Article
Polymer Science
Ruchita Jani, Niall Holmes, Roger West, Kevin Gaughan, Xiaoli Liu, Ming Qu, Esther Orisakwe, Lorenzo Stella, Jorge Kohanoff, Hongxi Yin, Bartlomiej Wojciechowski
Summary: Thermoelectric materials can convert thermal energy into electrical energy, and can be used to harvest the heat energy generated by temperature differences between the inside and outside of buildings. This paper presents research on the development and characterization of a cement-based thermoelectric material, which is doped with metal oxides to enhance its thermoelectric properties. The study also discusses the positive impact of moisture content on the electrical conductivity of the material.
Review
Chemistry, Multidisciplinary
Yan Sun, Yue Liu, Ruichuan Li, Yanshuai Li, Shizheng Bai
Summary: This paper reviews the design and research progress of thermoelectric materials around lifting ZT value in recent years, discussing the optimization of carrier concentration, improvement of carrier mobility, and the influence of lattice thermal conductivity on thermoelectric performance. The synergistic effect of different dimensions, scales, and crystal structures to reduce lattice thermal conductivity is also discussed, as well as the new application of electro-acoustic decoupling in thermoelectric materials, providing practical ideas for expanding the application and scale industrialization of thermoelectric devices.
FRONTIERS IN CHEMISTRY
(2022)
Article
Chemistry, Physical
A. M. Adam, E. M. M. Ibrahim, Anshu Panbude, K. Jayabal, Pandiyarasan Veluswamy, A. K. Diab
Summary: Stoichiometric Pb1-xGexTe crystalline alloys were synthesized and their crystal structure and thermoelectric properties were investigated. Highly Ge-doped samples exhibited the highest thermoelectric power factor at high temperatures. A noticeable reduction in electronic thermal conductivity due to Ge doping was observed, which could lead to a considerable enhancement in the thermoelectric figure of merit.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Muath M. Al Malki, Xun Shi, Pengfei Qiu, G. Jeffrey Snyder, David C. Dunand
Summary: The n-type Skutterudite alloy Yb0.3Co4Sb12 exhibits plastic deformation and creep characteristics under compressive stress at 500 degrees C, showing a moderate creep resistance. The study results indicate that Yb0.3Co4Sb12 can withstand certain pressures and maintain ductility at 500 degrees C, but a decrease in electrical conductivity leads to a slight reduction in its thermoelectric performance.
JOURNAL OF MATERIOMICS
(2021)
Article
Materials Science, Ceramics
I. V. Shamsutov, A. A. Markov, O. V. Merkulov
Summary: This article discusses the development of a z-type thermoelectric element with a direct electrical junction based on dissimilar oxide conductors, Ca0.9Bi0.1MnO3 (n-type) and Ca2.7Bi0.3Co4O9 (p-type). A thermoelectric z-element was fabricated using hydrostatic pressing and an interconnector based on an oxide composite and silver particles. The microstructure of the thermoelectric legs was studied using electron microscopy. Measurements of resistivity and Seebeck coefficient were conducted, and the estimated power factor was calculated for different ceramic samples. The maximum output power of the manufactured thermoelectric module reached 1.1 mW at a temperature gradient of 580 degrees C and a cold side temperature of 37 degrees C. Additionally, simulations were performed to determine the resistance of interfaces between the thermoelectric material and interconnector. The study highlights the potential of hydrostatic pressing in producing complex-shaped thermoelectric elements without vulnerable metal-semiconductor electrical connections in oxide thermoelectric modules.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Multidisciplinary
Syed Irfan, Muhammad Aizaz Ud Din, Muhammad Qaisar Manzoor, Deliang Chen
Summary: A novel low-temperature double solvent sol-gel method was used to fabricate (Sm, Ce, Gd) and (Sn, Se, I) co-doped Bi2Te3 nanostructures, which were then hot-pressed by spark plasma sintering. The temperature of spark plasma sintering significantly affects the thermoelectric properties of bulk Bi2Te3 pellets, with the co-dopants enhancing the power factor of the nanopowders.
Article
Chemistry, Physical
D. Zhao, Q. Jiang, Y. Jia, J. Zhou, N. Zheng, D. Hu, Y. Ma
Summary: This study demonstrates the use of phenyl lithium doping to create a suspension mixed with unsubstituted NDI, which can be drop-cast to prepare dense films for TE applications. By optimizing the doping ratio, impressive electrical conductivity and Seebeck coefficient were achieved in the TE film.
MATERIALS TODAY ENERGY
(2021)
Article
Chemistry, Physical
Vikash Sharma, Divya Sharma, Ranu Bhatt, Pankaj K. Patro, Gunadhor Singh Okram
Summary: We report on the thermoelectric properties of nickel-doped Ag2-xNixTe nanostructures in a certain temperature range. The material undergoes a metal-insulator transition with increasing nickel doping concentration. The electrical resistivity and Seebeck coefficient show linear relationships with temperature. The material achieves higher thermoelectric coefficient through a sharp decrease in thermal conductivity associated with a structural phase transition.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Pradeep Kumar Sharma, T. D. Senguttuvan, V. K. Sharma, Pankaj Patro, Sujeet Chaudhary
Summary: In this study, the thermoelectric performance of PbTe compound was significantly improved through bismuth doping and dispersing SiC nanoparticles. Bismuth doping improved the electrical conductivity, while SiC nanoparticles regulated the Seebeck coefficient and suppressed the lattice thermal conductivity.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
O. Merkulov, D. Lopes, A. A. Markov, N. M. Ferreira, M. Patrakeev, A. Kovalevsky
Summary: This study explores the use of laser processing to create materials for a modular thermoelectric generator, resulting in the identification of pathways for potential performance improvements. The module exhibits promising power output but is hindered by contact resistance and impurities, highlighting the need for further optimization.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Stephane Grauby, Aymen Ben Amor, Geraldine Hallais, Laetitia Vincent, Stefan Dilhaire
Summary: With a specially designed AFM set-up, the research team has developed and validated a prototype capable of detecting both thermal and electrical properties simultaneously. AFM approach allows imaging of nanostructures and extraction of physical properties, paving the way for quantitative estimation of the figure of merit of nanostructures.
Article
Construction & Building Technology
Xiaoli Liu, Ming Qu, Alan Phong Tran Nguyen, Neil R. Dilley, Kazuaki Yazawa
Summary: The research investigates thermoelectric cement candidates for building envelope applications, studying the impact of additives graphite and MnO2, as well as two different fabrication methods (wet-mixing and dry-mixing) on thermoelectric performance. The DynaCool Physical Properties Measurement System was used to test the thermoelectric properties of candidates, revealing that the thermoelectric cement with 10% graphite and 5% MnO2 has the highest ZT value at 350 K.
CONSTRUCTION AND BUILDING MATERIALS
(2021)
Article
Chemistry, Physical
A. M. Adam, A. El-Khouly, A. K. Diab
Summary: This study demonstrates that replacing Bi atoms with Ag atoms in the n-type Bi2-xAgxSe3 system can result in higher electrical conductivity and larger Seebeck coefficient. The concerned alloys were prepared by high temperature melting, with microstructure and surface morphology identified through XRD and SEM-EDX analysis. Promising ZT values were achieved due to the high electrical conductivity and Seebeck coefficient of some doped alloys.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Engineering, Electrical & Electronic
Joao Ider, Adhimar Oliveira, Rero Marques Rubinger
Summary: Due to the rising cost of energy and the continuous development of thermoelectric materials, a new system for characterizing thermoelectric generation devices has been proposed, which can significantly reduce errors and costs.
IEEE TRANSACTIONS ON INSTRUMENTATION AND MEASUREMENT
(2021)
Review
Chemistry, Physical
Chun Zhang, Hui Li, Yalong Liu, Pengcheng Li, Siqi Liu, Chaobin He
Summary: This review summarizes recent advances in PANI/CNTs composites, including dispersion methods of CNTs, fabrication engineering, post-treatments, and multi-components composites. Various approaches are comprehensively discussed to illustrate the microstructure modulation and conduction mechanism within PANI/CNTs composites, and future prospects are given.
Article
Ophthalmology
Olivier Loria, Laurent Kodjikian, Philippe Denis, Christine Vartin, Sarra Dimassi, Lucas Gervolino, Antoine Maignan, Ronan Kermarrec, Claudine Chambard, Pierre Pradat, Thibaud Mathis
Summary: The study evaluated quantitative alterations of the choriocapillaris in swept-source optical coherence tomography angiography in diabetic patients and found a significant correlation between choroidal flow voids and DR stage. Choriocapillaris alterations were significantly increased in diabetic patients without DR compared to healthy subjects.
RETINA-THE JOURNAL OF RETINAL AND VITREOUS DISEASES
(2021)
Article
Nanoscience & Nanotechnology
Quansheng Guo, Wenhao Zhang, Zihang Liu, Xiuwei Fu, Sylvain Le Tonquesse, Naoki Sato, Hyoung-Won Son, Kiyoshi Shimamura, David Berthebaud, Takao Mori
Summary: This study reveals the significant effects of Cr single doping and Cr-Fe dual-element doping on the carrier concentration, carrier scattering mechanism, and lattice thermal conductivity of higher manganese silicides.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Physical
Antoine Maignan, Marcus Schmidt, Yurii Prots, Oleg Lebedev, Ramzy Daou, Chun-Fu Chang, Chang-Yang Kuo, Zhiwei Hu, Chien-Te Chen, Shih-Chang Weng, Simone G. Altendorf, Liu-Hao Tjeng, Yuri Grin
Summary: Synthetic crystals of ferberite FeWO4 have been grown and their properties were investigated, including magnetic, electrical and structural characteristics.
CHEMISTRY OF MATERIALS
(2022)
Article
Materials Science, Ceramics
Tatiana Aksenova, Nadezhda E. Volkova, Antoine Maignan, Vladimir A. Cherepanov
Summary: The phase equilibria in the 1/2Nd(2)O(3)-BaO-1/2Fe(2)O(3) system were studied, and the crystal structure and oxygen content of different intermediate oxides were determined. The substitution of neodymium by barium was found to decrease the oxygen content and influence the thermal properties.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2022)
Article
Chemistry, Inorganic & Nuclear
Antoine Maignan, Jacqueline-Nadine Jiongo-Dongmo, Christine Martin, O. I. Lebedev, Francoise Damay, Xiao Wang, Chang-Yang Kuo, Chun-Fu Chang, Zhiwei Hu, Liu Hao Tjeng
Summary: In this study, the Fe4-xNixNb2O9 material was analyzed using various experimental methods. It was found that the structure of the material remains unchanged as nickel substitutes for iron, but there is a decrease in the unit cell volume. Fe3NiNb2O9 has a lower antiferromagnetic transition temperature than Fe4Nb2O9, and below this temperature, its magnetization and electric polarization show a stronger dependence on magnetic field.
SOLID STATE SCIENCES
(2022)
Article
Chemistry, Inorganic & Nuclear
Sylvie Hebert, Oleg Lebedev, Antoine Maignan
Summary: A series of CuCr1-xTi1+xS4 thiospinel ceramics were synthesized and characterized. The structural characterization confirmed the spinel cubic structure and a homogeneous cation distribution. Transport properties measurements showed a sign change of the majority charge carriers near a specific x value. The materials exhibited asymmetric thermoelectric properties and magnetoresistance depending on composition and temperature.
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
(2022)
Article
Chemistry, Inorganic & Nuclear
Antoine Maignan, Christine Martin
Summary: The structural, magnetic and magnetoelectric properties of a newly synthesized member, Co2Fe2Ta2O9, were studied. Despite having structural features intermediate between Co4Ta2O9 and Fe4Ta2O9, the compound exhibited a very different magnetoelectric behavior. A comparison between different compounds was proposed to reveal the influence of different M and M' pairs on the properties.
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
(2022)
Article
Materials Science, Multidisciplinary
Subarna Das, P. Singha, Ramzy Daou, Oleg Lebedev, Sylvie Hebert, Antoine Maignan, Aritra Banerjee
Summary: Te-impurity-incorporated Sb2Te3 composites were synthesized, and the doping of Te and suppression of Te vacancies resulted in a lower carrier concentration and an increased Seebeck coefficient. Despite the increase in electrical resistivity due to Te impurities, the charge carrier mobility remained stable due to enhanced lattice texturing. The addition of Te also led to strong phonon scattering, reducing the thermal conductivity and achieving a high ZT value.
PHYSICAL REVIEW MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Vanessa Proust, Quentin Kirscher, Thi Kim Ngan Nguyen, Lisa Obringer, Kento Ishii, Ludivine Rault, Valerie Demange, David Berthebaud, Naoki Ohashi, Tetsuo Uchikoshi, Dominique Berling, Olivier Soppera, Fabien Grasset
Summary: The objective of this study was to develop simple and easy methods to prepare polymorphic HfO2 thin film materials with the best balance of patterning potential, reproducibility and stability. Nanostructured HfO2 thin films were synthesized by two different methods: deep ultraviolet (DUV) photolithography and electrophoretic deposition (EPD) of HfO2 nanoparticles. The morphology, composition and crystallinity of the HfO2 nanoparticles and thin films were investigated, and the results showed that both DUV photolithography and EPD are suitable methods to prepare controllable and tunable HfO2 nanostructures.
Article
Physics, Applied
Juan P. Bolletta, Francois Fauth, Christine Martin, Antoine Maignan
Summary: This study investigates the magnetization reversal behavior of Ni4Nb2O9 and its dependence on non-magnetic Zn substitution. The results show that Zn substitution can control magnetization reversal in Ni4Nb2O9 and cause counterintuitive changes in its magnetic properties.
JOURNAL OF APPLIED PHYSICS
(2022)
Article
Chemistry, Inorganic & Nuclear
Sylvie Hebert, Raul Carbonio, Christine Martin, Antoine Maignan
Summary: The T-dependent Seebeck (S) of Sr2Fe1+xRe1-xO6 series samples (x <= 0.33) was investigated. These polycrystalline samples crystallize in the I4/m double perovskite structure. The decrease of magnetization with increasing x is explained by cation disorder, while the change in S sign and the positive magneto Seebeck effect are attributed to the spin polarized transport of these double-perovskite materials.
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
(2023)
Article
Chemistry, Multidisciplinary
Meiqi Zhang, Fabien Grasset, Yuji Masubuchi, Toshihiro Shimada, Thi Kim Ngan Nguyen, Noee Dumait, Adele Renaud, Stephane Cordier, David Berthebaud, Jean-Francois Halet, Tetsuo Uchikoshi
Summary: The Mo cluster-MoS2 composite was synthesized through a one-step sulfurization process using H2/H2S gas flow. The decomposed Mo-6 cluster iodides acted as a template and precursor, forming complex Mo cluster compounds and eventually producing MoS2. After sulfurization, the response of the composite to NH3 gas increased three times while showing conversion from p-type to n-type semiconductor, enhancing its potential for device applications.
Article
Materials Science, Multidisciplinary
Hanen Abdelli, Houeida Issa Hamoud, Juan Pablo Bolletta, Arnold Paecklar, Afrah Bardaoui, Krassimir L. Kostov, Ewelina Szaniawska, Antoine Maignan, Christine Martin, Mohamad El-Roz
Summary: A highly efficient CuFe2O4-based photocatalyst is reported for the photo-catalytic dehydrogenation of formic acid under visible light at room temperature. The catalyst exhibits high selectivity and stability, making it a promising material for photocatalytic dehydrogenation. This study provides a new route to design cost-effective Cu-based photocatalysts for visible-light driven reactions.
APPLIED MATERIALS TODAY
(2023)
Article
Materials Science, Multidisciplinary
J. N. Jiongo-Dongmo, J. P. Bolletta, A. Maignan, F. Damay, C. Martin
Summary: Ni4Nb2O9 and Co4Nb2O9 have different structures derived from corundum and exhibit distinct magnetic and electrical properties. The ferrimagnetism associated with magnetization reversal of Ni4Nb2O9 and the antiferromagnetism combined with the magnetic field control of polarization of Co4Nb2O9 are of interest for applications in spintronics. This study explores the Ni4-xCoxNb2O9 series to generate exotic magnetic ground states due to competing magnetic exchanges caused by the framework of the O-6 octahedra. The stability domains of each structure, as well as the evolution of structural and physical properties, are investigated, leading to the establishment of a (T, x) phase diagram.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Materials Science, Multidisciplinary
Juan P. Bolletta, Gabriel J. Cuello, Vivian Nassif, Emmanuelle Suard, Alexander Kurbakov, Antoine Maignan, Christine Martin, Raul E. Carbonio
Summary: Rare-earth orthoferrites provide a flexible platform for magnetic materials design, with magnetic properties arising from the interactions between R3+ and Fe3+ ions. SmFeO3 exhibits a unique high-temperature spin reorientation, which can be tuned to occur at room temperature by replacing Sm with Tm in the Sm0.70Tm0.30FeO3 compound. This study demonstrates the control of magnetic properties by small changes in composition within the Sm1-xTmxFeO3 series. Neutron powder diffraction was used to investigate the magnetic structure of a samarium-based perovskite using 152Sm, resulting in the construction of a magnetic phase diagram.