Biodiesel from mutton fat using KOH impregnated MgO as heterogeneous catalysts

The use of MgO impregnated with KOH as heterogeneous catalysts for the transesterification of mutton fat with methanol has been evaluated. The mutton fat (fat) with methanol (1:22 M ratio) at 65 degrees C showed > 98% conversion to biodiesel with 4 wt% of MgO-KOH-20(1) (MgO impregnated with 20 wt% of KOH) in 20 min. The reaction conditions optimized were: the amount of KOH impregnation (5-20 wt%), the amount of catalyst (1.5-4 wt%, catalyst/fat), the reaction temperature (45-65 degrees C), fat to methanol molar ratio (1:11-1:22) and the effect of addition of water/oleic acid/palmitic acid (upto 1 wt%). Although, transesterification of fresh fat (moisture content 0.02 wt% and free fatty acids 0.002 wt%) with methanol in the presence of KOH (homogenous catalyst) resulted in the complete conversion to biodiesel, but in the presence of additional 1 wt% of either free fatty acid or moisture content, formation of soap was observed. The MgO-KOH-20 catalyst was found to tolerate additional 1 wt% of either the moisture or FFAs in the fat. (C) 2011 Elsevier Ltd. All rights reserved.