期刊
PHYSICAL REVIEW E
卷 81, 期 4, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevE.81.041503
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资金
- RFBR [09-02-91351]
- Presidium of RAS
- Deutsche Forschungsgemeinschaft [436 RUS113/992/0]
Nearly all glass-forming liquids feature, along with the structural alpha-relaxation process, a faster secondary process (beta relaxation), whose nature belongs to the great mysteries of glass physics. However, for some of these liquids, no well-pronounced secondary relaxation is observed. A prominent example is the archetypical glass-forming liquid glycerol. In the present work, by performing dielectric spectroscopy under superhigh pressures up to 6 GPa, we show that in glycerol a significant secondary relaxation peak appears in the dielectric loss at P > 3 GPa. We identify this beta relaxation to be of Johari-Goldstein type and discuss its relation to the excess wing. We provide evidence for a smooth but significant increase in glass-transition temperature and fragility on increasing pressure.
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