期刊
PURE AND APPLIED CHEMISTRY
卷 80, 期 5, 页码 855-860出版社
INT UNION PURE APPLIED CHEMISTRY
DOI: 10.1351/pac200880050855
关键词
homogeneous catalysis; supramolecular chemistry; self-assembly; hydroformylation; asymmetric hydrogenation
Inspired by the principle of DNA base-pairing, a new concept for the self-assembly of molecular catalysts is described herein. Thus, employing A-T analogous complementary hydrogen-bonding templates, self-assembly of monodentate to bidentate ligands in the coordination sphere of a transition-metal salt occurs to give defined self-assembly catalysts. This approach is intrinsically combinatorial and allows the facile generation of defined catalyst libraries through simple component mixing. From the study of these ligand libraries, excellent catalysts for linear-selective hydroformylation, asymmetric hydrogenation, and anti-Markovnikov hydration of terminal alkynes have emerged.
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