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The effect of lignin on the structure and characteristics of composite coatings electrodeposited on titanium

期刊

PROGRESS IN ORGANIC COATINGS
卷 75, 期 4, 页码 275-283

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.porgcoat.2012.07.005

关键词

Electrophoretic deposition; Composite coating; Organosolv lignin; Hydroxyapatite; Titanium; Cytotoxicity

资金

  1. Ministry of Education and Science of the Republic of Serbia [III 45019, OI 175011, III 45015]
  2. National Sciences and Engineering Research Council of Canada (NSERC)

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Composite coatings based on lignin, obtained by electrophoretic deposition (EPD) on titanium, were investigated. The aim of this work was to produce hydroxyapatite/lignin (HAP/Lig) coatings on titanium and to investigate the effect of the lignin concentration on microstructure, morphology, phase composition, thermal behavior and cytotoxicity of the HAP/Lig coatings. An organosolv lignin was used for the production of the composite coatings studied in this research. The properties of HAP/Lig coatings were characterized using X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), thermogravimetric analysis (TGA), attenuated total reflection Fourier transform infrared spectroscopy (ATR-FT-IR) and X-ray photoelectron spectroscopy (XPS), as well as the MTT test of cytotoxicity. The results showed that higher lignin concentrations protected the HAP lattice during sintering, thereby improving the stability of the HAP/Lig coatings. The cell survival of peripheral blood mononuclear cells (PBMC) after proliferation indicates that the HAP/Lig coating with 1 wt% Lig electrodeposited on titanium was non-toxic with significant promise as a potential bone-repair material. (C) 2012 Elsevier B.V. All rights reserved.

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