Article
Materials Science, Ceramics
Yun Sun, Jiangtao Wu, Ying Tang, Huaicheng Xiang, Jie Li, Liang Fang
Summary: X-ray diffractometer with Rietveld refinement and Raman spectroscopy were used for phase analysis. Ca doping leads to a decrease in epsilon(r), Q × f, and tau(f), which does not conform to the mutual constraint relationship among the three parameters of microwave dielectric properties. The epsilon(r) of Ce1-xCaxO2-x ceramics is affected by the ion polarizability and the rattling and valence states of Ce cations, with rattling playing a dominant role. The presence of oxygen vacancies in Ce1-xCaxO2-x ceramics explains the decrease in Q × f, and tau(epsilon), epsilon(r), and alpha(L) are responsible for the decrease in tau(f), especially for the tau(alpha m)-3 alpha(L) values.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2023)
Article
Materials Science, Ceramics
Junqi Chen, Zhiwei Zhang, Peili Qing, Jingjing An, Jinwu Chen, Liang Fang
Summary: In this study, garnet structured Ca3Yb2Ge3O12 ceramics were synthesized and their structural and dielectric properties were investigated. The results showed that the Yb3+ ion entered the B-sites and affected the bond lengths, the Ca cation had a critical effect on the dielectric constant, and the Ge-O bond was the main factor influencing the dielectric loss.
CERAMICS INTERNATIONAL
(2023)
Review
Materials Science, Multidisciplinary
R. D. dos Reis, L. S. Veiga, G. Fabbris, F. Garcia, D. Haskel, F. C. G. Gandra, N. M. Souza-Neto
Summary: By using x-ray absorption spectroscopy at Eu and Pt L-3 edges, we investigated the effects of lattice contraction induced by temperature and external pressure on the magnetic and electronic properties of the EuPt2Si2 system. Our study found a clear relationship between the volume and Eu valence in this material. From XANES experiments under pressure, we showed that the Europium valence tends to stabilize at 3+ for pressures up to 27 GPa. The XMCD results demonstrated that the pressure-induced valence change of the Europium ion leads to a suppression of the magnetic ordering of the material. Overall, our results provide direct evidence that Eu-4f/5d electronic hybridization effects control the valence and magnetic ordering in this material.
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Tetsu Watanuki, Masaichiro Mizumaki, Shinji Watanabe, Naomi Kawamura, Kiyofumi Nitta, Akihiko Machida, Tsutomu Ishimasa
Summary: In this paper, the temperature dependence of Yb valence in an Au-Al-Yb intermediate-valence quasicrystal is investigated. The results show that the Yb valence increases as the temperature decreases, consistent with the anomalous suppression of thermal shrinkage reported previously. The effect of the Yb valence changes on the volume is also quantitatively analyzed.
MATERIALS TRANSACTIONS
(2022)
Article
Physics, Applied
B. Tegomo Chiogo, N. P. Martin, L. V. B. Diop, B. Malaman, D. Malterre, F. Baudelet, L. Nataf, T. Mazet
Summary: The crystal structure and valence state of a non-stoichiometric YbMnSi compound were investigated using room-temperature x-ray diffraction and temperature / pressure-dependent x-ray absorption experiments. The results showed that the valence state of Yb is temperature independent and relatively low, which is inconsistent with the presence of local magnetism. Under pressure, the valence state of Yb increases continuously but remains far from trivalency.
JOURNAL OF APPLIED PHYSICS
(2022)
Article
Chemistry, Inorganic & Nuclear
Lee Shelly, Danielle Schweke, Albert Danon, Brian Ashley Rosen, Shmuel Hayun
Summary: In this study, the reduction-oxidation properties of Ce1-x U x O2 & PLUSMN;& delta; (with x & GE; 0.25) mixed oxides were explored. The oxygen extracted from these mixed oxides comes from a different source compared to CeO2, leading to a higher oxygen storage capacity and lower activation energy. These mixed oxide powders exhibit structural stability under reducing and oxidizing conditions and can be used as catalysts for thermochemical water splitting or as solid electrolytes in solid oxide fuel cells.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Dayu Huang, Qiuyun Ouyang, Hui Xiao, Bo Wang, Hongzhou Lian, Qingguang Zeng, Jun Lin
Summary: A novel NIR garnet-type phosphor, Ca2LaHf2Al3O12:Cr3+, has been synthesized, which demonstrated a broadening of NIR spectra by doping Yb3+ in the phosphor and reducing thermal quenching through energy transfer of Cr3+ -> Yb3+. The study also successfully fabricated a NIR pc-LED with Ca2LaHf2Al3O12:Cr3+,Yb3+ phosphor, showing great potential in super broadband NIR pc-LED applications.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Applied
Cristina Artini, Sabrina Presto, Massimo Viviani, Sara Massardo, Maria Maddalena Carnasciali, Lara Gigli, Marcella Pani
Summary: The experimental investigation of the Ce1-x(Nd0.74Tm0.26)(x)O2-x/2 doped ceria system revealed correlations between structural features and ionic conductivity, including the presence of two distinct conduction regimes with different activation energies and the formation of 1V(O)2Tm(Ce) trimers at lower temperatures. This study also showed larger cell parameters and a wider compositional extent compared to Sm-doped ceria.
JOURNAL OF ENERGY CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Guillaume Vidon, Pia Dally, Mirella Al-Katrib, Daniel Ory, Minjin Kim, Etienne Soret, Eva Rangayen, Marie Legrand, Alexandre Blaizot, Philip Schulz, Jean-Baptiste Puel, Daniel Suchet, Jean-Francois Guillemoles, Arnaud Etcheberry, Muriel Bouttemy, Stefania Cacovich
Summary: Understanding the effects of X-rays on halide perovskite thin films is crucial for accurate characterization and practical usage of these materials in detection systems. This study utilizes advanced optical imaging techniques to comprehensively understand the degradation mechanism occurring in the material during photoemission spectroscopy measurements. The findings highlight the impact of X-rays on the perovskite layers, providing valuable insights for investigations using X-ray based techniques and the development of perovskite-based X-ray detectors and solar cells for space applications.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Physics, Condensed Matter
S. Yamanaka, M. Hikiji, C. Michioka, H. Ueda, K. Yoshimura
Summary: We have successfully grown single crystals of a novel ytterbium-based layered compound Yb4RuGe8 and investigated its structural, magnetic, thermal, and transport properties. The magnetic susceptibility exhibits a broad peak due to the Kondo effect at around 40 K, and is enhanced below 15 K due to the development of additional magnetic correlations. Analysis using the grand-Kadowaki-Woods relation indicates that the low-temperature state, apart from the effect of the additional magnetic correlations, is a heavy-mass Fermi liquid.
JOURNAL OF PHYSICS-CONDENSED MATTER
(2023)
Review
Chemistry, Multidisciplinary
Paul M. Donaldson, Greg M. Greetham, Chris T. Middleton, Bradley M. Luther, Martin T. Zanni, Peter Hamm, Amber T. Krummel
Summary: Ultrafast spectroscopy and imaging have become essential tools for scientists in various fields. The commercialization of advanced spectrometers, such as transient absorption spectrometers and vibrational sum frequency generation spectrometers, has made these measurements available to non-experts in ultrafast spectroscopy. The shift to new Yb-based lasers offers exciting new possibilities in the chemical and physical sciences, with higher efficiency and improved noise characteristics.
ACCOUNTS OF CHEMICAL RESEARCH
(2023)
Article
Chemistry, Physical
M. B. Sreedhara, Kristyna Bukvisova, Azat Khadiev, Daniel Citterberg, Hagai Cohen, Viktor Balema, Arjun K. Pathak, Dmitri Novikov, Gregory Leitus, Ifat Kaplan-Ashiri, Miroslav Kolibal, Andrey N. Enyashin, Lothar Houben, Reshef Tenne
Summary: Misfit layered compound nanotubes have attracted significant interest due to their rich chemistry and unique quasi-1D structure. By tuning the chemical and structural interplay between different sublayers and alloying of elements, the properties of these nanotubes can be engineered for desired performance. A study on SmS-TaS2 nanotubes reveals their complex structure at the atomic scale and confirms the charge transfer and filling phenomenon. The investigation provides insights into the properties and potential applications of misfit layered compound nanotubes.
CHEMISTRY OF MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Guangda Wu, Xiaoqin Yin, Pingzhang Yu, Mengdi Fan, Fapeng Yu, Shuzhen Fan, Zhengping Wang, Xian Zhao
Summary: This paper reports on a novel Yb-doped strontium yttrium phosphate crystal with a disordered structure, detailing its crystal growth, structure, spectral properties, and laser performance. The crystal shows potential for multi-wavelength laser operation and terahertz source development.
Article
Chemistry, Physical
A. Magnette, L. Eichenberger, L. V. B. Diop, G. Venturini, L. Nataf, F. Baudelet, A. Verniere, T. Mazet
Summary: The magnetic structures of HoFe6Sn6-type (Immm) YbMn6-yFeySn6 alloys were determined using powder neutron diffraction experiments. The valence state and local magnetism of Yb were investigated with XANES and XMCD. Fe doping decreased the mean Yb valence and changed the spins arrangement of the 3d sublattice by reinforcing antiferromagnetic exchange interactions.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Materials Science, Multidisciplinary
Chia-Ping Su, Kari Ruotsalainen, Alessandro Nicolaou, Matteo Gatti, Alexandre Gloter
Summary: A real-space and reciprocal-space electron-energy-loss spectroscopy (EELS) investigation is performed on SVO bulk and nanostructures. It is found that a strong 1.35 eV excitation is attributed to a bulk plasmonic excitation from the 3d-t(2g) orbitals. Calculations done within a time-dependent density functional theory framework reveal the quantitative reproduction of this plasmon energy and dispersion.
ADVANCED OPTICAL MATERIALS
(2023)
Article
Chemistry, Physical
Lucia Perez Ramirez, Fabrice Bournel, Jean-Jacques Gallet, Lenart Dudy, Francois Rochet
Summary: In this article, the authors demonstrate the real-time monitoring of the oxidation process on aluminum surface using near-ambient pressure X-ray photoemission spectroscopy. They validate the central assumption of the Cabrera-Mott model and discuss the adsorption of oxygen anions at the oxide/gas interface. The study also addresses the impact of realistic conditions, such as water coadsorption, on the oxidation reaction.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Review
Chemistry, Physical
Duncan Atkins, Elixabete Ayerbe, Anass Benayad, Federico G. Capone, Ennio Capria, Ivano E. Castelli, Isidora Cekic-Laskovic, Raul Ciria, Lenart Dudy, Kristina Edstrom, Mark R. Johnson, Hongjiao Li, Juan Maria Garcia Lastra, Matheus Leal De Souza, Valentin Meunier, Mathieu Morcrette, Harald Reichert, Patrice Simon, Jean-Pascal Rueff, Jonas Sottmann, Wolfgang Wenzel, Alexis Grimaud
Summary: Understanding the phenomena at the electrode/electrolyte interfaces is crucial for improving battery technologies. Advances in simulations/modeling techniques and characterization approaches, especially for Li-ion batteries, are key in addressing future challenges. Implementation of unified workflow and collaborative initiatives are essential for unlocking the full investigative potential and meeting societal and environmental imperatives in this domain.
ADVANCED ENERGY MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Judith Gabel, Matthias Pickem, Philipp Scheiderer, Lenart Dudy, Berengar Leikert, Marius Fuchs, Martin Stuebinger, Matthias Schmitt, Julia Kuespert, Giorgio Sangiovanni, Jan M. Tomczak, Karsten Held, Tien-Lin Lee, Ralph Claessen, Michael Sing
Summary: Thin films of transition metal oxides are affected by oxygen adatoms on the surface, leading to the formation of an electronically dead surface layer and altering the band filling and electron correlations. It is important to consider the presence of surface apical oxygen when predicting the behavior of ultrathin films of transition metal oxides.
ADVANCED ELECTRONIC MATERIALS
(2022)
Review
Chemistry, Physical
J. D. Denlinger, J-S Kang, L. Dudy, J. W. Allen, Kyoo Kim, J-H Shim, K. Haule, J. L. Sarrao, N. P. Butch, M. B. Maple
Summary: The study investigates the relationship between narrow-band states and bulk Fermi surface topology in URu2Si2 using ARPES mapping of the electronic structure. It reveals the interaction between these states and other band states, and provides insight into the properties and temperature evolution of high symmetry points and nested Fermi-edge states, supporting the understanding of the hidden order transition.
ELECTRONIC STRUCTURE
(2022)
Article
Physics, Multidisciplinary
J. Choi, Q. Wang, S. Joehr, N. B. Christensen, J. Kuespert, D. Bucher, D. Biscette, M. H. Fischer, M. Huecker, T. Kurosawa, N. Momono, M. Oda, O. Ivashko, M. Zimmermann, M. Janoschek, J. Chang
Summary: In the cuprates, the unidirectional nature of the CDW in La1.88Sr0.12CuO4 was established using x-ray diffraction with uniaxial pressure. A significant enhancement of the CDW amplitude was found when homogeneous superconductivity was partially suppressed by a magnetic field.
PHYSICAL REVIEW LETTERS
(2022)
Article
Multidisciplinary Sciences
T. Weber, D. M. Fobes, J. Waizner, P. Steffens, G. S. Tucker, M. Bohm, L. Beddrich, C. Franz, H. Gabold, R. Bewley, D. Voneshen, M. Skoulatos, R. Georgii, G. Ehlers, A. Bauer, C. Pfleiderer, P. Boeni, M. Janoschek, M. Garst
Summary: The study found that the motion of a spin excitation in materials with nontrivial magnetic order is deflected, similar to the effect of the Lorentz force on a charged particle in an orbital magnetic field. By using neutron scattering, researchers investigated the propagation of magnons in a lattice of skyrmion tubes in manganese silicide and discovered a topological magnon band structure in reciprocal space.
Article
Multidisciplinary Sciences
Qisi Wang, K. von Arx, D. G. Mazzone, S. Mustafi, M. Horio, J. Kuspert, J. Choi, D. Bucher, H. Wo, J. Zhao, W. Zhang, T. C. Asmara, Y. Sassa, M. Mansson, N. B. Christensen, M. Janoschek, T. Kurosawa, N. Momono, M. Oda, M. H. Fischer, T. Schmitt, J. Chang
Summary: A study finds that mild uniaxial pressure can change the ordering pattern of stripes and pin them to the crystal axis. This change may have an impact on superconductivity and could be a key prerequisite for the coexistence of stripes and superconductivity.
NATURE COMMUNICATIONS
(2022)
Article
Multidisciplinary Sciences
M. C. Rahn, K. Kummer, A. Hariki, K-H Ahn, J. Kunes, A. Amorese, J. D. Denlinger, D-H Lu, M. Hashimoto, E. Rienks, M. Valvidares, F. Haslbeck, D. D. Byler, K. J. McClellan, E. D. Bauer, J. X. Zhu, C. H. Booth, A. D. Christianson, J. M. Lawrence, F. Ronning, M. Janoschek
Summary: Resonant inelastic X-ray scattering (RIXS) was used in this study to investigate CePd3 and clarify the hybridization process between local high-energy degrees of freedom and the underlying metallic state at low temperature, highlighting its impact on the properties of correlated metals.
NATURE COMMUNICATIONS
(2022)
Article
Chemistry, Physical
Lenart Dudy, Piotr Chudzinski, Julian Aulbach, Victor Rogalev, Joerg Schaefer, Ralph Claessen
Summary: In this study, we investigated the temperature dependence of the metallic-like bands of Si(553)-Au using angular-resolved photoemission spectroscopy. By overcoming the challenges posed by surface stability and photo-voltage effects, we were able to extract changes in band-filling and Fermi-velocity. Our findings shed light on the nature of the low-temperature phase of the step edge in Si(553)-Au and rule out a structural-related phase transition.
Article
Materials Science, Multidisciplinary
M. Zapf, M. Schmitt, J. Gabel, P. Scheiderer, M. Stubinger, B. Leikert, G. Sangiovanni, L. Dudy, S. Chernov, S. Babenkov, D. Vasilyev, O. Fedchenko, K. Medjanik, Yu Matveyev, A. Gloskowski, C. Schlueter, T-L Lee, H-J Elmers, G. Schonhense, M. Sing, R. Claessen
Summary: Novel two-dimensional electron systems at the interfaces and surfaces of transition-metal oxides have recently gained attention for their tunable and intriguing properties. In this study, a high-mobility quasi-two-dimensional electron system with strong spin-orbit coupling was induced at the surface of a KTaO3 crystal by pulsed laser deposition of a disordered LaAlO3 film. Through angle-resolved photoelectron spectroscopy, the electronic structure of the buried electron system was mapped out. The results showed a deviation in the band structure from the bulk KTaO3 due to the confinement to the interface, and also confirmed the theoretical expectations of the confined electron system.
Article
Materials Science, Multidisciplinary
R. Frison, J. Kuespert, Qisi Wang, O. Ivashko, M. V. Zimmermann, M. Meven, D. Bucher, J. Larsen, Ch. Niedermayer, M. Janoschek, T. Kurosawa, N. Momono, M. Oda, N. B. Christensen, J. Chang
Summary: A combined x-ray and neutron diffraction study was conducted on the stripe-ordered superconductor La₀Sr₀.₁₂CuO₄. The crystal structure was found to be consistent with the orthorhombic Bmab space group commonly reported in the literature. However, this structure is not symmetry compatible with the second-order phase transition into the stripe order phase. Many forbidden Bragg peaks in the Bmab space group were observed in this study, and the analysis revealed monoclinic lattice distortions consistent with charge stripe order.
Article
Physics, Multidisciplinary
Ioannis Giannakis, Divyanshi Sar, Joel Friedman, Chang-Jong Kang, Marc Janoschek, Pinaki Das, Eric D. Bauer, Gabriel Kotliar, Pegor Aynajian
Summary: The Kondo hybridization in UGe2, a heavy fermion system, leads to the formation of two ferromagnetic phases accompanied by spin-triplet superconductivity. Scanning tunneling microscopy and spectroscopy reveal the presence of Kondo resonance and sharp 5f-electron states at high temperatures. The resonance narrows and splits, causing the itinerant f-electron spectral weight to disappear at the Fermi energy as the temperature decreases.
PHYSICAL REVIEW RESEARCH
(2022)
Article
Materials Science, Multidisciplinary
Piotr Chudzinski, Julian Aulbach, Joerg Schaefer, Ralph Claessen, Lenart Dudy
Summary: This study investigates the effects of Rashba splitting on two-leg ladders with weakly screened Coulomb interactions, showing a break in the symmetry of scattering channels and leading to new instabilities. Experimental evidence of exotic properties, such as the mixing of magnetism with charge-density wave, is observed, along with differences in signatures of order in single-particle and two-body probes. Findings on the Au-Si(553) platform demonstrate the presence of partial spectral gaps opening and confirm the expected temperature dependence of band backfolding.
Article
Materials Science, Multidisciplinary
M. Schmitt, O. Kirilmaz, S. Chernov, S. Babenkov, D. Vasilyev, O. Fedchenko, K. Medjanik, Yu Matveyev, A. Gloskovskii, C. Schlueter, A. Winkelmann, L. Dudy, H-J Elmers, G. Schoenhense, M. Sing, R. Claessen
Summary: Magnetite is considered a promising material for spintronics applications due to its high spin polarization, but previous attempts to measure it were hindered by surface sensitivity and reconstruction. This study successfully determined the intrinsic spin polarization of magnetite using a novel setup and (111)-oriented thin films grown on ZnO(0001).
Article
Materials Science, Multidisciplinary
M. C. Rahn, A. Gallagher, F. Orlandi, D. D. Khalyavin, C. Hoffmann, P. Manuel, R. Baumbach, M. Janoschek
Summary: The hidden order phase in URu2Si2 is highly sensitive to electronic doping, and the substitution of silicon with phosphorus can isolate the effects of tuning the chemical potential to some extent. This substitution induces a new antiferromagnetic phase with localized magnetic moments, and enhanced exchange interactions due to chemical pressure lead to magnetic order. Comparison with other tuning studies of URu2Si2 helps delineate the mechanisms by which silicon-to-phosphorus substitution affects the system.