Article
Physics, Multidisciplinary
P. Hemme, J-c. Philippe, A. Medeiros, A. Alekhin, S. Houver, Y. Gallais, A. Sacuto, A. Forget, D. Colson, S. Mantri, B. Xu, L. Bellaiche, M. Cazayous
Summary: This study investigates the effect of strain on the ferroelectricity and dynamic magnetic response of BiFeO3. The results show that the ferroelectric soft mode is significantly enhanced under tensile strain, and low energy magnon modes are suppressed, indicating a transition from cycloidal to homogeneous magnetic state. Effective Hamiltonian calculations reveal the competition between the ferroelectric and antiferrodistortive modes in the tensile regime.
PHYSICAL REVIEW LETTERS
(2023)
Article
Physics, Condensed Matter
Mahebub Alam, Kalyan Mandal
Summary: ErFeO3, originally a centrosymmetric structure without ferroelectricity, unexpectedly exhibits ferroelectricity and antiferromagnetism at room temperature. The deviation of Fe3+-O-Fe3+ bond angles and the presence of super-exchange interaction contribute to this unique behavior. Complex impedance analysis and fitting with an equivalent circuit diagram reveal the conduction mechanism of ErFeO3, as well as the contribution of grain and grain boundary to its properties.
PHYSICA B-CONDENSED MATTER
(2021)
Article
Materials Science, Multidisciplinary
Rahul Kumar, A. Sundaresan
Summary: In this paper, the field-induced ferroelectricity in BaHoFeO4 within a narrow range of applied magnetic fields (1.5 T H 5 T) is reported. Magnetization measurements reveal magnetic anomalies at TFe ordering of Fe3+, a possible spin structure change of Fe3+, and the antiferromagnetic ordering of Ho3+ sublattices. Heat capacity data did not show any anomaly at TNFe, but exhibited a broad N . Isothermal magnetization measurements indicate a metamagnetic transition at 1.5 T below 40 K. Temperature-dependent dielectric measurements below 1 T reveal two anomalies corresponding to Ho3+ ordering and a possible change in the magnetic phase of the Fe sublattice. These anomalies disappear at higher magnetic fields, and a different dielectric anomaly appears above the metamagnetic transition. A switchable electric polarization appears below 25 K and above the metamagnetic transition field (H 1.5 T), but disappears above 5 T.
Article
Chemistry, Physical
Anindityo Nugra Arifiadi, Kwang-Tak Kim, Inna Yusnila Khairani, Chang Bae Park, Kee Hoon Kim, Sang-Koog Kim
Summary: CoFe2O4-BiFeO3 (CFO-BFO) nanocomposites were synthesized using a combination hydrothermal/citric acid sol-gel method, resulting in high-purity crystalline nanocomposites. The sintered sample with a 2:2 ratio exhibited high magnetization value, indicating dipolar interaction between CFO and BFO. The results suggest a reliable magnetic-field control of electric polarization in these multiferroic CFO-BFO nanocomposites.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Multidisciplinary
Wan-Rong Geng, Yun-Long Tang, Yin-Lian Zhu, Yu-Jia Wang, Bo Wu, Li-Xin Yang, Yan-Peng Feng, Min-Jie Zou, Tong-Tong Shi, Yi Cao, Xiu-Liang Ma
Summary: This study demonstrates the existence of multi-field-driven magnetoelectric-optical coupling mediated by ferroelastic switching at room temperature. It provides a framework for designing potential multifunctional magnetoelectric devices.
ADVANCED MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
T. Ahamed, A. Ahad, Mithun Kumar Das, M. A. Taher, Mohammad J. Miah, M. N. I. Khan
Summary: Polycrystalline Bi0.90Eu0.10Fe1-xVxO3 (BEFVO) ceramics were synthesized via solid-state reaction. The XRD pattern showed hexagonal crystal structures with impurity peaks. The doped BiFeO3 (BFO) exhibited greater stability than the parent BFO. The samples had varying crystallite sizes, densities, dielectric constant, resistivity, and magnetic properties depending on the V concentration.
RESULTS IN PHYSICS
(2023)
Article
Materials Science, Multidisciplinary
Xilong Xu, Ting Zhang, Ying Dai, Baibiao Huang, Yandong Ma
Summary: Using first-principles calculations, the researchers discovered that a nontrivial antiferromagnetic topological phase can be achieved in a multiferroic heterobilayer consisting of MnSe and In2S3. The control of this topological phase can be realized by reversing the ferroelectric polarization.
Article
Materials Science, Multidisciplinary
Jian-Min Yan, Ke Wang, Zhi-Xue Xu, Jing-Shi Ying, Ting-Wei Chen, Guo-Liang Yuan, Tao Zhang, Hai-Wu Zheng, Yang Chai, Ren-Kui Zheng
Summary: In this study, a ZnO layer was inserted on top of a ferroelectric BFTO film to form a p-n junction, improving electron extraction efficiency in photovoltaic devices significantly. Furthermore, changing the ferroelectric polarization direction led to additional enhancement in device performance.
JOURNAL OF MATERIALS CHEMISTRY C
(2021)
Article
Chemistry, Physical
Runqing Zhang, Peiju Hu, Lingling Bai, Xing Xie, Huafeng Dong, Minru Wen, Zhongfei Mu, Xin Zhang, Fugen Wu
Summary: In this study, two new stable BiFeO3 structures with large spontaneous polarization were found using an ab initio evolutionary algorithm. The discovery expands the structural diversity of BiFeO3 and holds constructive significance for the study of spontaneous polarization in new structures of multiferroic materials.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Chemistry, Inorganic & Nuclear
Nibedita Das, Sandeep Kumar, Vibhor Kumar, Nidhi Jain, Satyendra Singh, Laxmi C. Gupta, Ashok K. Ganguli
Summary: Efficient charge separation in ferroelectric materials can enhance solar energy conversion efficiency. In this study, two new multiferroic, semiconducting materials were synthesized with suitable band positions and bandgaps for efficient visible-light-driven photoelectrochemical water splitting applications. Spectroscopy and photoluminescence studies demonstrated enhanced visible light activity in these materials.
JOURNAL OF SOLID STATE CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Yancong Chen, Zhiyuan Tang, Minzhi Dai, Xin Luo, Yue Zheng
Summary: This study proposes a novel multiferroic tunneling junction that utilizes the electric polarization direction of the 2D ferroelectric material In2Se3 and the magnetization alignment of the electrodes to modulate resistance, achieving multiple resistance states. The inserted h-BN layer enhances both tunneling magnetoresistance and electroresistance, showing great potential in non-destructive non-volatile memories.
Article
Chemistry, Multidisciplinary
Bin Peng, Qi Lu, Haowen Tang, Yao Zhang, Yuxin Cheng, Ruibin Qiu, Yunting Guo, Ziyao Zhou, Ming Liu
Summary: In this study, researchers achieved a larger voltage control of magnetic anisotropy (VCMA) effect in thin films compared to bulk counterparts. This was made possible by utilizing the large in-plane piezo-strain mediated magnetoelectric coupling under strong fields. This finding is significant for developing integrated magnetic and spintronic devices.
MATERIALS HORIZONS
(2022)
Article
Physics, Condensed Matter
N. Ajnef, M. M. Habchi, A. Rebey
Summary: The study systematically explored the optical properties of interband and intersubband transitions in GaNAsBi/GaAs quantum well heterostructure. The importance of the polarization mode in changing optical absorption magnitude was highlighted through theoretical optimization of physical parameters, indicating the potential for tuning photodetection spectra in future designed systems by controlling relevant parameters.
MICRO AND NANOSTRUCTURES
(2022)
Article
Materials Science, Ceramics
Lu Liu, Yehui Zhang, Xin Xin Shi, Xiao Qiang Liu, Xiao Li Zhu, Bin Xu, Xiang Ming Chen
Summary: This study obtained Bi0.86Sm0.14FeO3 ceramics with near Pna2(1) single-phase structure through a repeated longtime sintering process. The evolution of Pna2(1) symmetry, ferroelectric transition, and magnetoelectric coupling were determined, revealing a giant electric field-controlled magnetism effect. The results deepen the understanding of Pna2(1) phase and offer insights for enhancing electric field-controlled magnetism in RE-substituted BiFeO3 multiferroic ceramics.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2022)
Article
Physics, Multidisciplinary
Yi Zhang, Yuhao Gu, Pengfei Li, Jiangping Hu, Kun Jiang
Summary: Motivated by recent progress in the superconductivity nonreciprocal phenomena, this study investigates the general theory of Josephson diodes, focusing on the asymmetric proximity process inside the tunneling barrier. From the perspective of symmetry breaking, there are two types of Josephson diodes: inversion breaking and time-reversal breaking. Voltage bias can effectively tune the proximity process in the inversion breaking case, while current flow can adjust the internal time-reversal breaking field in the time-reversal breaking case. These findings provide a comprehensive understanding and general principles for realizing Josephson diodes, including the recently discovered NbSe2/Nb3Br8/NbSe2 Josephson diodes.
Article
Chemistry, Multidisciplinary
Chengxi Huang, Jian Zhou, Huasheng Sun, Fang Wu, Yusheng Hou, Erjun Kan
Summary: This study theoretically predicts the coexistence of ferromagnetic and ferroelectric orders in a 2D transition metal carbide, where the spatial distribution of magnetic moments strongly couples with the electric polarization. Furthermore, an electric-field switching between ferromagnetic and ferrimagnetic orders is achievable by constructing a multiferroic vdW heterostructure based on this material.
Article
Physics, Applied
Cui-Qun Chen, Xiao-Sheng Ni, Dao-Xin Yao, Yusheng Hou
Summary: This study systematically investigates the electronic and topological properties of a class of 2D metal-organic frameworks (MOFs). The results show that these MOFs exhibit desirable properties such as Chern insulation and high Curie temperature, making them promising for applications in quantum anomalous Hall effect and spintronic devices.
APPLIED PHYSICS LETTERS
(2022)
Article
Nanoscience & Nanotechnology
Qingyun Zhou, Xingyuan Chen, Xiangfu Xu, Yusheng Hou, Tianshu Lai, Dao-Xin Yao
Summary: It is proposed that a graphene/nonmagnetic semiconductor CdX heterostructure can eliminate magnetic effects and achieve optical injection of spin polarization. First-principles calculations reveal that graphene on CdX slabs maintains its linear Dirac band structure and generates a built-in electric field near the interface. This electric field drives spin polarized electrons into graphene, and an optical detection scheme for measuring graphene's spin relaxation time is proposed based on Faraday and Hanle effects.
PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES
(2023)
Article
Chemistry, Multidisciplinary
Hao Li, Yali Yang, Shiqing Deng, Hui Liu, Tianyu Li, Yuzhu Song, He Bai, Tao Zhu, Jiaou Wang, Huanhua Wang, Er-Jia Guo, Xianran Xing, Hongjun Xiang, Jun Chen
Summary: Regulating the magnetic properties of multiferroics enables their potential application in spintronic devices. By utilizing oxygen defect engineering, we significantly enhanced the room temperature ferromagnetism of a representative ferrite, EuFeO3. Our findings suggest that the decrease in Fe-O-Fe bond angles caused by oxygen vacancies strengthens magnetic interactions and tilts Fe spins, leading to an approximately five-fold increase in saturation magnetization. Furthermore, we established the internal relationship between magnetism and oxygen vacancies by illustrating how magnetic structure and magnitude change with varying vacancy configuration and concentration. This strategy for regulating magnetic properties has broad applicability to various functional oxide materials.
Article
Physics, Multidisciplinary
Qingyun Zhou, Yusheng Hou, Tianshu Lai
Summary: In this paper, the electronic properties of graphene/InP heterostructures are calculated using density functional theory to understand the low power conversion efficiency (PCE) reported experimentally. It is found that the low Schottky barrier height (SBH) formed by the graphene contact with InP is the main reason for the low PCE. A new heterostructure, graphene/insulating layer/InP solar cells, is proposed to increase the SBH and PCE. Additionally, it is discovered that the bandgap of graphene and the SBH in graphene/InP heterostructures can be tuned by applying an electric field, which is useful for photodetectors.
FRONTIERS OF PHYSICS
(2023)
Article
Materials Science, Multidisciplinary
Fengliang Liu, Yiqing Hao, Jinyang Ni, Yongsheng Zhao, Dongzhou Zhang, Gilberto Fabbris, Daniel Haskel, Shaobo Cheng, Xiaoshan Xu, Lifeng Yin, Hongjun Xiang, Jun Zhao, Xujie Lu, Wenbin Wang, Jian Shen, Wenge Yang
Summary: Hexagonal LuFe2O4 exhibits various charge-ordered phases with different magnetic orders under external pressure. The redistribution of charge density induced by pressure in the frustrated double-layer [Fe2O4] cluster is responsible for the correlated spin-charge phase transitions. Enhanced Coulomb interactions among Fe-Fe bonds drive the frustrated charge order into a less frustrated charge order, leading to the transition from ferrimagnetism to antiferromagnetism. This study not only elucidates the coupling mechanism among charge, spin, and lattice degrees of freedom in LuFe2O4, but also provides a new approach for tuning spin-charge orders.
NPJ QUANTUM MATERIALS
(2023)
Article
Physics, Applied
Liang Qiu, Zequan Wang, Xiao-Sheng Ni, Dao-Xin Yao, Yusheng Hou
Summary: Tuning the damping of ferromagnetic metals is important for spintronic devices, and in this study, we investigate the magnetic properties of a van der Waals heterostructure formed by the FM metal CrTe2 and the ferroelectric monolayer In2Te3. We demonstrate that the magnetic easy axis of CrTe2 can be switched from in-plane to out-of-plane by reversing the ferroelectric polarization of In2Te3, and the Gilbert damping of CrTe2 can be tunable by changing the polarization direction of In2Te3. Our findings provide a promising approach to electrically control the damping of two-dimensional ferromagnetic metals by integrating them with ferroelectrics.
APPLIED PHYSICS LETTERS
(2023)
Article
Physics, Applied
Xiao-Sheng Ni, Yue-Yu Zhang, Dao-Xin Yao, Yusheng Hou
Summary: Recently, there has been growing interest in 2D transition metal chalcogenide monolayers due to their unique magnetic and electronic properties. In this study, we discovered a previously unexplored 2D antiferromagnetic CrSe monolayer with stable properties and a higher Neel temperature than room temperature. We also predicted an electric field-controllable metal-insulator transition in a van der Waals heterostructure composed of CrSe and Sc2CO2. This transition is attributed to changes in band alignment caused by the ferroelectric polarization reversal in Sc2CO2. Our findings suggest important potential applications for 2D antiferromagnetic CrSe monolayers in spintronics.
APPLIED PHYSICS LETTERS
(2023)
Article
Chemistry, Physical
Huimin Zhang, Yang Zhong, Chuying Ouyang, Xingao Gong, Hongjun Xiang
Summary: Layered LiMO2 (M = Co, Ni, and Mn) materials with distinctive layer structure are commonly used as cathode materials in lithium-ion batteries. In this study, a detailed investigation of LiNiO2, LiMnO2, and a half-doped material LiNi0.5Mn0.5O2 is performed using first-principles calculations and Monte Carlo simulations. The results reveal the most stable zigzag-type structure of LiNiO2 and different magnetic ground states in these three systems. The competition between short-range and long-range spin exchange interactions leads to a spiral order in LiNiO2, while the collinear antiferromagnetic state in LiMnO2 is determined by its nearest and next-nearest neighbor antiferromagnetic spin exchange interactions. On the other hand, the collinear ferrimagnetic state in LiNi0.5Mn0.5O2 is attributed to the ferromagnetic exchange interactions between nearest neighbor Ni-Ni and Mn-Mn pairs. This work demonstrates the relevance of different exchange interactions in these cathode materials to the performance of lithium-ion batteries.
JOURNAL OF CHEMICAL PHYSICS
(2023)
Article
Physics, Multidisciplinary
Junyi Ji, Guoliang Yu, Changsong Xu, H. J. Xiang
Summary: In this paper, a theory of bilayer stacking ferroelectricity (BSF) is proposed, which explains the ferroelectric behavior in stacked layers of the same 2D material with different rotation and translation. The theory is supported by group theory analysis and first-principles simulations, and it provides a new perspective and a solid foundation for designing a variety of bilayer ferroelectrics. The study also highlights the potential application of manipulating the electric polarization in the bilayer.
PHYSICAL REVIEW LETTERS
(2023)
Article
Physics, Multidisciplinary
Jiabin Chen, Yang Li, Hongyu Yu, Yali Yang, Heng Jin, Bing Huang, Hongjun Xiang
Summary: Controlling magnetic properties using optical stimulation is not only interesting from a physics perspective, but also significant for practical applications like magneto-optical devices. Based on a simple tight-binding model, a general theory of light-induced magnetic phase transition in antiferromagnets is proposed, which has been confirmed by first-principles calculations on 2D van der Waals antiferromagnetic materials. The theory provides a new approach to manipulate 2D magnetism with high speed and superior resolution.
SCIENCE CHINA-PHYSICS MECHANICS & ASTRONOMY
(2023)
Article
Physics, Multidisciplinary
Hualei Sun, Liang Qiu, Yifeng Han, Yunwei Zhang, Weiliang Wang, Chaoxin Huang, Naitian Liu, Mengwu Huo, Lisi Li, Hui Liu, Zengjia Liu, Peng Cheng, Hongxia Zhang, Hongliang Wang, Lijie Hao, Man-Rong Li, Dao-Xin Yao, Yusheng Hou, Pengcheng Dai, Meng Wang
Summary: Understanding the interplay between superconductivity and magnetism in EuTe2 is achieved through high pressure studies. A structural transition and superconductivity are observed at different pressures. Strong couplings between local moments and conduction electrons are observed in the low-pressure phase, while the high-pressure phase loses magnetism and has a lower upper critical field.
COMMUNICATIONS PHYSICS
(2023)
Article
Chemistry, Physical
Yang Zhong, Hongyu Yu, Xingao Gong, Hongjun Xiang
Summary: In this study, we propose a new framework called edge-based tensor prediction graph neural network that addresses the incompatibility of traditional invariant GNNs with directional properties. By expressing tensors as linear combinations of local spatial components projected on the edge directions of clusters with varying sizes, our framework is rotationally equivariant and satisfies the symmetry of local structures. We demonstrate the accuracy and universality of our framework by successfully predicting various tensor properties from first to third order. This work enables GNNs to step into the broad field of prediction of directional properties.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2023)
Article
Physics, Multidisciplinary
Xuanyi Li, Changsong Xu, Boyu Liu, Xueyang Li, L. Bellaiche, Hongjun Xiang
Summary: A realistic first-principle-based spin Hamiltonian is constructed for the type-II multiferroic NiI2, which includes single ion anisotropy, isotropic Heisenberg terms, Kitaev interaction, and a biquadratic term. The model can reproduce the experimental helical ground state features and establish the relationship between Kitaev interaction and the multiferroicity of NiI2. Additionally, Monte Carlo simulations reveal three equivalent domains and different topological defects.
PHYSICAL REVIEW LETTERS
(2023)
Article
Materials Science, Multidisciplinary
Yingwei Chen, Yali Yang, Changsong Xu, Hongjun Xiang
Summary: In this paper, a method of constraining spin directions by imposing a local parallel magnetic field is proposed. It is found that this method is more efficient in constraining spin directions than existing methods.