期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 5, 期 4, 页码 2441-2448出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cy00004a
关键词
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资金
- National Natural Science Foundation of China [21428301, 21373038]
- Fundamental Research Funds for the Central Universities [DUT13RC(3)41]
- Postdoctoral Science Foundation of China [2013M541220]
A series of metallic Re/C catalysts were prepared with the microwave-assisted thermolytic method by using decacarbonyldirhenium [Re-2(CO)(10)] as a precursor for the hydrogenation of succinic acid. The results of FT-IR, UV-Vis, XRD, HRTEM, ICP, TPR and CO chemical adsorption showed that the as-prepared catalysts had well-dispersed rhenium nanoparticles on activated carbon. Changing irradiation time or rhenium loadings could effectively adjust the properties of Re/C catalysts which exhibited good catalytic performance for the hydrogenation of succinic acid. There were plenty of active sites on Re/C catalysts for the high concentration hydrogenation of succinic acid, and increasing temperature or pressure improved catalytic activity at a defined scope. From the kinetic study of succinic acid catalytic hydrogenation, there was a certain converting relationship between the different intermediates and the product distribution which could be controlled by variation of reaction time.
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