期刊
POLYMER CHEMISTRY
卷 4, 期 8, 页码 2384-2394出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2py20987j
关键词
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资金
- National Natural Science Foundation of China [50873029, 20974117, 51073042, 51103026]
- Shanghai Natural Science Funds [11ZR1403100]
- Shanghai Scientific and Technological Innovation Project [11JC1400600, 10431903000]
- Shanghai Rising Star Program [12QB1402900]
- Specialized Research Fund for the Doctoral Program of Higher Education [20110071120006]
The aim of this review is to summarize and highlight the rapidly expanding area of nitroxide radical coupling reactions, including atom transfer nitroxide radical and single electron transfer nitroxide radical coupling reactions, in polymer and material synthesis. Initial discussion is focused on the influencing factors, e.g. temperature, solvent, catalyst and the structure of reactant, on the reaction rate and efficiency. In addition, this review attempts to demonstrate the broad applications of nitroxide radical coupling reactions on the terminal functionalization of polymers, the synthesis of polymers with complex and well-defined architecture, and the preparation of organic-inorganic composites. Finally, the current challenges and future directions of nitroxide radical coupling reactions are also discussed.
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