期刊
POLYMER
卷 50, 期 19, 页码 4438-4446出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2009.07.022
关键词
Polybetaines; Polymer support; Amino acids
资金
- EXPERTISSUES Network of Excellence (NoE)
- Spanish Ministry of Ciencia e Innovacion [MAT2007-63355, CTQ2007-67403/BQU]
The synthesis of two new types of methacrylic polybetaines bearing trans-4-hydroxy-L-proline connected via its hydroxyl group is described, one with an aliphatic spacer of 6 carbon atoms and the other without any spacer. The pH sensitivity in aqueous media and the catalytic activity of the products in asymmetric aldol additions have been studied. The two polyzwitterions show an isoelectric point (IEP) close to 3. Swelling of networks prepared with the two monomers exhibit reversible pH sensitivity; the largest the pH distance from the IEP, the higher the net charge (positive or negative) and the higher the swelling. At basic pH and an ionic strength of 0.15, maximum swelling degrees of around 11 and 24 (g water/g polymer) have been found for the systems with and without spacer respectively. The polymers have been shown to be efficient catalysts for aldol reactions under homogeneous conditions in DMF but not in water. (C) 2009 Elsevier Ltd. All rights reserved.
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