期刊
CHEMICAL SCIENCE
卷 6, 期 5, 页码 3044-3050出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5sc00221d
关键词
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资金
- National Institutes of Health [GM110382]
- Georgia State University
- NSFC [21272027]
- China Scholarship Council
An iron-catalyzed enantioselective and diastereoselective intramolecular olefin aminochlorination reaction is reported (ee up to 92%, dr up to 15 : 1). In this reaction, a functionalized hydroxylamine and chloride ion are utilized as nitrogen and chlorine sources, respectively. This new method tolerates a range of synthetically valuable internal olefins that are all incompatible with existing asymmetric olefin aminochlorination methods.
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