期刊
RARE METALS
卷 27, 期 2, 页码 158-164出版社
NONFERROUS METALS SOC CHINA
DOI: 10.1016/S1001-0521(08)60107-2
关键词
lithium-ion battery; layered transition metal oxide; sol-gel process; high capacity
To obtain homogenous layered oxide Li(Co1/3Ni1/3Mn1/3)O-2 as a lithium insertion positive electrode material, the sol-gel process using citric acid as a chelating agent was applied. The material Li(Co1/3Ni1/3Mn1/3)O-2 was synthesized at different calcination temperatures. XRD experiment indicated that the layered Li(Co1/3Ni1/3Mn1/3)O-2 material could be synthesized at a lower temperature of 800 degrees C, and the oxidation state of Co, Ni, and Mn in the cathode confirmed by XPS were +3, +2, and +4, respectively. SEM observations showed that the synthesized material could form homogenous particle morphology with the particle size of about 200 nm. In spite of different calcination temperatures, the charge-discharge curves of all the samples for the initial cycle were similar, and the cathode synthesized at 900 degrees C showed a small irreversible capacity loss of 11.24% and a high discharge capacity of 212.2 mAh(.)g(-1) in the voltage range of 2.9-4.6 V.
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