Starting from the microscopic Hamiltonian describing free electrons in a periodic lattice, we derive the Hamiltonian appropriate to Frenkel excitons. This is done through a grouping of terms different from the one leading to Wannier excitons. This grouping makes the atomic states appear as a relevant basis to describe Frenkel excitons in the second quantization. Using them, we derive the Frenkel exciton creation operators as well as the commutators which rule these operators and which make the Frenkel excitons differ from elementary bosons. The main goal of the present paper is to provide the necessary grounds for future works on Frenkel exciton many-body effects, with the composite nature of these particles treated exactly through a procedure similar to the one we have recently developed for Wannier excitons.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据