期刊
PROGRESS IN ORGANIC COATINGS
卷 72, 期 3, 页码 517-521出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.porgcoat.2011.06.011
关键词
Benzophenone; Photoinitiator; Free radical polymerization
资金
- Changzhou microelectronics chemical material public technology platform
- Natural Science Foundation of Jiangsu Province [BK2010190]
Benzophenone-di-1,3-dioxane (BP-DDO), a novel photoinitiator for free radical polymerization, was synthesized and characterized. The photopolymerization kinetics of BP-DDO was studied by real-time infrared spectroscopy (FT-IR). When this photointiator was used to efficiently initiate polymerization of acrylates and rnethacrylates, there was an optimum cure rate with the increase in BP-DDO concentration. Both the polymerization rate and final conversion increased with the increase in light intensity. The kinetics study of photopolymerization of TMPTA showed that BP-DDO was a more effective photoinitiator than benzophenone and benzophenone/ethyl-4-dimethylaminobenzoate (EDAB). (C) 2011 Elsevier B.V. All rights reserved.
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