4.6 Article

Polystyrene trimethyl ammonium chloride impregnated Rh(0) (Rh@PMe3NCl) as a catalyst and methylating agent for esterification of alcohols through selective oxidation of methanol

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CATALYSIS SCIENCE & TECHNOLOGY
卷 5, 期 5, 页码 2575-2580

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cy00002e

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  1. CSIR, New Delhi [CSC-0108]
  2. UGC

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Rhodium(0) nanoparticle (NP)-impregnated polystyrene trimethyl ammonium chloride (PMe3NCl) resin (Rh@PMe3NCl) under basic conditions acts as a cross-dehydrogenative coupling-methylating (CDCM) agent for the selective oxidation of methanol and its in situ reaction with benzyl/alkyl alcohols allowing methyl group transfer for acetate ester synthesis in a tandem approach. The redox property of methanol which restricts the oxidation of benzyl/alkyl alcohols for product formation is critically investigated.

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