期刊
POLYMER CHEMISTRY
卷 5, 期 10, 页码 3379-3388出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3py01574b
关键词
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资金
- National Basic Research Program of China [2012CB025901]
- State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Dong Hua University, China
In this work, we report an elegant design of novel graft copolymers based on two natural abundant biopolymers with opposite physical properties: rigid and hydrophilic cellulose, and flexible and hydrophobic synthesized polyisoprene (analogue of natural rubber), which combines rigidity and flexibility, hydrophobicity and hydrophilicity all in one macromolecule. These cellulose-graft-polyisoprene (Cell-g-PI) copolymers were synthesized via homogenous supplemental activator and reducing agent atom transfer radical polymerization (SARA ATRP). FT-IR, H-1 NMR, C-13 NMR and TGA measurements demonstrate that Cell-g-PI copolymers are successfully prepared. TEM and DMA results illustrate that phase separation occurs in Cell-g-PI copolymers. Water contact angle measurements verify that their hydrophobicity increases with increasing polyisoprene side chain length. In addition, the core-shell Cell-g-PI nanoparticles in water can be prepared via a self-organized precipitation (SORP) method.
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