期刊
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
卷 46, 期 12, 页码 1353-1359出版社
PLEIADES PUBLISHING INC
DOI: 10.1134/S1023193510120037
关键词
Pt(Mo) electrodes; galvanic displacement; methanol oxidation
资金
- Russian Foundation for Basic Research [09-03-00498]
The electrocatalytic Pt-Mo system was obtained by formation of platinum particles on the Mo surface under its contact with PtC (6) (2-) (PtCl (4) (2-) ) under the open circuit conditions. Cyclic voltammograms of the obtained Pt(Mo) electrodes feature well pronounced peaks of hydrogen adsorption and desorption on Pt particles. Nonuniform platinum distribution across the electrode surface was found. Pt(Mo) electrodes showed a higher specific activity in the reaction of methanol oxidation in the potential range of 0.35-0.45 V (RHE) as compared to Pt/Pt.
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