期刊
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
卷 44, 期 7, 页码 950-957出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070428008070038
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资金
- Russian Academy of Sciences
- President of the Russian Federation [NSh 5538.2008.3]
A series of new substituted gem-dibromospiropentanes was studied in a reaction with methyllithium at -55...-50 degrees C. This reaction is a carbenoid rearrangement that leads to the formation of monomeric and dimeric bromocyclobutenes and also to the products of cyclobutylidene insertion into a C-H bond of the solvent depending on the character of substituents in the dibromospiropentane fragment.
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