4.6 Article

Successive optimisation of waste cooking oil transesterification in a continuous microwave assisted reactor

期刊

RSC ADVANCES
卷 5, 期 94, 页码 76743-76751

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra15834f

关键词

-

资金

  1. Universiti Malaysia Pahang [GRS140304]
  2. Ministry of Higher Education for the MTUN COE grant [RDU121216]

向作者/读者索取更多资源

This paper presents an optimization study of waste cooking oil (WCO) transesterification in a continuous microwave assisted reactor (CMAR). The custom-built CMAR employed an integrated proportional-integral-derivative controller for accurate control of temperature and reactant flowrate. The fatty acid methyl ester contents in the sample were determined using gas chromatography mass spectrometry (GC-MS). The results from two-level factorial design showed that the methanol to oil molar ratio, amount of NaOCH3 catalyst and reaction time influenced markedly the biodiesel conversion, with the significance of 45.99%, 6.76% and 3.21%, respectively. Further analysis using a successive optimization method generated by the Box-Behnken design predicted an optimum biodiesel conversion of circa 97.13% at 0.68 wt% of catalyst loading, 11.62 : 1 of methanol to oil molar ratio and 4.47 min of reaction time. Experimental validation of the optimum conditions showed an excellent agreement, with a minimum deviation of 0.18% from three replicates. The biodiesel produced in this work also met the specification of ASTM D6751.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Energy & Fuels

Electro-oxidation of waste glycerol to tartronic acid over Pt/CNT nanocatalyst: study of effect of reaction time on product distribution

Muhammad Sheraz Ahmad, Chin Kui Cheng, Huei Ruey Ong, Hamidah Abdullah, Chi Shein Hong, Gek Kee Chua, Puranjan Mishra, Md Maksudur Rahman Khan

Summary: This work reported the valorization of glycerol into tartronic acid using a Pt/CNT electrocatalyst. The nanocatalyst was synthesized using a chemical reduction method with hydrazine as a reducing agent. The Pt/CNT nanoparticles exhibited high catalytic activity and selectivity.

ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS (2023)

Article Chemistry, Applied

CO2 hydrogenation to methanol at high reaction temperatures over In2O3/ ZrO2 catalysts: Influence of calcination temperatures of ZrO2 support

Thanapha Numpilai, Pinit Kidkhunthod, Chin Kui Cheng, Chularat Wattanakit, Metta Chareonpanich, Jumras Limtrakul, Thongthai Witoon

Summary: The calcination temperature of ZrO2 support plays a crucial role in the crystal structure and reducibility of In2O3, as well as in the formation of methane and methanol. Different calcination temperatures of ZrO2 support significantly affect the yield of methane and methanol.

CATALYSIS TODAY (2021)

Article Chemistry, Physical

Photoelectrocatalytic reduction of CO2 to methanol over CuFe2O4@PANI photocathode

Kaykobad Md. Rezaul Karim, Mostafa Tarek, Shaheen. M. Sarkar, Rabah Mouras, Huei Ruey Ong, Hamidah Abdullah, Chin Kui Cheng, Md. Maksudur Rahman Khan

Summary: The study successfully synthesized a hybrid photocatalyst PANI@CuFe2O4 and demonstrated its high efficiency in photoelectrocatalytic reduction of CO2 to methanol. Experimental results showed that the hybrid photocatalyst exhibited high methanol formation rate and Faradaic efficiency in the PEC CO2 reduction process.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Article Energy & Fuels

Effect of reaction conditions on the lifetime of SAPO-34 catalysts in methanol to olefins process - A review

Muhammad Sheraz Ahmad, Chin Kui Cheng, Prakash Bhuyar, A. E. Atabani, Arivalagan Pugazhendhi, Nguyen Thuy Lan Chi, Thongthai Witoon, Jun Wei Lim, Joon Ching Juan

Summary: The rising demand for light olefins production due to population growth, expanding transportation network, and rapid industrialization has made methanol-to-olefins conversion the most preferred route, although high selectivity remains a challenge. Molecular sieves have been an active commercial development area for the past two decades, as they efficiently decrease coke deposition, improve mass transport, and enhance catalytic performance in methanol to olefins reaction. SAPO-34 molecular sieves are highly selective for ethylene and propylene synthesis, exhibiting the best performance for the MTO process.
Article Chemistry, Applied

Optimisation of microwave-assisted extraction (MAE) of anthraquinone and flavonoids from Senna alata (L.) Roxb

Yi Ling Yeong, Sook Fun Pang, Aditya Putranto, Jolius Gimbun

Summary: This study investigated the optimum processing conditions of microwave assisted extraction of anthraquinone and flavonoids from Senna alata leaves, finding that MAE had a greater extraction rate compared to ultrasonic-assisted and maceration methods. The highest yields were obtained at 90.5% ethanol, 18.6 W/mL microwave power, with a desirability of 0.82, showing positive correlation between yield of compounds and antioxidant activity.

NATURAL PRODUCT RESEARCH (2022)

Editorial Material Chemistry, Physical

Recent trends in hydrogen production and utilization

Jolius Gimbun, Suwimol Wongsakulphasatch

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Article Food Science & Technology

Stability and controlled release enhancement of Labisia pumila's polyphenols

Afiqah Yeop, Jessinta Sandanasamy, Sook Fun Pang, Jolius Gimbun

Summary: The study demonstrated that the thermal stability and controlled release of Labisia pumila's polyphenols were improved by using a surface protein encapsulated microcapsule, which increased the polyphenols retention and elucidated degradation mechanisms involving decarboxylation and hydrolysis. The surface protein acted as a protective layer and enhanced polyphenols stability, while the release kinetics best fit the Hixson-Crowell model.

FOOD BIOSCIENCE (2021)

Article Engineering, Multidisciplinary

EFFECT OF FEED FLOWRATES ON THE PHYSICAL PROPERTIES AND ANTIOXIDANT OF MAHKOTA DEWA (PHALERIA MACROCARPA) ENCAPSULATED POWDER

Muhammad Norzaman Kathiman, Siti Kholijah Abdul Mudalip, Jolius Gimbun

Summary: The experimental study focused on encapsulating Mahkota Dewa extracts using maltodextrin and spray drying. Increasing feed flow rate led to larger particle size, higher moisture content, and slightly increased antioxidant activity. The study found that decreasing feed flow rate resulted in lower antioxidant activity, moisture content, and particle size.

IIUM ENGINEERING JOURNAL (2022)

Article Engineering, Chemical

A novel idea to increase the performance of a wheat flour cyclone separator: Controlling the reverse flow

Ehsan Aghaei, Vahid Rostampour, Adel Rezvanivand Fanaei, Ali M. Nikbakht, Jolius Gimbun

Summary: This study evaluated the reverse flow effect on a wheat flour cyclone performance using computational fluid dynamics simulation and experimental measurements. The results showed that the separation efficiency of wheat flour increased with increasing reverse flow levels, but decreased after a certain level.

JOURNAL OF FOOD PROCESS ENGINEERING (2023)

Article Polymer Science

Physio-Chemical and Biological Characterization of Novel HPC (Hydroxypropylcellulose):HAP (Hydroxyapatite):PLA (Poly Lactic Acid) Electrospun Nanofibers as Implantable Material for Bone Regenerative Application

S. Mary Stella, T. M. Sridhar, R. Ramprasath, Jolius Gimbun, U. Vijayalakshmi

Summary: The research on extracellular matrix (ECM) is a new and developing area focused on cell proliferation and differentiation, and aims to improve cell viability for various biomedical applications. ECM not only maintains biological functions but also exhibits properties such as controlled material degradation, cell binding, and cellular uptake for tissue engineering applications.

POLYMERS (2023)

Article Materials Science, Multidisciplinary

Effective Strengthening of RC Beams Using Bamboo-Fibre-Reinforced Polymer: A Finite-Element Analysis

Jia Ning Siew, Qi Yan Tan, Kar Sing Lim, Jolius Gimbun, Kong Fah Tee, Siew Choo Chin

Summary: This paper presents a finite-element model of RC beams with and without openings strengthened with BFRC plates. The simulation results show good agreement with experimental observations. The most successful arrangement for strengthening beams with openings is to place BFRC plates perpendicular to the crack on both sides of the beam's surface, which significantly increases the load-bearing capacity. Attaching a BFRC plate to the entire bottom soffit is the most effective method for strengthening RC beams in flexure, but it reduces the beam's ductility.

FIBERS (2023)

Article Chemistry, Multidisciplinary

Enhancing Sustainable Production of Fatty Acid Methyl Ester from Palm Oil Using Bio-Based Heterogeneous Catalyst: Process Simulation and Techno-Economic Analysis

Phonsan Saetiao, Napaphat Kongrit, Jakkrapong Jitjamnong, Chatrawee Direksilp, Chin Kui Cheng, Nonlapan Khantikulanon

Summary: A new sustainable solid carbon catalyst using pyrolytic coconut shell ash (CSA) has been developed for biodiesel synthesis. The optimum catalyst was found to be the 30 wt % K2CO3/CSA catalyst, with an obtained biodiesel yield of 97.14%. Techno-economic analysis showed a net present value of 5.16 million USD, a payback period of 2.49 years, and an internal rate of return of 44.2%. An environmental assessment revealed lower carbon dioxide emissions (1401.86 ton/y) compared to the conventional process (1784.6 ton/y).

ACS OMEGA (2023)

Article Pharmacology & Pharmacy

Fabrication of blended chitosan nanofibers by the free surface wire electrospinning

Nawzat D. AlJbour, Mohammad Dalour Hossen Beg, Jolius Gimbun, Mior Ahmad Khushairi Mohd Zahari

Summary: Nanofibers, with their small size and special characteristics, have potential applications in wound dressing, tissue engineering, and drug delivery systems. Chitosan, a natural polymer, is difficult to directly spin into nanofibers due to its high molecular weight, low solubility, and high viscosity. Blending chitosan with other polymers like polyvinyl alcohol, polycaprolactone, and Polylactic acid enhances its spinnability and produces better quality nanofibers.

PHARMACIA (2023)

Proceedings Paper Materials Science, Multidisciplinary

Synthesis and characterization of nano-hydroxyapatite/graphene oxide composite materials for medical implant coating applications

M. Kaviya, P. Ramakrishnan, S. B. Mohamed, R. Ramakrishnan, J. Gimbun, K. M. Veerabadran, M. R. Kuppusamy, K. Kaviyarasu, T. M. Sridhar

Summary: Nano-hydroxyapatite/Graphene Oxide composites were synthesized and examined for structural and morphological changes. FTIR analysis confirmed the presence of reduced graphene oxide and graphene oxide in the composite, while FE-SEM analysis confirmed the presence of graphene flakes and nanosized hydroxyapatite on the surface.

MATERIALS TODAY-PROCEEDINGS (2021)

Proceedings Paper Biotechnology & Applied Microbiology

Effect of encapsulation agents on antioxidant activity and moisture content of spray dried powder from Mahkota Dewa fruit extract

M. N. Kathiman, S. K. Abdul Mudalip, J. Gimbun

5TH INTERNATIONAL CONFERENCE OF CHEMICAL ENGINEERING AND INDUSTRIAL BIOTECHNOLOGY (ICCEIB 2020) (2020)

暂无数据