期刊
POLYMER CHEMISTRY
卷 5, 期 3, 页码 712-717出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3py01442h
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资金
- Catalysis Research Center (CRC)
- Sumitomo Foundation
- Asahi Glass Foundation
- JSPS Research Fellowships for Young Scientists [25-2727]
- Japan Society for the Promotion of Science
- Grants-in-Aid for Scientific Research [13J02727, 24685023, 13J10001] Funding Source: KAKEN
An alternating copolymer consisting of achiral and chiral units emits remarkably efficient CPL on photo-excitation. The main-chain twist bias is enhanced by thermal annealing by the factor of 10(4) in the ground state. An anisotropy factor of the polymer in the excited state is greater by approximately an order of magnitude compared with that in the ground sate.
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