Article
Materials Science, Multidisciplinary
Ozge Varlik, Yapincak Goncu, A. Y. Nuran
Summary: Titanium diboride-chitosan composite coatings were successfully produced by electrophoretic deposition techniques. The effect of process parameters on the coatings was investigated and the suspension properties and deposition mechanism were discussed. The results showed that the coatings had a uniform and crack-free morphology, and the chitosan content significantly affected the adhesion behavior.
MATERIALS CHEMISTRY AND PHYSICS
(2022)
Article
Materials Science, Coatings & Films
Sandeep Singh, Gurpreet Singh, Niraj Bala
Summary: The study fabricated a composite coating of CS-HA-BG-Fe3O4 with bioactivity, high corrosion resistance, and excellent cell proliferation, suitable for biomedical applications.
SURFACE & COATINGS TECHNOLOGY
(2021)
Article
Materials Science, Multidisciplinary
Sri Rahmadani, Anawati Anawati, Muhammad Dikdik Gumelar, Razie Hanafi, I. Nyoman Jujur
Summary: Bioactive hydroxyapatite (HA) coating was successfully applied on commercially pure Ti using electrophoretic deposition (EPD), with the 30 V coating showing the best corrosion resistance due to high HA grain density and low corrosion current density.
MATERIALS RESEARCH EXPRESS
(2022)
Article
Polymer Science
Claudio Zanca, Bernardo Patella, Elisa Capuana, Francesco Lopresti, Valerio Brucato, Francesco Carfi Pavia, Vincenzo La Carrubba, Rosalinda Inguanta
Summary: Calcium phosphate/chitosan/collagen composite coating on AISI 304 stainless steel was investigated for its protective behavior and biocompatibility.
Article
Materials Science, Multidisciplinary
Claudio Zanca, Alessandro Milazzo, Simona Campora, Elisa Capuana, Francesco Carfi Pavia, Bernardo Patella, Francesco Lopresti, Valerio Brucato, Vincenzo La Carrubba, Rosalinda Inguanta
Summary: The potential of calcium phosphate/Bioglass composite coatings on AISI 316L as beneficial coatings for orthopedic implants was investigated. These coatings were fabricated through galvanic co-deposition of calcium phosphate compounds and Bioglass particles. The effect of different amounts of Bioglass on the performance of the coatings was studied. The coatings exhibited good protection against corrosion and proved to be biocompatible.
Article
Chemistry, Applied
Sandeep Singh, Gurpreet Singh, Niraj Bala
Summary: In this study, iron oxide particles were combined with hydroxyapatite to produce a coating that enhanced the antimicrobial and bioactive properties of magnesium implants. The composite coating was found to be blood compatible and could potentially be widely utilized in biomedical implant applications.
PROGRESS IN ORGANIC COATINGS
(2021)
Review
Chemistry, Physical
Marija Djosic, Ana Jankovic, Vesna Miskovic-Stankovic
Summary: Current trends in biomaterials science focus on designing multifunctional implant coatings that can inhibit bacterial growth while promoting osseointegration to ensure prolonged implant functionality.
Article
Materials Science, Multidisciplinary
Arman Molaei, MardAli Yousefpour
Summary: Composite coatings of chitosan-bioglass-hydroxyapatite-halloysite nanotube were successfully produced by electrophoretic deposition, demonstrating good corrosion resistance and apatite-inducing ability in corrected simulated body fluid.
Article
Materials Science, Ceramics
Weiwei Han, Li Liu, Benrui Yu, Qingxia Zhu
Summary: Graphene oxide (GO)/hydroxyapatite (HA) composite coatings were successfully prepared on titanium substrates using electrophoretic deposition technology. The coating's microstructure, phase composition, adhesion strength, hydrophilicity, corrosion resistance, bioactivity, antibacterial activity, and biocompatibility were evaluated. The adhesive strength of the coating increased by 76% when the GO content increased from 0 wt% to 12 wt%, and the corrosion rate reached its minimum at (1.493 x 10-3mm/a) with 8 wt% GO. Biomineralization experiments demonstrated the excellent bioactivity of the GO/HA composite coatings. The water contact angle of the composite coatings increased from 20.6 degrees (0 wt% GO) to 38.1 degrees (12 wt% GO). The antibacterial rate of the coating with 5 wt% GO was 96.7%, but decreased to 25% after thermal treatment. In-vitro L929 cell culture experiments confirmed the biocompatibility of the composite coatings with 5 wt% GO.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Ceramics
Jingpei Zhu, Chuanwei Fan, Conghui Ning, Wei Wang
Summary: HA-rGO-ZnO ternary composite coatings were successfully prepared on ZK60 magnesium alloy by cathodic electrophoretic deposition method. The addition of ZnO nanoparticles reduced the crystallinity of hydroxyapatite and improved the corrosion resistance and bioactivity of the coatings.
CERAMICS INTERNATIONAL
(2023)
Article
Multidisciplinary Sciences
Sagar V. Kanhere, Graham W. Tindall, Amod A. Ogale, Mark C. Thies
Summary: This study investigates the conversion of lignin from poplar into carbon fibers and its importance. The researchers found that the Aqueous Lignin Purification with Hot Agents (ALPHA) process could effectively purify and fractionate hybrid poplar lignin. The resulting high molecular weight fraction had very low sugar and ash content, and could be spun into stable carbon fibers. The strength and modulus of these carbon fibers were double those achieved with neat poplar lignin, and the stabilization time was reduced by a factor of five.
Article
Chemistry, Physical
Filip Maciag, Tomasz Moskalewicz, Kazimierz Kowalski, Alicja Lukaszczyk, Zoya Hadzhieva, Aldo Roberto Boccaccini
Summary: In this study, zein coatings were successfully obtained on titanium substrates by electrophoretic deposition, with the coating morphology being significantly influenced by the zein content, water to ethanol ratio, process voltage, and time. Chemical treatment of the Ti substrate surface prior to deposition was found to enhance the adhesion of the coatings. Coated titanium substrates exhibited slightly lower electrochemical corrosion resistance in aqueous solution compared to uncoated substrates, and showed well-developed surface topography and hydrophilic nature.
Article
Engineering, Biomedical
Kaori Iwanami-Kadowaki, Tetsuo Uchikoshi, Masayoshi Uezono, Masanori Kikuchi, Keiji Moriyama
Summary: EPD is a simple, rapid, and inexpensive technique for uniform coatings with controlled thicknesses. The modified EPD technique using Mg2+ ions successfully coated HAp/Col on a Ti substrate with controlled thickness, drastically increasing adhesive strength compared to non-Mg2+ EPD coating. The new coating showed potential for applications in instruments requiring rapid osseointegration at the bone-implant surface.
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A
(2021)
Article
Materials Science, Coatings & Films
GwangHee Lee, Mi-Jin Jin, Kun-Jae Lee
Summary: The deliberate control of titanium surfaces, such as crack-free and white-color coatings, is crucial for a wide range of titanium applications. By using electrophoretic deposition (EPD) method with different particle sizes of BaSO4 and TiO2, a crack-free white BaSO4-TiO2 coating with high density was achieved on the titanium surface. The crack-free coating was achieved by reducing the shrinkage stress per unit volume acting on the coating.
SURFACE & COATINGS TECHNOLOGY
(2021)
Article
Materials Science, Multidisciplinary
M. E. Aksoy, B. Aksakal, N. Aslan, B. Dikici
Summary: In this study, boron-doped hydroxyapatite (B-HAp) biocomposites were synthesized and applied as coatings to metallic implants using electrophoretic deposition (EPD). The results showed that the highest adhesion strength and corrosion resistance were achieved with 15 wt.% B-HAP coating at 120 s deposition time and 76.5 mu m coating thickness.
JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE
(2021)
Article
Chemistry, Applied
Julijana D. Tadic, Jelena M. Ladarevic, Zeljko J. Vitnik, Vesna D. Vitnik, Tatjana P. Stanojkovic, Ivana Z. Matic, Dusan Z. Mijin
Summary: This study synthesized seven novel azo dyes and investigated their structures and biological reactivity through experimental and theoretical approaches. Compound 5 showed potential as an antioxidant and anticancer agent, with concentration-dependent cytotoxicity against cancer cell lines and no permeation to the blood brain barrier.
Article
Biotechnology & Applied Microbiology
Ivana Z. Matic, Sercan Ergun, Marija Dordic Crnogorac, Sema Misir, Yuksel Aliyazicioglu, Ana Damjanovic, Hurija Dzudzevic-Cancar, Tatjana Stanojkovic, Kalbiye Konanc, Nina Petrovic
Summary: The study investigated the anticancer activities of extracts obtained from Hypericum perforatum, with extract 6 showing the highest cytotoxic activity. These extracts induced apoptosis in HeLa cells through activation of caspase-3 and greatly reduced the expression levels of specific genes. Flower extracts may have a stronger impact on miRNA level changes compared to branch-body extracts.
Review
Chemistry, Physical
Marija Djosic, Ana Jankovic, Vesna Miskovic-Stankovic
Summary: Current trends in biomaterials science focus on designing multifunctional implant coatings that can inhibit bacterial growth while promoting osseointegration to ensure prolonged implant functionality.
Review
Electrochemistry
Samira Naghdi, Vesna Miskovic-Stankovic
Summary: Graphene coatings deposited by chemical vapour deposition (CVD) on different metal substrates have shown significant improvement in corrosion resistance, making them an ideal choice for corrosion protection.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Nevena Stevanovic, Mima Jevtovic, Dragana Mitic, Ivana Matic, Marija Dordic Crnogorac, Miroslava Vujcic, Dusan Sladic, Bozidar Cobeljic, Katarina Andelkovic
Summary: This study characterized a previously synthesized Cu(II) complex and investigated its biological activities, including cytotoxicity, antioxidant properties, and DNA binding abilities. The results provided insights into the potential anticancer mechanisms of the Cu(II) complex.
JOURNAL OF THE SERBIAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Applied
Katarina Nesovic, Vesna Miskovic-Stankovic
Summary: This study aimed to analyze silver release from electrochemically synthesized antibacterial silver nanoparticles loaded poly(vinyl alcohol) hydrogels for wound dressing applications, showing potential in antibacterial activity assessment against Staphylococcus aureus and Escherichia coli bacterial strains.
JOURNAL OF VINYL & ADDITIVE TECHNOLOGY
(2022)
Article
Biochemistry & Molecular Biology
Violeta M. Milutinovic, Ivana Z. Matic, Tatjana P. Stanojkovic, Marina D. Sokovic, Ana D. Ciric, Ljubos J. Usjak, Marjan S. Niketic, Silvana D. Petrovic
Summary: The antimicrobial and cytotoxic activities of different herbs and their compounds were tested. The extracts showed inhibition against various microorganisms and cancer cells.
CHEMISTRY & BIODIVERSITY
(2022)
Article
Engineering, Biomedical
Maja D. Markovic, Julijana D. Tadic, Sanja Savic, Ivana Z. Matic, Tatjana P. Stanojkovic, Dusan Z. Mijin, Vesna V. Panic
Summary: This study investigates the potential of a hydrophilic carrier based on poly(methacrylic acid) and casein for encapsulation and controlled release of a novel poorly water-soluble compound. The results show that the carrier has great potential for application in leukemia treatment.
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A
(2022)
Article
Biochemistry & Molecular Biology
Nenad Jankovic, Emilija Milovic, Jelena Dorovic Jovanovic, Zoran Markovic, Milan Vranes, Tatjana Stanojkovic, Ivana Matic, Marija Dordic Crnogorac, Olivera Klisuric, Miroslav Cvetinov, Syed Nasir Abbas Bukhari
Summary: The novel Biginelli hybrids and their ruthenium(II) complexes were synthesized and evaluated for their cytotoxic effects on cancer cells and virus. Two compounds were found to induce apoptosis in cancer cells, while showing significant inhibition against SARS-CoV-2 M-pro. This opens up a new avenue for the design of dual-active drugs with anticancer and antiviral properties.
CHEMICO-BIOLOGICAL INTERACTIONS
(2022)
Article
Biochemistry & Molecular Biology
Teodora Vitomirov, Filitsa Dimiza, Ivana Z. Matic, Tatjana Stanojkovic, Andrea Pirkovic, Lada Zivkovic, Biljana Spremo-Potparevic, Irena Novakovic, Katarina Andelkovic, Milos Milcic, George Psomas, Maja Sumar Ristovic
Summary: This article reports on the cytotoxicity, genotoxicity, and interaction with DNA and proteins of two Cu(II) complexes with a salicylaldehyde derivative and alpha-diimine. The complexes exhibited cytotoxic effects against malignant cell lines, with the Cu(II) complex with phen showing higher cytotoxicity than the one with bipy. The complexes induced apoptosis through activation of specific caspases and showed antioxidant and antigenotoxic effects. They also demonstrated the ability to intercalate with CT DNA and bind reversibly and tightly to albumins.
JOURNAL OF INORGANIC BIOCHEMISTRY
(2022)
Article
Pharmacology & Pharmacy
Vesna Miskovic-Stankovic, Marko Janev, Teodor M. Atanackovic
Summary: This study introduces a new two compartmental model with a recently defined General fractional derivative, and applies it to the study of gentamicin release in poly (vinyl alcohol)/gentamicin hydrogel. The model has the advantage of introducing new parameters in the definition of the fractional derivative.
JOURNAL OF PHARMACOKINETICS AND PHARMACODYNAMICS
(2023)
Article
Multidisciplinary Sciences
Veronica Anastasoaie, Ovidiu Teodor Matica, Cecilia Lete, Raluca Isopescu, Vesna Miskovic-Stankovic, Eleonora-Mihaela Ungureanu
Summary: Previous studies have demonstrated the complexing properties of 2-(azulen-1-yldiazenyl)-5-phenyl-1,3,4-thiadiazole (T) towards heavy metals (HMs) in solution. T can also be attached to electrode surfaces to form chemically modified electrodes (T-CMEs). The films of T-CMEs exhibited insulating properties with a thickness of approximately 10 μm, an active surface area about 6 times larger than the geometrical one, and a conductivity of about 10(-6) S/cm. Voltammetric techniques revealed the reversible anodic and cathodic redox CV peaks for the polymer, while spectroelectrochemistry showed intensified charge transport through polarons due to the anodic polarization of the film.
Article
Microbiology
Jerome Vanheuverzwijn, Eloise-Eliane Maillard, Amal Mahat, Lee Fowler, Daniel Monteyne, Leila Bonnaud, Nicolas Landercy, Axel Hemberg, Ana Jankovic, Franck Meyer, Vesna Miskovic-Stankovic, Milena Stevanovic, Codruta Mirica, David Perez-Morga, Reto Luginbuehl, Christele Combes, Gabriel Furtos, Veronique Fontaine
Summary: This research aimed to develop an easy, robust, quantitative assay to evaluate the surface antimicrobial activities of medical implants. The study identified that the 5 cent Euro coin or other metal-based antibacterial coins could be used as positive controls due to their significant reduction in bacterial survival. These methods and controls provide a useful tool for assessing the antimicrobial activities of new implant materials.
Article
Mathematics, Interdisciplinary Applications
Vesna Miskovic-Stankovic, Teodor M. M. Atanackovic
Summary: A novel two-compartment model for drug release was proposed, using general fractional derivatives of a specific type and distributed order. Earlier models in pharmacokinetics with fractional derivatives are special cases of the proposed model. The model was applied to study the release of gentamicin from different hydrogels and coatings, and showed good agreement with experimental data. The form of the general fractional derivatives used in the model improves the approximation of experimental data with a slightly more complex numerical procedure.
FRACTAL AND FRACTIONAL
(2023)
Article
Biochemistry & Molecular Biology
Ivana Z. Matic, Ana Mrakovic, Zlatko Rakocevic, Milovan Stoiljkovic, Vladimir B. Pavlovic, Tatjana Momic
Summary: This study synthesized novel luteolin capped gold nanoparticles (AuNPL) and investigated their anticancer effects on HeLa cells. The results showed that AuNPL exhibited selective cytotoxicity against cancer cells compared to normal cells. They induced cell cycle arrest and apoptosis in HeLa cells and demonstrated antioxidative and cytoprotective properties.
JOURNAL OF TRACE ELEMENTS IN MEDICINE AND BIOLOGY
(2023)
Article
Chemistry, Applied
Heena, Komal Sharma, Kamlesh Kumar, Bhargab Das, Raj Kumar
Summary: In this study, holographic films were prepared using an automatic film applicator, and their performance was compared with films prepared by other methods. The results showed that holographic films prepared with the automatic film applicator had higher diffraction efficiency and more uniform thickness, making them suitable for holographic applications.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Athira S. Vijayan, Antony Joseph, Abey Joseph, T. S. Abhijith, Baiju G. Nair, V. Sajith
Summary: Novel polydopamine functionalized ceria-zirconia nanoparticles filled water-borne epoxy nanocomposite coatings were developed to prevent microbial-induced corrosion of mild steel. The coatings exhibited exceptional anti-biofouling and anti-biocorrosion properties due to the synergistic effect of PDA functionalization and zirconium incorporation, providing significant enhancement in charge transfer resistance and coating resistance.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Yudan Yi, Qingyong Sun, Qijun Li, Bi Shi, Ya-nan Wang
Summary: Producing metal-free leather is an effective approach to eliminate Cr pollution and achieve sustainable development of the leather industry. However, current metal-free tanning technologies have limitations in terms of water sorption and charge properties. By using cationic amphiphilic acrylic copolymers (PSD) as retanning agents, the properties of metal-free leather can be significantly improved, including enhanced hydrophobicity, better dye absorption, and excellent filling effect.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Yunqing Xia, Lifen Tong, Xiaofang Feng, Hubing Xiang, Yi He, Xiaobo Liu
Summary: By incorporating functionalized nanofillers, such as polydopamine-modified graphitic carbon nitride and cerium oxide, into epoxy coatings, their corrosion resistance can be improved and their protective period can be extended.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Weineng Lu, Guanhao Ma, Jinqing Qu
Summary: Four novel bis-chalcone-based carbazole derivative photoinitiators were designed and synthesized in this study. Their maximum absorption wavelengths were determined and found to exhibit high molar extinction coefficients. Furthermore, a three-component photoinitiation system including bis-chalcone/iodonium/amine was successfully used to trigger the rapid and efficient photopolymerization of acrylates. The photoinitiators also showed good photo bleaching and biocompatibility, making them suitable for applications such as 3D printing and deep coating curing.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Xingnan Zhou, Shixian Zhang, Yiheng Song, Hongmei Qin, Chuanxi Xiong, Shan Wang, Quanling Yang, Delong Xie, Rong Fan, Dan Chen
Summary: In this study, eco-friendly 3-amino-1,2,4-triazole (ATA) molecules were used to modify graphene oxide (GO) nanosheets for improving the anti-corrosion performance of water-borne epoxy (WEP) coating. The results show that ATA modification enhances the dispersion of GO in the polymer coating and significantly improves the barrier effect.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Hao Fu, Wei Bing, Xushibojie Liu
Summary: In this study, temperature-sensitive coatings with bacteria-killing and bacteria-releasing functions were prepared on silicone rubber surfaces by UV polymerization and UV photocatalysis. The modified surface exhibited strong and persistent bactericidal effect, inhibiting the formation of bacterial biofilm. Moreover, the smart surface can effectively release bacteria and resist bacterial adhesion through temperature changes. The modified silicone rubber surface showed good biocompatibility without cytotoxicity.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Lee Eyann, Zulkifli Mohamad Ariff, Mohamad Danial Shafiq, Raa Khimi Shuib, Muhamad Sharan Musa
Summary: By investigating the effect of MAA addition on the properties of the WEA core-shell emulsion, film and coating, it was found that MAA can significantly impact the structure and performance of the coatings, and has great potential for applications.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Jinkyu Choi, Kyung Hoon Min, Byeong Seok Kim, Sung-Hyeon Baeck, Sang Eun Shim, Yingjie Qian
Summary: A novel phosphorus-based flame retardant was designed by incorporating aryl groups, which effectively improved the flame retardancy and mechanical properties of polyurethanes.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Saowaluk Taechutrakul, Thananchai Piroonpan, Beata Paulina Rurarz, Slawomir Kadlubowski, Piotr Ulanski, Wanvimol Pasanphan
Summary: This study proposes the use of nanogels to disperse and stabilize water-insoluble organic pigment particles in water-based inks. The nanogels were prepared using electron beam-induced chemical reactions and showed good dispersion and stabilization properties. The use of nanogels in ink formulation improved the ink's hiding power, lightfastness, and resistance properties.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Shan Wan, Huikai Chen, Bokai Liao, Xingpeng Guo
Summary: In this study, 2-amino-5 mercapto-1,3,4-thiadiazole (ATT) was used as an intercalating agent to prepare ATT/BNNS nanofillers via a liquid-phase assisted ultrasound method. TEM results showed that ATT successfully exfoliated BNNS and reduced agglomeration. The WEP ATT/BNNS coating exhibited the best protective performance under saline immersion due to the combined action of ATT inhibitor and BNNS physical barrier.
PROGRESS IN ORGANIC COATINGS
(2024)
Review
Chemistry, Applied
Lijie Yin, Bo Zhang, Ming Tian, Nanying Ning, Wencai Wang
Summary: This paper reviews the recent progress in the synthesis of bio-based waterborne polyurethanes (BWPU) and focuses on its applications in coatings, adhesives, and antimicrobials. BWPU has attracted much attention due to its good physical and chemical properties, no VOCs emissions, exploitation of renewable substances, and structural design-ability.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Yuyang Zhou, Yang Chen, Xinming Cao, Haodong Fu, Yun Li, Yonghui Zhang, Jun Ma, Xin Liu
Summary: This study proposes a strategy to fabricate a high-strength double-layer superhydrophobic actuator, which consists of a metal/glass-based superhydrophobic substrate and a polymer superhydrophobic coating. The coating has high adhesive strength, self-cleaning, anti-ultraviolet irradiation, and anti-stripping properties, along with photothermal and magnetic response capabilities, enabling its application in various fields.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Fengbiao Chen, Fei Gao, Xinru Guo, Yu Chen, Xuelang Gao, Liang Shen
Summary: In this study, various covalent adaptable networks (CANs) were synthesized using multifunctional amines and compared with CANs prepared from primary and secondary amines. The results showed that the performance of CANs is closely related to the crosslinking density, and increasing the content of secondary amines improves the performance but weakens the dynamics.
PROGRESS IN ORGANIC COATINGS
(2024)
Article
Chemistry, Applied
Qian Zhang, Mengyi Shen, Xingcai Liu, Hao Fu, Wenbo Yang, Jinyuan Zhao, Jian Wang, Yaping Du, Chunjie Ma
Summary: Rare earth-containing corrosion inhibitors were successfully synthesized and added into epoxy coatings for the anti-corrosion of steel materials. The results showed that the coatings with rare earth elements had better anti-corrosion performance, and this difference in performance could be explained by the inherent properties of rare earth elements.
PROGRESS IN ORGANIC COATINGS
(2024)