Cation-Promoted Supramolecular Assembly of Bivalent Metal Tetra-15-Crown-5-Phthalocyaninates: Controlling the Architecture of Supramolecular Aggregates

Cation-promoted supramolecular assembly of cobalt(II) and ruthenium(II) tetra-15-crown-5-phthalocyaninates is comparatively studied using the electronic absorption and infrared spectroscopy. The effects of the nature of the receptor and substrate on the architecture of the supramolecular aggregates formed are discovered. By contrast to Cu(II), Zn(II), and Ni(II) tetra-15-crown-5-phthalocyaninates, Co(II) and Ru(II) complexes are found to demonstrate sodium-potassium selectivity determined by the peculiarities of supramolecular structures formed upon the interaction with the cations. DOI: 10.1134/S2070205111040083