the rate-determining step depends on the concentration of the reducing agents: when they are in excess, it is a step of elimination of cyanocobalamin, at lower concentrations of reducing agents a rate-determining is a step of their addition to cobalamin.
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