期刊
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING
卷 51, 期 14, 页码 1483-1486出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/03602559.2012.715710
关键词
Conductive polymer composites; Graphene nanosheets; Percolation threshold; Segregated structure
资金
- State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Dong Hua University [LK1006]
- NSF of China [21176158, U1162131, 20976112]
This article reports a novel conductive ultrahigh-molecular-weight polyethylene (UHMWPE) composite with a segregated and double percolated structure, in which graphene nanosheets (GNSs) form prefect conductive pathways in the high-density polyethylene (HDPE) and the GNS/HDPE component forms continuous conductive layers at the interface between the UHMWPE granules. The combination of segregated and double-percolated GNS conductive network achieved an ultralow percolation of 0.05 vol. %. Structural observations and the determination of the critical exponent t-value obtained from the classical threshold mechanism indicate the formation of a two-dimensional GNS network in GNS/HDPE/UHMWPE composites. Comparison of the electrical performance of GNS and CNT-filled segregated composites indicated that the geometry of the conductive nanoparticles can greatly affect the dimensionality of the segregated conductive network.
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