New laboratory measurements of CH4 in Titan's conditions and a reanalysis of the DISR near-surface spectra at the Huygens landing site

Laboratory spectra of methane-nitrogen mixtures have been recorded in the near-infrared range (1.0-1.65 mu m) in conditions similar to Titan's near surface, to facilitate the interpretation of the DISR/DLIS (DISR-Descent Imager/Spectral Radiometer) spectra taken during the last phase of the descent of the Huygens Probe, when the surface was illuminated by a surface-science lamp. We used a 0.03 cm(-1) spectral resolution, adequate to resolve the lines at high pressure (P-N2 similar to 1.5 bar). By comparing the laboratory spectra with synthetic calculations in the well-studied v(2)+2(v)3 band (7515-7620cm(-1)), we determine a methane absorption column density of 178 +/- 20 cm atm and a temperature of 118 +/- 10 K in our experiment. From this, we derive the methane absorption coefficients over 1.0-1.65 mu m with a 0.03 cm(-1) sampling, allowing for the extrapolation of the results to any other methane column density under the relevant pressure and temperature conditions. We then revisit the calibration and analysis of the Titan lamp-on DLIS spectra. We infer a 5.1 +/- 0.8% methane-mixing ratio in the first 25 m of Titan's atmosphere. The CH4 mixing ratio measured 90 s after landing from a distance of 45cm is found to be 0.92 +/- 0.25 times this value, thus showing no post-landing outgassing of methane in excess of similar to 20%. Finally, we determine the surface reflectivity as seen between 25 m and 45 cm and find that the 1500 nm absorption band is deeper in the post-landing spectrum as compared to pre-landing. (C) 2007 Elsevier Ltd. All rights reserved.