期刊
PURE AND APPLIED CHEMISTRY
卷 81, 期 12, 页码 2327-2335出版社
WALTER DE GRUYTER GMBH
DOI: 10.1351/PAC-CON-08-11-23
关键词
iron phthalocyanine; magnetically separable; photocatalysis; nanocomposite; repetitive use; visible light
A novel magnetically separable photocatalyst iron phthalocyanine/Fe3O4 (FePc/Fe3O4) nanocomposite was easily prepared by an organic-inorganic complexation technique, and characterized by transmission electron microscopy (TEM), X-ray powder diffraction (XRD), and Fourier transform-infrared (FTIR). This functional nanocomposite has been found to exhibit high catalytic activity in the presence of added hydrogen peroxide, for oxidative degradation of methylene blue (MB) under visible light irradiation. Under these conditions, MB (10 mg/l) underwent about 78 % oxidation in 2 h, and the catalyst still retained high activity after five catalytic cycles. Intervening recovery was easily achieved by changing the external magnetic field.
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