In-depth structure–selectivity investigations on asymmetric, copper-catalyzed oxidative biaryl coupling in the presence of 5-cis-substituted prolinamines

The Biocatalytic Repertoire of Natural Biaryl Formation

(2014) Hülya Aldemir et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Atroposelective Aldol Condensation: Synthesis of Axially Chiral Biaryls by Arene Formation

(2014) Achim Link et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Axially Chiral Biaryls through Sulfoxide-Directed Asymmetric Mild CH Activation and Dynamic Kinetic Resolution

(2014) Chinmoy Kumar Hazra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

(2S,5R)-2-Methylaminomethyl-1-methyl-5-phenylpyrrolidine, a chiral diamine ligand for copper(ii)-catalysed Henry reactions with superb enantiocontrol

(2014) Dagmar Scharnagel et al.   CHEMICAL COMMUNICATIONS

Access to Optically Active 3-Substituted Piperidines by Ring Expansion of Prolinols and Derivatives

(2014) Domingo Gomez Pardo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Flexible and Modular Syntheses of Enantiopure 5-cis-Substituted Prolinamines from l-Pyroglutamic Acid

(2014) Matthias Breuning et al.   SYNTHESIS-STUTTGART

Enantioselective oxidative-coupling of polycyclic phenols

(2014) Shinobu Takizawa et al.   TETRAHEDRON

Enantioselective Synthesis of Axially Chiral Biaryl Monophosphine Oxides via Direct Asymmetric Suzuki Coupling and DFT Investigations of the Enantioselectivity

(2014) Yougui Zhou et al.   ACS Catalysis

Toward a mechanistic understanding of oxidative homocoupling: the Glaser–Hay reaction

(2014) Jesús Jover et al.   Catalysis Science & Technology

Enantioselective Oxidative Coupling of 2-Naphthol Derivatives by Copper-(R)-1,1′-Binaphthyl-2,2′-diamine-TEMPO Catalyst

(2013) Santosh Kumar Alamsetti et al.   ADVANCED SYNTHESIS & CATALYSIS

Aerobic Copper-Catalyzed Organic Reactions

(2013) Scott E. Allen et al.   CHEMICAL REVIEWS

Metal-complexes of optically active amino- and imino-based pyridine ligands in asymmetric catalysis

(2013) Giorgio Chelucci   COORDINATION CHEMISTRY REVIEWS

5-Substituted Derivatives of the Tricyclic (+)-Sparteine Surrogate in the Enantioselective Lithiation/Stannylation of anO-Alkyl Carbamate

(2013) Matthias Breuning et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Developments in Meyers’ Lactamization Methodology: En Route to Bi(hetero)aryl Structures with Defined Axial Chirality

(2013) Svetlana Postikova et al.   JOURNAL OF ORGANIC CHEMISTRY

Efficient Syntheses of Korupensamines A, B and Michellamine B by Asymmetric Suzuki-Miyaura Coupling Reactions

(2013) Guangqing Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Aryl–Aryl Bond Formation: An Atroposelective [3,3]-Rearrangement Approach to BINAM Derivatives

(2013) Gong-Qiang Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of (+)-Davidiin

(2012) Yusuke Kasai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Winding up Alkynes: A Pd-Catalyzed Tandem-Domino Reaction to Chiral Biphenyls

(2012) Markus Leibeling et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition-Metal-Free Atropo-Selective Synthesis of Biaryl Compounds Based on Arynes

(2012) Frédéric R. Leroux et al.   CHEMISTRY-A EUROPEAN JOURNAL

Phosphino Hydrazones as Suitable Ligands in the Asymmetric Suzuki–Miyaura Cross-Coupling

(2012) Abel Ros et al.   JOURNAL OF ORGANIC CHEMISTRY

Divergent Approach to the Bisanthraquinone Natural Products: Total Synthesis of (S)-Bisoranjidiol and Derivatives from Binaphtho-para-quinones

(2012) Erin E. Podlesny et al.   JOURNAL OF ORGANIC CHEMISTRY

Total Synthesis of (±)-Decinine via an Oxidative Biaryl Coupling with Defined Axial Chirality

(2012) Zhen-Hua Shan et al.   ORGANIC LETTERS

Enantioselective Total Synthesis of (S)-Bisoranjidiol, an Axially Chiral Bisanthraquinone

(2012) Erin E. Podlesny et al.   ORGANIC LETTERS

Atroposelective Heck Macrocyclization: Enantioselective Synthesis of Bis(bibenzylic) Natural Products

(2012) Matthias Groh et al.   ORGANIC LETTERS

Palladium(II)-catalyzed asymmetric cycloisomerization of enynes for axially chiral biaryl construction

(2012) Nobuaki Kadoya et al.   TETRAHEDRON LETTERS

Theoretical and spectroscopic studies on the conformational equilibrium of 9-oxabispidines in solution

(2011) Matthias Breuning et al.   JOURNAL OF MOLECULAR STRUCTURE

Enantioselective Synthesis of Axially Chiral Hydroxy Carboxylic Acid Derivatives by Rhodium-Catalyzed [2 + 2 + 2] Cycloaddition

(2011) Shuichiro Ogaki et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Chiral and Modifiable Hexahydroxydiphenoyl Compounds

(2011) Noriaki Asakura et al.   JOURNAL OF ORGANIC CHEMISTRY

N-Heterocyclic Pyridylmethylamines: Synthesis, Complexation, Molecular Structure, and Application to Asymmetric Suzuki–Miyaura and Oxidative Coupling Reactions

(2011) Guillaume Grach et al.   ORGANOMETALLICS

Development of New N,N-Ligands for the Enantioselective Copper(II)-Catalyzed Henry Reaction

(2011) Gonzalo Blay et al.   SYNLETT

First example of an atropselective dehydro-Diels–Alder (ADDA) reaction

(2011) Pablo Wessig et al.   TETRAHEDRON LETTERS

Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products

(2010) Gerhard Bringmann et al.   CHEMICAL REVIEWS

Bis(μ-oxo) Dicopper(III) Species of the Simplest Peralkylated Diamine: Enhanced Reactivity toward Exogenous Substrates

(2010) Peng Kang et al.   INORGANIC CHEMISTRY

Enantioselective Synthesis of Axially Chiral Biaryls by the Pd-Catalyzed Suzuki−Miyaura Reaction: Substrate Scope and Quantum Mechanical Investigations

(2010) Xiaoqiang Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioenriched Synthesis ofC1-Symmetric BINOLs: Iron-Catalyzed Cross-Coupling of 2-Naphthols and Some Mechanistic Insight

(2010) Hiromichi Egami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Biphenols from 1,4-Diketones by Traceless Central-to-Axial Chirality Exchange

(2010) Fenghai Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Kinetic Resolution of Biaryl Atropisomers via Peptide-Catalyzed Asymmetric Bromination

(2010) J. L. Gustafson et al.   SCIENCE

Total synthesis of chiral biaryl natural products by asymmetric biaryl coupling

(2009) Marisa C. Kozlowski et al.   CHEMICAL SOCIETY REVIEWS

Chiral 2-endo-Substituted 9-Oxabispidines: Novel Ligands for Enantioselective Copper(II)-Catalyzed Henry Reactions

(2009) Matthias Breuning et al.   CHEMISTRY-A EUROPEAN JOURNAL

Perylenequinone Natural Products: Enantioselective Synthesis of the Oxidized Pentacyclic Core†

(2009) Carol A. Mulrooney et al.   JOURNAL OF ORGANIC CHEMISTRY

Perylenequinone Natural Products: Evolution of the Total Synthesis of Cercosporin

(2009) Barbara J. Morgan et al.   JOURNAL OF ORGANIC CHEMISTRY

Perylenequinone Natural Products: Total Synthesis of Hypocrellin A

(2009) Erin M. O’Brien et al.   JOURNAL OF ORGANIC CHEMISTRY

Perylenequinone Natural Products: Total Syntheses of the Diastereomers (+)-Phleichrome and (+)-Calphostin D by Assembly of Centrochiral and Axial Chiral Fragments

(2009) Barbara J. Morgan et al.   JOURNAL OF ORGANIC CHEMISTRY

Design, Synthesis, and Investigation of Protein Kinase C Inhibitors: Total Syntheses of (+)-Calphostin D, (+)-Phleichrome, Cercosporin, and New Photoactive Perylenequinones

(2009) Barbara J. Morgan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Asymmetric Aerobic Oxidation: Oxidative Coupling of 2-Naphthols

(2009) Hiromichi Egami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Stereochemistry Transfer in a Transannular Aldol Reaction: Total Synthesis of Hypocrellin A

(2008) Erin M. O'Brien et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Flexible Route to Chiral 2-endo-Substituted 9-Oxabispidines and Their Application in the Enantioselective Oxidation of Secondary Alcohols

(2008) Matthias Breuning et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Study of Asymmetric Oxidative Biaryl Coupling: Evidence for Self-Processing of the Copper Catalyst to Achieve Control of Oxidase vs Oxygenase Activity

(2008) J. Brian Hewgley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Bicyclo[2.2.2]octenones Using a Copper-Mediated Oxidative Dearomatization/[4 + 2] Dimerization Cascade1

(2008) Suwei Dong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis acid-assisted oxidative cross-coupling of 2-naphthol derivatives with copper catalysts

(2008) Pei Yan et al.   TETRAHEDRON

Dual activation in oxidative coupling of 2-naphthols catalyzed by chiral dinuclear vanadium complexes

(2008) Shinobu Takizawa et al.   TETRAHEDRON