A formalism to calculate Raman susceptibilities as well as nonlinear optical susceptibilities with ultrasoft pseudopotentials is presented. Based on the 2n + 1 theorem, the third-order energy derivatives are computed from the first-order wave functions, in which a uniform electric field is treated by taking a long-wavelength limit analytically. For this treatment, two non-self-consistent second-order Sternheimer equations are introduced. Since they need to be solved only once, an additional computational effort is quite small as compared with those for the linear response calculations, in particular, for large systems. The method is applied for alpha-SiO2 and YMn2H6 to validate the formalism.
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