期刊
POLYMER DEGRADATION AND STABILITY
卷 109, 期 -, 页码 367-372出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymdegradstab.2014.05.031
关键词
Itaconic acid; Bioplastics; Polyamides; Heterocycles; Biodegradation
资金
- [24655099]
- Grants-in-Aid for Scientific Research [24655099] Funding Source: KAKEN
Highly-thermostable but degradable polyamides have been synthesized by a polycondensation of bio-derived itaconic acid salts with aromatic diamines to form heterocyclic pyrrolidone ring in the polymer backbone. The molecular weight was greater than 33,600 g/mol. Glass transition temperatures, T-g, and 10% weight loss temperatures, T-10, ranged 156-242 degrees C and 370-400 degrees C, respectively, which were higher than those of conventional bio-based plastics. However their processability was too low to process the fiber as specimens of mechanical tests. We then incorporated an appropriate amount of aliphatic moiety into the aromatic backbones to prepare the high-performance and processable polyamides with T-g over 115 degrees C and T-10 over 355 degrees C. The processed fibers showed tensile strength and Young's modulus ranged 20-58 MPa and 0.2-2.3 GPa, respectively. The degradation behaviors inside soil and under ultraviolet-irradiation in water were additionally found. (C) 2014 Elsevier Ltd. All rights reserved.
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