期刊
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
卷 45, 期 11, 页码 1292-1295出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S102319350911010X
关键词
conductivity; aqueous solutions; strong electrolytes
Conductivity of concentrated aqueous solutions of strong electrolytes is analyzed in a wide range of temperatures and concentrations. The highest conductivity of solutions at a given temperature and the concentration corresponding to the highest conductivity are used as the generalizing parameters. It is shown that in the temperature range from 0 to 100 degrees C and the concentration range from 0.1 to 12 M, the values of reduced conductivity (the ratio between the conductivity and its maximum value at a given temperature) for KOH aqueous solution fall on a common curve, if the reduced concentration (the ratio between the concentration of solution and the concentration corresponding to the highest conductivity) is used as the argument. The reduced conductivities of strong acids, bases, and salts of some I-I, I-II, II-I, III-I, and II-II electrolytes fall on the same curve.
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