期刊
PURE AND APPLIED CHEMISTRY
卷 84, 期 4, 页码 869-878出版社
WALTER DE GRUYTER GMBH
DOI: 10.1351/PAC-CON-11-09-15
关键词
alkynes; alkyne metathesis; carbon; carbon-rich; depolymerization; macrocycles; explosives
资金
- NSF [CHE-1010680, CBET-0730667]
- DHS [2009-ST-108-LR0005]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0931466, 1010680] Funding Source: National Science Foundation
This report details the advances in synthetic strategies toward arylene-ethynylene macrocycles (AEMs). After a brief description of traditional methods, we summarize recent advances based on dynamic covalent chemistry (DCC) whereby a highly active and functional group tolerant alkyne metathesis catalyst yields scalable quantities of AEMs under thermodynamic controlled reaction conditions.
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