期刊
POLYMER CHEMISTRY
卷 5, 期 21, 页码 6325-6333出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4py00647j
关键词
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资金
- EPSRC [EP/F057865/1, EP/H000925]
- E.ON [EP/C511794/1]
- Engineering and Physical Sciences Research Council [EP/F057865/1, EP/C511794/1, EP/K039687/1] Funding Source: researchfish
- EPSRC [EP/K039687/1] Funding Source: UKRI
We discuss in detail the mechanism of formation of a highly microporous polymer, CMP-1, formed mainly via Sonogashira-Hagihara coupling. We demonstrate how the microporosity evolves with time, and discuss the importance of alkyne homo-coupling on the microporosity.
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